Briliant: Jurnal Riset dan Konseptual
Vol 11 No 1 (2026): Volume 11 Nomor 1, Februari 2026

STUDI KINETIKA REAKSI EKSTRAKSI DOLOMIT DENGAN ASAM FOSFAT

Fahturrozak, Ahmad (Unknown)
Adzani, Mayla Fayzza (Unknown)
Sumada, Ketut (Unknown)



Article Info

Publish Date
22 Feb 2026

Abstract

Dolomite (CaMg(CO₃)₂) is generally white but can also appear gray or bluish, with magnesium (Mg) and calcium (Ca) as its main composition.. This study analyzes the kinetics and conversion of dolomite extraction using phosphoric acid through a solid-liquid extraction method. Initially, dolomite was calcined at 850°C for 240 minutes and then sieved. A total of 40 grams of the sieved sample was extracted with 250 mL of 2M phosphoric acid at varying temperatures (30, 45, 60, 75, and 90°C) and extraction times (60, 90, 120, 150, and 180 minutes). The extracted solution was filtered and analyzed using AAS to determine the extracted calcium and magnesium content. The highest conversion was achieved at 90°C for 180 minutes, with calcium extraction at 65.67% and magnesium at 65.98%, with the ash layer as the controlling step. The activation energy, based on the Arrhenius equation, was 27,745.49 J/mol·K for calcium and 19,120.5 J/mol·K for magnesium, with reaction rate constants of K=9.8149 e^(3336.6/T) for calcium and K=1.8063 e^(2299.8/T) for magnesium. This study demonstrates that temperature and reaction time significantly influence dolomite extraction, which follows the Arrhenius model, providing valuable insights into the kinetics and efficiency of dolomite extraction using phosphoric acid.

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Journal Info

Abbrev

BRILIANT

Publisher

Subject

Civil Engineering, Building, Construction & Architecture Computer Science & IT Education

Description

BRILIANT : Jurnal Riset dan Konseptual published by Universitas Nahdlatul Ulama Blitar. Published four times a year in print and online. Journals are published every three months, in February, May, August and November. The article topics contained in this journal are the results of research and ...