Mechanical Engineering for Society and Industry
Vol 5 No 2 (2025)

Investigating the corrosion behavior of hot-dip galvanized Zn and Zn-10Al coatings on carbon steel without top coating in chloride-rich immersion environments

Agus Solehudin (Universitas Pendidikan Indonesia, Indonesia)
Haipan Salam (Universitas Pendidikan Indonesia, Indonesia)
Risti Ragadhita (Universitas Pendidikan Indonesia, Indonesia)
Muhammad Irfansyah Maulana (Daegu Gyeongbuk Institute of Science and Technology (DGIST), Republic of Korea)



Article Info

Publish Date
28 Dec 2025

Abstract

This study investigates the corrosion resistance, surface hardness, morphological structure, and predicted lifetime of carbon steel coated with pure zinc (Zn) and zinc aluminum alloy (ZnAl) in chloride rich environments. Coatings were applied by hot dip galvanizing, and characterized using Field Emission Scanning Electron Microscopy Energy Dispersive X-ray Spectroscopy (FESEM-EDS), Vickers hardness testing, and salt spray testing. Before exposure, both coatings confirmed homogeneity with smooth, topographically uniform surfaces, and no macroscopic defects. ZnAl coatings also delivered superior hardness compared to pure Zn and uncoated steel. After exposure, ZnAl maintained smoother, more stable surfaces with smaller and fewer pitting defects, whereas pure Zn suffered medium to severe damage. Pure Zn coatings showed fluctuating corrosion behavior with an average rate of 7.8944 µm/year, while ZnAl coatings exhibited minimal fluctuations within ±0.1 µm/year, indicating high resistance to chloride concentration. Predicted lifetime ranged from 3.7 to 5.5 years for pure Zn (average 4.7 years) and 5.9 to 6.5 years for ZnAl (average 6.2 years). Despite being thinner, ZnAl provided superior corrosion protection and structural stability. These findings indicate that ZnAl alloy coatings provide superior corrosion protection, structural stability, and mechanical performance for carbon steel in chloride rich environments.

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Journal Info

Abbrev

mesi

Publisher

Subject

Aerospace Engineering Automotive Engineering Chemical Engineering, Chemistry & Bioengineering Control & Systems Engineering Electrical & Electronics Engineering Energy Engineering Industrial & Manufacturing Engineering Materials Science & Nanotechnology Mechanical Engineering Transportation

Description

Aims Mechanical engineering is a branch of engineering science that combines the principles of physics and engineering mathematics with materials science to design, analyze, manufacture, and maintain mechanical systems (mechanics, energy, materials, manufacturing) in solving complex engineering ...