Warta IHP (Warta Industri Hasil Pertanian)
Vol 27, No 01 (2010)

(The Effect of Acetate Anhhhydrida Ratio in the Process of Cellulose Acetylation of Pulp from Sengon (Paraserianthe falcataria) on the Production of Cellulose Triacetate Polymer)

Meurah Rosnelly, Cut (Unknown)
Aziz Darwis, Abdul (Unknown)
Noor, Erliza (Unknown)
-, Kaseno (Unknown)



Article Info

Publish Date
07 Jul 2017

Abstract

Almost all of Cellulose acetate is produced by reaction of cellulose and acetic anhydride using strong acids as catalyst and acetic acid as a solvent. A typical industrial process requires very high quality cellulose raw materials having a high a-cellulose content. The cellulose used as a raw material in this research is wood pulp of sengon (Paraserianthes falcataria) due to fast growing species and has potential used as a raw material as if has a high cellulose content. The main objective of this research was to obtain condition for making cellulose triacetate by applying applying ratio levels of acetic anhydride toward cellulose in acetylation process. Cellulose triacetate flake was produced by activation and acetylation process. Activation was carried out by mixing cellulose of sengon pulp with glacial acetic in proportion  1:8 at 50oC about 15; 30; 60; 90, and 120 minutes. Acetylation is then conducted using reagents in following proportions relative to the pulp mass; variable of acetic anhydride ratio (3.35:1), (4:1), (5:1), and (6:1), acetic acid as solvent (4.5 : 1), sulfuric acid (0.015 : 1) as catalyst while controlling the reaction temperature at 50oC for 60 minutes. The result showed anhydride toward cellulose 3.35 in acetylation process.

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Journal Info

Abbrev

ihp

Publisher

Subject

Agriculture, Biological Sciences & Forestry Industrial & Manufacturing Engineering

Description

Warta IHP (Industri Hasil Pertanian) is a Scientific Journal which is sourced from research papers, new theoretical/interpretive findings, and critical studies or reviews (by invitation) in the agro-based industry scope that cover any discipline such as: food science and technology, agricultural ...