Journal of Physics: Theories and Applications
Vol 10, No 1 (2026): Journal of Physics: Theories and Applications

Electrolyte concentration and nafion membrane effects on supercapacitor discharge dynamics and charge retention

Jagendra Chaudhari (Department of Physics, Patan Multiple Campus, Tribhuvan University, Patandhoka, Lalitpur-44700, Nepal)
Sangita Rai (Department of Physics, Goldengate International College, Tribhuvan University, Kathmandu, Nepal)



Article Info

Publish Date
31 Mar 2026

Abstract

Supercapacitors (SCs) are promising energy storage devices due to their high charge retention and rapid discharge capabilities. However, the efficiency of supercapacitors can be influenced by factors such as the choice of separator material and electrolyte concentration. This study investigates the performance of SCs fabricated using Nafion separators with Na₂SO₄ electrolytes of varying concentrations (1M and 0.5M) and charging conditions. The objective of this research is to evaluate the self-discharge behavior, capacitance, and voltage stability of supercapacitors to determine the optimal configuration for high-performance energy storage. The methodology involves fabricating SCs with Nafion separators and charging them under different voltages (1V, 1.2V, 1.4V) for varying time intervals (1 minute, 1.5 minutes, and 2 minutes). Self-discharge characteristics were monitored, and capacitance was calculated using the capacitor discharge equation. The experiments also included discharge tests using a 500-ohm resistor to simulate realistic usage. Major findings include that SCs with Nafion separators and 0.5M Na₂SO₄ electrolyte exhibit significantly lower self-discharge rates and more stable voltage profiles than those with napkin paper separators. Higher charging voltages and longer charging times lead to better charge retention. These results suggest that Nafion membranes and optimized electrolyte concentrations enhance supercapacitor performance, making them suitable for long-term, efficient energy storage applications.

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Journal Info

Abbrev

jphystheor-appl

Publisher

Subject

Education Materials Science & Nanotechnology Physics

Description

Journal of Physics: Theories and Applications (cited as J. Phys.: Theor. Appl.) is a peer-reviewed and open access journal, which is published twice a year by Physics Department, Sebelas Maret University. The journal is designed to serve researchers, developers, professionals, graduate students and ...