JPSE (Journal of Physical Science and Engineering)
Vol 9, No 2 (2024): JPSE (Journal of Physical Science and Engineering)

The Role of CTAB Surfactant Composition on the Structural and Magnetic Properties of Mn0.5Zn0.5Fe2O4 Ferrofluid for Energy Harvesting Devices

Wa Ode Umratul Khazanah (Universitas Negeri Malang)
Arif Hidayat (Universitas Negeri Malang)
Ahmad Taufiq (Universitas Negeri Malang)
ST. Ulfawanti Intan Subadra (Universitas Negeri Malang)



Article Info

Publish Date
31 Oct 2024

Abstract

Concerns about environmental damage caused by pollution and the use of non-renewable energy sources have driven many researchers to explore sustainable energy-harvesting materials. This study successfully developed an energy harvester based on Mn0.5Zn0.5Fe2O4 ferrofluid. Notably, Cetyl Trimethyl Ammonium Bromide (CTAB) was used as the surfactant in the synthesis of the Mn0.5Zn0.5Fe2O4 ferrofluid via the coprecipitation method. The CTAB mass was varied at 0, 0.25, 0.5, 0.75, and 1 gram, labeled as MZC0, MZC0.25, MZC0.5, MZC0.75, and MZC1. XRD patterns showed that MZC0 have a cubic spinel structure, while CTAB addition altered the structure to monoclinic, following CTAB’s pattern. FTIR spectra at 418.1, 571.1, and 445.3 cm⁻¹ confirmed Mn–O, Fe–O, and Zn–O stretching, indicating successful spinel formation. Meanwhile, FTIR bands at 2800 and 2900 cm⁻¹ in MZC0.25–MZC1 samples were due to C–H stretching from CTAB. VSM analysis revealed a decreasing saturation magnetization (Ms) with increasing CTAB. SEM images confirmed surfactant coating on nanoparticles. Energy harvesting tests showed output voltages of -0.4 to 2.9 V and low induced currents (0.3–1.9 μA), suggesting the potential of Mn0.5Zn0.5Fe2O4/CTAB-based ferrofluid as an eco-friendly energy harvester.

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Journal Info

Abbrev

jpse

Publisher

Subject

Astronomy Electrical & Electronics Engineering Materials Science & Nanotechnology Physics

Description

JPSE (Journal of Physical Science and Engineering) is published twice a year in April and October by Physics Department of Universitas Negeri Malang, Indonesia. e-ISSN: 2541-2485 The journal is devoted to publishing original, frontier and important of various branches of Physics Science and ...