Civil Engineering Journal
Vol 4, No 3 (2018): March

Optimization of Process Parameters by Response Surface Methodology for Methylene Blue Removal Using Cellulose Dusts

Seyed Hassan Sharifi Pajaie (Wood and Paper Science Department, Faculity of Natural Resources, Sari Agricultural Sciences and Natural Resource University)
Saltanat Archin (Wood and Paper Science Department, Faculity of Natural Resources, Sari Agricultural Sciences and Natural Resource University)
Ghasem Asadpour (Wood and Paper Science Department, Faculity of Natural Resources, Sari Agricultural Sciences and Natural Resource University)



Article Info

Publish Date
07 Apr 2018

Abstract

This study was aimed to use Cellulose dusts (CD) produced in drying section of paper mills of paper making industry as a potential adsorbent to remove methylene blue (MB) dye from aqueous solution.  The adsorbent was characterized by scanning electron microscopy and Fourier transform infrared spectrometer and X-ray Diffraction. The influences of the effective parameters including pH solution, adsorbent dosage, initial MB concentration, and contact time were optimized by CCD which stands for central composite design. The influence of these parameters on the adsorption capacity was analyzed using the batch process. The accuracy of the equation that is produced by CCD was affirmed by the variance analysis and also by calculating the correlation coefficient that connects the predicted and the empirical values of the percentage of removed MB dye. Maximum removal percentage of MB dye (98.05 %) which obtained at pH 9.84, adsorbent dosage 4.38 g L-1, MB concentration 75.50 g L-1 and time 208.13 min. Freundlich, Temkin, Harkins-Jura and Langmuir isotherms are used to analyze the empirical data. Results revealed that the data is in a satisfying agreement with the Freundlich isotherm (R2= 0.99). Pseudo-first order, Pseudo-second-order, Elovich and Intraparticle diffusion models were used to fit the kinetic data and it is found out that MB dye’s adsorption onto CD has a good agreement with the pseudo-second-order kinetic model. The results showed that CD can be an efficient and low-cost adsorbent for methylene blue adsorption.

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Journal Info

Abbrev

cej

Publisher

Subject

Civil Engineering, Building, Construction & Architecture

Description

Civil Engineering Journal is a multidisciplinary, an open-access, internationally double-blind peer -reviewed journal concerned with all aspects of civil engineering, which include but are not necessarily restricted to: Building Materials and Structures, Coastal and Harbor Engineering, ...