Indonesian Journal of Chemistry
Vol 8, No 1 (2008)

CHARACTERISTIC OF ACRYLIC ACID GRAFTED POLYETHYLENE FILM PREPARED BY GAMMA IRRADIATION METHOD

John Hendri (Department of Chemistry, Faculty of Mathematics and Natural Sciences, Lampung University, Bandar Lampung, 35144)
Irwan Ginting Suka (Department of Chemistry, Faculty of Mathematics and Natural Sciences, Lampung University, Bandar Lampung, 35144)
Wasinton Simanjuntak (Department of Chemistry, Faculty of Mathematics and Natural Sciences, Lampung University, Bandar Lampung, 35144)
Annisa Annisa (Department of Chemistry, Faculty of Mathematics and Natural Sciences, Lampung University, Bandar Lampung, 35144)
Gatot Gatot (Centre for the Application Technology of Isotopes and Radiation, National Nuclear Energy Agency, Jl. Cinere, Pasar Jumat, Jakarta Selatan)



Article Info

Publish Date
17 Jun 2010

Abstract

In this study, high density polyethylene (PE) film (thickness 80 μm) was modified by grafting of acrylic acid (AA) onto the film using 15 kGy of g irradiation as initiator, applied at different exposure times. In addition to irradiation dose, other variables investigated are concentration of AA, the type of solvent, and polymerization time carried out at 60 oC. The success of the graft copolymerization processes was confirmed by analysing the grafted film using FTIR spectroscopy, which revealed the existence of absorption band at wave number of 1721 cm-1(assigned to C=O), and that at 3385 cm-1 (assigned to -OH), and the physical endurance of the sample was evaluated by carrying out tensile strength measurement. The percent of grafting was determined according to the gravimetric method. The results indicated that the highest percent of grafting was obtained by application of 2-hour irradiation time, with monomer concentration of 30 % in water as a solvent, grafting temperature of 60 oC. Activity of grafted was evaluated by measurement of the absorption capacity toward water and Cu2+ ion, and revealed the increase of the absorption capacity with increased percent of grafting.

Copyrights © 2008






Journal Info

Abbrev

ijc

Publisher

Subject

Chemical Engineering, Chemistry & Bioengineering Chemistry

Description

Indonesian Journal of Chemistry is an International, peer-reviewed, open access journal that publishes original research articles, review articles, as well as short communication in all areas of chemistry including applied chemistry. The journal is accredited by The Ministry of Research, Technology ...