Indonesian Journal of Chemistry
Vol 10, No 2 (2010)

SORPTION OF Au(III) BY Saccharomyces cerevisiae BIOMASS

Amaria Amaria (Department of Chemistry, Faculty of Mathematics and Natural Sciences, Surabaya State University, Surabaya)
Suyono Suyono (Department of Chemistry, Faculty of Mathematics and Natural Sciences, Surabaya State University, Surabaya)
Eko Sugiharto (Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Yogyakarta)
Anis N Rohmah (Department of Chemistry, Faculty of Mathematics and Natural Sciences, Surabaya State University, Surabaya)



Article Info

Publish Date
08 Jul 2010

Abstract

Au(III) sorption by S. cerevisiae biomass extracted from beer waste industry was investigated. Experimentally, the sorption was conducted in batch method. This research involved five steps: 1) identification the functional groups present in the S. cerevisiae biomass by infrared spectroscopic technique, 2) determination of optimum pH, 3) determination of the sorption capacity and energy, 4) determination of the sorption type by conducting desorption of sorbed Au(III) using specific eluents having different desorption capacity such as H2O (van der Waals), KNO3 (ion exchange), HNO3 (hydrogen bond), and tiourea (coordination bond), 5) determination of effective eluents in Au(III) desorption by partial desorption of sorbed Au(III) using thiourea, NaCN and KI. The remaining Au(III) concentrations in filtrate were analyzed using Atomic Absorption Spectrophotometer. The results showed that: 1) Functional groups of S. cerevisiae biomass that involved in the sorption processes were hydroxyl (-OH), carboxylate (-COO-) and amine (-NH2),2) maximum sorption was occurred at pH 4, equal to 98.19% of total sorption, 3) The sorption capacity of biomass was 133.33 mg/g (6.7682E-04 mol/g) and was involved sorption energy 23.03 kJ mol-1, 4) Sorption type was dominated by coordination bond, 5) NaCN was effective eluent to strip Au(III) close to 100%.

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Journal Info

Abbrev

ijc

Publisher

Subject

Chemical Engineering, Chemistry & Bioengineering Chemistry

Description

Indonesian Journal of Chemistry is an International, peer-reviewed, open access journal that publishes original research articles, review articles, as well as short communication in all areas of chemistry including applied chemistry. The journal is accredited by The Ministry of Research, Technology ...