Indonesian Journal of Chemistry
Vol 5, No 3 (2005)

THE USE OF THE FURFURAL FROM THE SOLID WASTE OF SUGAR INDUSTRY (BAGASSE) TO SYNTHESIZE β-(2-FURYL) ACRYLIC ACID AS AN ALTERNATIVE FOR THE RAW MATERIAL OF SUNSCREEN COMPOUND

Mitarlis Mitarlis (Chemistry Department, Faculty of Mathematics and Natural Sciences State University of Surabaya, Surabaya)
Prima Retno Wikandari (Chemistry Department, Faculty of Mathematics and Natural Sciences State University of Surabaya, Surabaya)



Article Info

Publish Date
15 Jun 2010

Abstract

The research of the usefullness of furfural from bagasse for the production of β-(2-furyl)-acrilyc acid as an alternative raw material of sunscreen compound had been done. The research was done on two stages, the first stage was synthesis of furfural from bagasse and the second was synthesis of β-(2-furyl)-acrilyc acid that is an analog of cynnamic acid in which some derivatives are known possess activities as sunscreen. Cynnamic acid could be produced from benzaldehyde by Perkin methods using alkali hydrolysis. With the similarity of the main structure, so β-(2-furyl)-acrilyc acid can also be synthesized from furfural by Perkin method. The β-(2-furyl)-acrilyc acid had been synthesized in this research from furfural isolated from bagasse by NaOH hydrolysis. Synthesis was done by reflux for 2 hr at 140 - 145 oC and 3 hr at 145 - 150 oC. From the spectroscopic data its known that furfural could be produced from bagasse in 11.65 % yield and 33.83% of β-(2-furyl)-acrilyc acid from the synthesis on the second process. The UV -Vis spectrophotometer analysis result of β-(2-furyl)-acrilyc acids showed λmax at 296.20 nm. It showed that until this step the sunscreen compound can be resulted from furfural isolated from bagasse, especially as a sunscreen that protected skin from eritema (λmax at 290 - 320 nm) that is called as sunscreen UV-B. 

Copyrights © 2005






Journal Info

Abbrev

ijc

Publisher

Subject

Chemical Engineering, Chemistry & Bioengineering Chemistry

Description

Indonesian Journal of Chemistry is an International, peer-reviewed, open access journal that publishes original research articles, review articles, as well as short communication in all areas of chemistry including applied chemistry. The journal is accredited by The Ministry of Research, Technology ...