Indonesian Journal of Chemistry
Vol 1, No 1 (2001)

Selectivity of an Active Natural Zeolite in Catalytic Conversion Process of Bangkirai, Kruing and Kamper Woods Biofuel to Gasoline Fraction

Wega Trisunaryanti (Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Sekip Utara PO BOX BLS 21, Yogyakarta 55281)



Article Info

Publish Date
01 Jun 2010

Abstract

The selectivity of an active natural zeolite (ZAAH) in catalytic conversion process of Bangkirai, Kruing and Kamper woods biofuels has been studied. The ZAAH catalyst was prepared from a natural zeolite (ZA) treated with acids solution (1% HF and 6M HCI) and hydrothermal then calcined at 500 °C and oxidized at 400 °C under nitrogen and oxygen gas stream, respectively. Characterizations of the catalysts including Si/Al ratio and acidity were determined by atomic adsorption spectroscopy (AAS) and ammonia gas adsorption method, respectively. The conversion process was carried out in a flow reactor system at 400 °C, under N2 stream (20 mL/min). The biofuel was vaporized from the pyrolysis zone to the catalytic reactor. A liquid product was covered and analyzed by gas chromatograph (GC) and that connected with mass spectroscopy (GC-MS). The characterization results showed that the Si/AI ratio and acidity of the ZAAH were higher than that of the ZA catalyst. The GC-MS data showed that the highest product selectivity was 2,4-dimethyl heptane and 1,2-dimethyl benzene. The total product selectivity using the ZAAH catalyst (bangkirai = 68.10%; kruing = 54.76%; kamper = 50.72%) was higher than that of the ZA catalyst (bangkirai = 39.24%; kruing = 44.38%; kamper = 46.11%).

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Journal Info

Abbrev

ijc

Publisher

Subject

Chemical Engineering, Chemistry & Bioengineering Chemistry

Description

Indonesian Journal of Chemistry is an International, peer-reviewed, open access journal that publishes original research articles, review articles, as well as short communication in all areas of chemistry including applied chemistry. The journal is accredited by The Ministry of Research, Technology ...