Indonesian Journal of Chemistry
Vol 18, No 3 (2018)

Electrically Conductive Nanocomposites Polymer of Poly(Vinyl Alcohol)/Glutaraldehyde/Multiwalled Carbon Nanotubes: Preparation and Characterization

Fitri Khoerunnisa (Department of Chemistry, Universitas Pendidikan Indonesia, Jl. Dr. Setiabudi 229, Bandung 40154, Indonesia)
Hendrawan Hendrawan (Department of Chemistry, Universitas Pendidikan Indonesia, Jl. Dr. Setiabudi 229, Bandung 40154, Indonesia)
Yaya Sonjaya (Department of Chemistry, Universitas Pendidikan Indonesia, Jl. Dr. Setiabudi 229, Bandung 40154, Indonesia)
Rizki Deli Hasanah (Department of Chemistry, Universitas Pendidikan Indonesia, Jl. Dr. Setiabudi 229, Bandung 40154, Indonesia)



Article Info

Publish Date
30 Aug 2018

Abstract

Electrically conductive nanocomposites polymer of poly(vinyl alcohol)/PVA, glutaraldehyde (GA) and multiwalled carbon nanotubes (MWCNT) has been successfully synthesized. The polymer nanocomposites were prepared by mixing PVA, GA (crosslinker), and MWCNT dispersion with an aid of ultrasonic homogenizer at 50 °C. The content of MWCNT, in particular, was varied in order to determine the effect of MWCNT on electrical conductivity of polymer composites. The polymer mixture was casted into a disc to obtain thin film. The electrical conductivity, surface morphology, and mechanical properties of the composites film were investigated by means of four probes method, FTIR spectroscopy, X-ray diffraction, SEM, AFM, and tensile strength measurement, respectively. It was found that the optimum composition of PVA (10%): GA (1%): MWCNT (1%) was 20:20:3 in volume ratio. The addition of MWCNT induced the electrically conductive network on polymer matrix where the electrical conductivity of nanocomposites film significantly increased up to 8.28 x 10-2 S/sq due to reduction of the contact resistance between conductive filler. Additionally, the mechanical strength of nanocomposites polymer were significantly increased as a result of MWCNT addition. Modification of morphological structure of composite film as indicated by FTIR spectra, X-ray diffraction patterns, SEM, and AFM images verified the effective MWCNT filler network in the polymer matrix.

Copyrights © 2018






Journal Info

Abbrev

ijc

Publisher

Subject

Chemical Engineering, Chemistry & Bioengineering Chemistry

Description

Indonesian Journal of Chemistry is an International, peer-reviewed, open access journal that publishes original research articles, review articles, as well as short communication in all areas of chemistry including applied chemistry. The journal is accredited by The Ministry of Research, Technology ...