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INDONESIA
Indonesian Journal of Chemistry
ISSN : 14119420     EISSN : 24601578     DOI : -
Indonesian Journal of Chemistry is an International, peer-reviewed, open access journal that publishes original research articles, review articles, as well as short communication in all areas of chemistry including applied chemistry. The journal is accredited by The Ministry of Research, Technology and Higher Education (RISTEKDIKTI) No : 21/E/KPT/2018 (in First Rank) and indexed in Scopus since 2012. Since 2018 (Volume 18), Indonesian Journal of Chemistry publish four issues (numbers) annually (February, May, August and November).
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Articles 27 Documents
Search results for , issue "Vol 8, No 2 (2008)" : 27 Documents clear
INVESTIGATION OF STABLE ISOTOPE OF 18O AND 2H IN SHALLOW GROUNDWATER FROM KARAWANG AREA E. Ristin Pujiindiyati
Indonesian Journal of Chemistry Vol 8, No 2 (2008)
Publisher : Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (285.228 KB) | DOI: 10.22146/ijc.21614

Abstract

Karawang area is well known as an agriculture area and 2% area is utilized for industries. Clean water demands increase due to developing industry development and population increasement. The origin of groundwater is necessary to keep the sustainability of water resources in this area. Stable isotopes such as 18O and 2H can be used as a parameter to trace the ground water origin. The methods used were Epstein-Mayeda and Zinc reduction for analysis 18O and 2H, respectively. Sampling period was conducted in major dry season in year 2002. The result showed that evaporation effect had influenced to the content of both isotopes in its shallow groundwater that caused a slope shift from its local meteoric line. The origin of its shallow groundwater was from rainwater infiltrating directly in less than 10 m altitude. Citarum River showed more depleted values in both isotopes compared to shallow groundwater and it indicated that its water might originate from spring at the altitude of 600 m.
ACTIVITY TEST OF GUAVA (Psidium guajava L.) LEAF METHANOL EXTRACT AS CONTRACEPTION ANTIFERTILITY TO WHITE MICE (Rattus norvegicus) Sri Retno Dwi Ariani; Endang Susilowati; Elfi Susanti VH; Setiyani Setiyani
Indonesian Journal of Chemistry Vol 8, No 2 (2008)
Publisher : Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (412.846 KB) | DOI: 10.22146/ijc.21632

Abstract

The aim of this research is to know about if the guava (Psidium guajava L.) leaf methanol extract on 10.5 mg/mL and 21.0 mg/mL dossages indicate a positive test as contraception antifertility to white mice (Rattus norvegicus). The sample is guava leaf from Mungkid, Magelang Central of Java Indonesia. The animals experiment are the white mice on 140-300 g for female, 200-250 g for male and about 3 months of age in average. The steps of this research are : (1) preparing  sample, i.e. washing, drying on to indirect sunlight and make the sample into powder, (2) isolation the guava leaf powder in soxhlet instrument with hexane, (3) evaporation the sample with rotary evaporator until guava leaf hexane extract produced, (4) maseration the sample with methanol, (5) evaporation the sample with rotary evaporator until guava leaf methanol extract produced, (6) conducting contraception antifertility activity test to guave leaf methanol extract on 10.5 mg/mL and 21.0 mg/mL dossages to mice white. The results of this research are guava leaf methanol extract on 10.5 mg/mL and 21.0 mg/mL dossages indicate a negative contraception antifertility test to white mice but in these dossages have indicated that an antiimplantation effect (the total natality of fetus is less than the total implantation site in mice white).
TOXIC NORMAL HYDROCARBONS (NHs) IN THE FISH SAMPLES FROM DIFFERENT PARTS OF BANGLADESH M. Amzad Hossain; S. M. Salehuddin
Indonesian Journal of Chemistry Vol 8, No 2 (2008)
Publisher : Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (270.224 KB) | DOI: 10.22146/ijc.21615

Abstract

Toxic normal hydrocarbon (NH), nonadecane in the dichloromethane-hexane crude extract of the flesh of fish samples collected from the different districts of Bangladesh was analyzed by GC-MS/MS. It was observed that NH deposition on the samples takes place in different morphological parts of the biological materials. The NH, nonadecane, was found in the fish samples collected from the roadside by the extraction of dichloromethane-hexane mixture solvents.
ADSORPTION OF Th-232 AND U-238 BY γ- Al2O3-HUMATE AT SINGLE AND COMPETITIVE SYSTEMS Muzakky Muzakky; Sri Juari Santosa
Indonesian Journal of Chemistry Vol 8, No 2 (2008)
Publisher : Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (258.384 KB) | DOI: 10.22146/ijc.21618

Abstract

The calculation experiments of adsorption capacities of Th-232 and U-238 in γ- Al2O3-humate at single system and competitive with Freundlich method has been done. The purpose of the research is (1) to characterize γ- Al2O3-humat functional groups, (2) to know γ- Al2O3-humat solubility and (3) to predict adsorption capacities of U-238 and of Th-232 at adsorbent γ-Al2O3-humate. The characterization of functional groups γ- Al2O3-humate is done by Fourier Transform Infra red (FTIR) Spectrometry. Based on perception results of functional spectra characteristic of γ-Al2O3-humate is similar with humic substance with decrease at stretching -OH at 3400 - 3300 cm-1, and C=O stretching of COOH spectra, C=C aromatic or hydrogen bond of C=O at 1725-1720 cm-1spectra. The solubility testing of γ-Al2O3-humate indicated that the compound it's effective used as adsorption U-238 and of Th-232 at pH 1 to 4 conditions. At single adsorption system with 1000 mg/L of U-238 or Th-232 feed, 0.001 g up to 0.1 g weight of γ-Al2O3-humate were got for U-238 balanced to 992.15 mg/L and 980.66 mg/L for Th-232.  By using regression line curve between ln C and ln x/m, adsorption capacities of U-238 and Th-232 at single system can be calculated as 3.63 mg/g and 2.93 mg/g, respectively, while adsorption capacity of Th-232 was increases to 8.08 mg/g and U-238 decreases to 0.91 mg/g at competitive system.
SYNTHESIS OF MESOPOROUS METHYL-SILICA HYBRID FOR ADSORPTION OF ALIZARIN RED-S Bambang Rusdiarso; Eko Sri Kunarti; Saprini Hamdiani
Indonesian Journal of Chemistry Vol 8, No 2 (2008)
Publisher : Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (336.943 KB) | DOI: 10.22146/ijc.21622

Abstract

Mesoporous methyl-silica hybrid has been synthesized through sol-gel process, by using tetraethylorthosilicate and methyltriethoxysilane as precursors and tartaric acid as a template. The adsorbent was applied to study the adsorption of alizarin red-S. The preparation of methyl-silica hybrid was carried out at various mol ratios of precursors and tartaric acid concentration. The methyl-silica hybrid result was characterized by infrared spectroscopy, X-ray diffraction, and surface area analyzer. Adsorption experiment was conducted to study the effect of pH and Alizarin Red-S concentration on the adsorption capacity of the adsorbent. The adsorbed Alizarin Red-S was calculated from different of Alizarin Red-S concentration before and after adsorption based on the analysis with UV-Vis method. Characterization with Infrared Spectroscopy showed that methyl-silica hybrid has been successfully synthesized as indicated by appearance of characteristic functional group vibrations i.e Si-C, silanol (Si-OH) and siloksan (Si-O-Si). The X-ray diffraction data showed amorphous structure of methyl-silica Hybrid. The Surface Area Analyzer analysis data showed that the pore diameter and surface area of methyl-silica hybrid tended to increase as the template concentration increases. Adsorption study of methyl-silica hybrid showed that the adsorption decreased as the pH was increased. The optimum adsorption was obtained at pH=2.0 with the concentration of Alizarin Red-S of 70 mg/L.
SYNTHESIS OF 4-(4-METHOXY-PHENYL)-3-BUTENE-2-ON AND THE ACTIVITY TEST AS A FRUIT FLIES ATRACTANT Deni Pranowo; Edhi Martono; Suputa Suputa; Muchalal Muchalal; Tutik D. Wahyuningsih; M. Yusuf Afandi
Indonesian Journal of Chemistry Vol 8, No 2 (2008)
Publisher : Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (115.446 KB) | DOI: 10.22146/ijc.21627

Abstract

4-(4-methoxyphenyl)-3-buten-2-on has been synthesized from p-anisaldehyde and acetone via aldol condensation. The reaction was performed at room temperature under basic condition for 12 hours to give brown solid of product (m.p 64-65 oC) in 66.19 % yield. p-anisaldehyde itself was produced from oxidation of anetol major component of anise oil by the use of potassium permanganate as a oxidator. The structure of the products was analyzed by FTIR, 1H NMR and GC-MS. Activity test of 4-(4-methoxyphenyl)-3-buten-2-on as an attractant was carried out in Sleman with methyl eugenol as a reference. The result showed that 4-(4-methoxyphenyl)-3-buten-2-on was inactive compound as a fruit flies attractant and some of fruit flies, i.e. Bactrocera papayae, B. carambolae, B. umbrosa and B. abdolonginqua was found on the test area.
PHENOL OXIDATION USING NATURAL ZEOLITE SUPPORTED METAL ION CATALYST Sri Wardhani; Danar Purwonugroho; Diah Mardiana
Indonesian Journal of Chemistry Vol 8, No 2 (2008)
Publisher : Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (95.926 KB) | DOI: 10.22146/ijc.21636

Abstract

Phenol which contained in waste water has to be reduced and it could be done by oxygen oxidation.  In order to increase the rate of reaction it was needed a catalyst. In this research the capability of various catalysts, namely zeolite-Zn(II), zeolite-Cu(II) and zeolite-Co(II)in oxidation of phenol has been investigated. The aim of this research was to study the type of metal ion catalyst towards the percentage of oxidated phenol. The oxidation process were carried out in an aqueous phenol of 100 ppm with oxygen flow rate of 200 mL/min. in the presence of catalysts with 0.2M of initial impregnation concentration. The capabilities of catalysts were performed by calculating the activation energy and it was done at two different temperatures, i.e. 70 and 90 oC. The percentage of oxidated phenol was determinated by measuring its concentration using UV-VIS spectrophotometer. In addition, the impregnated metal was calculated by measuring the ion concentration remains in the filtrate solution and it was determined using Atomic Absorption Spectrophotometer. The results showed that metal ion types affected the catalytic activity. The order of phenol oxidationactivity decreased as Co(II) > Cu(II) > Zn(II). The surface characteristics of catalysts were supported by pore volume and pore diameter i.e 0.009 cm3/g and 16.59 Å for Zn(II) whereas specific surface area was 10.32 m2/g for Zn(II), 0.004 cm3/g and 24.37 Å for Cu(II) whereas specific surface area was 3.57 m2/g for Cu(II), 0.001 cm3/g and 19.63 Å for Co(II) whereas specific surface area was 10.26m2/g for Co(II).

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