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INDONESIA
Jurnal Energi dan Lingkungan (Enerlink)
Published by Badan Pengkajian dan Penerapan Teknologi
ISSN : 02169541     EISSN : -     DOI : -
Core Subject : Science,
Energy
Enerlink adalah jurnal yang diterbitkan 2 kali setahun oleh Pusat Teknologi Pengembangan Sumberdaya Energi dan Industri Kimia BPPT di bidang energi dan lingkungan. Enerlink is a scientific journal that publishes twice annually by Centre of Energy Technology and Chemical Industry of BPPT.
Arjuna Subject : -
Articles 6 Documents
 1 
Search results for , issue "Vol. 3 No. 2 (2007)" : 6 Documents clear
FUNDAMENTAL STUDY ON LIQUEFACTION OF KALIMANTAN BROWN COALS Hartiniati Hartiniati; Lambok Hlarius Silalahi
Jurnal Energi dan Lingkungan (Enerlink) Vol. 3 No. 2 (2007)
Publisher : Badan Pengkajian dan Penerapan Teknologi

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.29122/elk.v3i2.1543

Abstract

Efek karakateristik batubara terhadap yield produk pencairan batubaradiinvetigasi menggunakan sampel batubara dari Berau (Lati dan Kelai), Mulia,Wara dan Kideco. Batubara Banko dari Tanjung Enim, Sumatera Selatan,digunakan sebagai batubara rujukan. Pengujian pencairandilaksanakanmenggunakan gas-flow type autoclave (5L) dengan umpanbatubara 2002 (daf), pelarut batubara turunan (b.p.300-420oC) 400g, katalis Fe1.0-3.0 wt% (daf), elemen sulfur (rasio atom S/Fe 2.,0) pada tekanan 14.7MPa,suhu 450oC selama 60menit. Sampel limonit dari Soroako Indonesia dan YandiYellow dari Australia, yang terutama terdiri dari α-FeOOH, digunakan sebagaibahan katalis pada pengujian pencairan batubara. Studi ini merekomendasikanbertambahnya minyak yield akibat peningkatan kandungan oksigen dalambatubara, rasio atom H/C dan kandungan besi dalam batubara, mengingat besidalam batubara dapat berfungsi sebagai katalis dalam pencairan batubara.Limonit Soroako medium grade (MGL) menunjukkan aktifitas lebih tinggidibandingkan Yandi Yellow (YY) karena sifat transformasinya membentuk kristalkristalpyrrhotite (Fe1-XS), fase aktif dalam pencairan batubara. Sejumlahsenyawa nitrogen dan sulfur dalam minyak batubara telah berhasil dihilangkanmelalui proses hydrotreatment selanjutnya memperbaiki mutu produk.Keywords: pencairan, batubara berau, limonit, pyrrhotite, soroako,hydrotreatment
PENINGKATAN PEROLEHAN MINYAK EFEK RESIKEL RESIDU PENCAIRAN BATUBARA Muhammad Hanif
Jurnal Energi dan Lingkungan (Enerlink) Vol. 3 No. 2 (2007)
Publisher : Badan Pengkajian dan Penerapan Teknologi

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.29122/elk.v3i2.1544

Abstract

This paper presents the effect of recycle CLB (coal liquid bottom) on oil yieldfrom coal liquefaction process which contains of activated catalyst, organicresidue, and ash from coal. To recover activated catalyst from CLB is notextremely difficult but also very expensive. Therefore one possible way ofutilizing this activated catalyst and remaining convertible organic residue in CLBmore effectively is by recycling the CLB. As a result, the efficiency of coalliquefaction process can be improved significantly. Experiment using 1Lautoclave that's equipped with stirrer is conducted using Banko Coal at operatingtemperature of 450oC, initial hydrogen pressure of 12 MPa, and holding time 60min. Catalyst used in the experiment is medium grade limonite (MGL) fromSoroako with particle size less than 0.8 m and concentration of 3% mafc as Fe.Coal particle size is 200 mesh (74m).The experiment result suggests that CLBaddition can increase the oil yield of coal liquefaction. Recycle (additional) CLB of50 and 70wt% mafc can increase the oil yield from 25,71wt% mafc to 51,83 and65,7wt% mafc respectively.Kata kunci: hidrogenasi, likuifaksi, katalis, limonit, Soroako, pencairan batubara,CLB, daur ulang
KARAKTERISASI SECARA RINCI SENYAWA HETEROATOM DALAM FRAKSI RINGAN MINYAK BATUBARA TANITO HARUM DAN PRODUK MINYAK HASIL HYDROTREATMENT Sri Djangkung Sumbogo Murti; Lambok Hlarius Silalahi
Jurnal Energi dan Lingkungan (Enerlink) Vol. 3 No. 2 (2007)
Publisher : Badan Pengkajian dan Penerapan Teknologi

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.29122/elk.v3i2.1545

Abstract

Heteroatom compounds contained in coal oil Tanito Harum both before and afterhydrotreatment were identified using a gas feed chromatography with atomicemission detector (GC AED). Alkylated dibenzothiophenes benzothiophenes andsulfur compounds were found to be dominant in the original faction, his wholesuccessfully removed through hydrotreatment process on the condition of 350oC,10 MPa, and 60 min. Alkylated anilines, quinoline, indoles, and carbazoles foundin the original oil as nitrogen compounds. Two types of specific nitrogencompounds persist for hydrotreatment process underway and identifiedrespectively as C11H20N and C14H23N, based on the ratio of the element iscalibrated by GC-AED and the molecular weight was measured by GC-MS (massspectrometry). The empirical formula is very similar to such C11H19N andC14H23N, were detected by MS and NMR after concentrated by extraction. Somesulfur compounds present in non-aromatic fraction, while all nitrogen compoundsare completely concentrated in the aromatic fraction after separation byconventional chromatographic columns. There was also alkylated phenols,benzofurans and dibenzofurans were found as typical oxygen compounds in theoil.Kata Kunci: limonite catalyst; coal liquefaction, catalytic hydrotreating, liquefiedcoal oil, gas oil fraction, cetane index, octaen number
ANALISIS KONSUMSI HIDROGEN PADA PENCAIRAN BATUBARA BANKO TENGAH DAN RESIDU KILANG MINYAK BALIKPAPAN Hartiniati Hartiniati
Jurnal Energi dan Lingkungan (Enerlink) Vol. 3 No. 2 (2007)
Publisher : Badan Pengkajian dan Penerapan Teknologi

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.29122/elk.v3i2.1546

Abstract

A series of liquefaction test to understand the effect of initial hydrogen pressureon the yield structure of Banko coal liquefaction under the presence of catalystand short residue solvent was studied. Three sets of initial pressure at 5, 9 and12MPa were tested under liquefaction condition. The test was carried out in CoalLiquefaction Laboratory-BPPT, using 1 liter autoclave at temperature of 450oC forone hour. The results showed that by increasing the initial H2 pressure from5MPa to 9 and 12MPa would improve the distillate yield for about 8-9wt%dafc.This was due to the availability of hydrogen gas provided at 5MPa was smallerthan 9MPa and 12MPa, so that the molecular hydrogen transformed into protonhydrogen and involved in stabilizing decomposed coal structure and shortresidue became larger. It was found that the changes of H2O, CO+CO2 and ofC1~C4 yields were independent to the variable of initial hydrogen pressure. Theseresults possibly confirm that H2O and CO+CO2 yield depend on the raw coalquality input. It was also found that at higher initial pressure (>9MPa), thehydrogen consumption was become less. This may confirm that hydrogen donoravailability of short residue at higher pressure plays a good role in the reaction sothat less amount of hydrogen from the gas is required for the liquefactionreaction.Kata kunci: hydrogen-donor, catalyst, liquefaction yield
KARAKTERISTIK MINYAK PRODUK PENCAIRAN BATUBARA MUDA DARI LATI, KALIMANTAN TIMUR Hartiniati Hartiniati
Jurnal Energi dan Lingkungan (Enerlink) Vol. 3 No. 2 (2007)
Publisher : Badan Pengkajian dan Penerapan Teknologi

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.29122/elk.v3i2.1547

Abstract

Liquefied coal contains of higher aromatic compound, nitrogen, oxygen andsmaller amount of sulfur compared to petroleum fuel oil. These componentscauses gum/sludge formation which disturbs product stability duringtransportation and storage. High aromatic content lowers the cetane number ofliquefied coal oil. The study suggests that the catalytic hydrotreating of liquefiedcoal oil produced from Lati coal liquefaction can reduce the amount of S, O, andN heteroatom significantly. Gas oil fraction derived from Lati coal has a cetaneindex = 38.6, while the octane number of naphtha is expected to be higher than95 through catalytic reforming. In general, it can be concluded that synthetic fueloil derived from Lati coal has the qualification as transportation fuel oil throughthe application of Improved BCL Process.Kata Kunci: limonite catalyst, coal liquefaction, catalytic hydrotreating, liquefiedcoal oil, gas oil fraction, cetane index, octaen number
KOMPARASI REAKTIFITAS PELARUT DARI MINYAK BAKAR DAN RESIDU RANTAI PANJANG PADA PENCAIRAN BATUBARA BANKO Herman Hidayat; Nasikin Nataadmadja
Jurnal Energi dan Lingkungan (Enerlink) Vol. 3 No. 2 (2007)
Publisher : Badan Pengkajian dan Penerapan Teknologi

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.29122/elk.v3i2.1548

Abstract

The needs of fuel, especially for automotive fuel, in Indonesia keeps onincreasing, while petroleum reserves is getting lessen everyday. One alternativeto achieve the diversified energy strategy for the transportation sector is theutilization of the Indonesian low rank coal reserves through the implementation ofcoal liquefaction technology. Coal liquefaction process that has been done beforewas found economically and technically less effective. Those are the reasons fordoing coal liquefaction research using petroleum residue as the solvent, namelyco-processing, which expected to give a better performance than the standardcoal liquefaction. The feedstocks are lignite coal from Central Banko, petroleumresidue (fuel oil and long residue), limonite catalyst from Soroako and hydrogengas. The reactions were carried out in a stirred batch autoclave reactor at 120Kg/cm2 of initial hydrogen pressure and 450oC for 1 hour, at 2 of S/Fe atomicratio and 2 of solvent/coal weight ratio. The liquid products were fractionated byvacuum distillation and the gaseous products were analyzed by gaschromatography. It showed that co-processing with long residue as the solvent isbetter than fuel oil or standard coal liquefaction, with 39.17 wt% daff of oil yiled.The cetane index of middle oil fraction was 27.8 and the efficiency of hydrogenconsumption was 23.68 (oil yield/hydrogen consumption).Kata kunci: pencairan batubara, co-processing, residu minyak bumi, batubaralignit

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