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ASEAN Journal of Chemical Engineering

AJChE
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Published by Universitas Gadjah Mada

ISSN : 26555409 EISSN : 26555409 DOI : https://doi.org/10.22146/ajche.52004

Core Subject : Science, Engineering,

Biochemistry, Genetics & Molecular Biology Chemical Engineering, Chemistry & Bioengineering Chemistry

The ASEAN Journal of Chemical Engineering publishes papers on Chemical Engineering, specifically but not limited to the areas of thermodynamics, reaction kinetics, transport phenomena, process control, environment, energy, biotechnology, corrosion, separation science, powder technology, materials science, and chemical engineering education

Arjuna Subject : Teknik Kimia (semua kategori) - Kimia Proses dan Teknologi

Articles 8 Documents

Search results for , issue "Vol 14, No 2 (2014)" : 8 Documents clear

Stability and Emission Characteristics of Diesel-Ethanol-Coconut Methyl Ester Blends for the Diesel Engines Tanti Ardiyati; Nathaniel P. Dugos; Susan A. Roces; Masaaki Suzuki; Kusnanto Kusnanto
ASEAN Journal of Chemical Engineering Vol 14, No 2 (2014)
Publisher : Department of Chemical Engineering, Universitas Gadjah Mada

The stability and emission characteristics of diesel-ethanol-coconut methyl ester (CME) blends were studied to determine the most suitable fuel blends to be applied in diesel engines. This is done in order to assess the potential of the blends as a substitute for commercially available diesel fuel used in diesel engine. The stability results of the blends using 100% and 99.5% ethanol purity showed that the fuel blends containing ethanol up to 10% and CME of 5% and greater exhibited high mutual solubility at any temperature range and were resistant to microbial growths after 3 months storage. Engine operations at low speed especially at idle-no load and using a bigger size engine lead to a minimum ignition delay and result in lower fuel consumption rate. The emission test results with the new- blended fuels showed a reduction in CO2 and increasing percentage by volume of CO2 compared to commercially available diesel. The blends could deliver an efficient combustion and could run efficiently since production of the CO2 gases is higher than that of CO. The blends of 80% diesel, 5% ethanol, 10% CME; and 80% diesel, 10% ethanol, 10% CME could reduce the smoke opacity compared to commercially available diesel.

Effects of Various Mixed Metal Chlorides- AlCl3 in TiCl4/MgCl2/THF Catalytic System on Ethylene Polymerization Nittaya Sudsong; Wanna Phiwkliang; Bunjerd Jongsomjit; Piyasan Praserthdam
ASEAN Journal of Chemical Engineering Vol 14, No 2 (2014)
Publisher : Department of Chemical Engineering, Universitas Gadjah Mada

In this research, the modification of TiCl4/MgCl2/THF catalyst system with various metal chlorides was investigated on ethylene polymerization. Experimentally, metal chlorides (CaCl2, FeCl2 and ZnCl2) were simultaneously introduced different with TiCl4/MgCl2/THF catalyst. ICP analysis was used to determine the total amount of each metal in the catalyst. For polymerization reaction, TEA was used as cocatalyst and hexane was used as a medium solvent. The Al/Ti molar ratio was 140. The activity result of Ca-Al, Zn-Al and Fe-Al was 979, 1009 and 1476 kgPE/molTi.h, respectively. The coaddition of AlCl3 and FeCl2 in TiCl4/MgCl2/THF catalyst system exhibited the highest activity. It suggested that the co-addition of AlCl3 and FeCl2 has higher electronegativity (EN) and the radius of Fe2+ is closer to Mg2+ resulting in an increased efficiency of the THF removal. This result led to improve the catalyst performance.

Lignin Removal From Aqueous Solution Using Calcium Lactate: The Effect Of Polymers And Magnesium Hydroxide As A Flocculant Aids A. Y. Zahrim; A. Nasimah; S. Rosalam
ASEAN Journal of Chemical Engineering Vol 14, No 2 (2014)
Publisher : Department of Chemical Engineering, Universitas Gadjah Mada

Palm oil mill effluent (POME) which is mainly associated with lignin has becoming a major concern due to its highly coloured appearance. The main colourant, i.e. lignin particles are difficult to be degraded in oil palm conventional biological ponding system. Coagulation/flocculation could remove the lignin prior to biological treatment and is considered vital to minimize the recalcitrance nature of palm oil mill effluent particles. In this study, the coagulation/flocculation process was investigated to remove lignin particles from aqueous solution. A non-toxic and biodegradable chemical i.e. calcium lactate was utilized as a destabilizer for the removal of lignin with an addition of several flocculants aid i.e. anionic polyacrylamide (APAM), polydimethyldiallylammonium chloride (polyDADMAC) and magnesium hydroxide. The effect of coagulant and flocculant aids dosage was investigated. From this study, it was found that the optimum condition was at 0.7g/L of calcium lactate and 0.5-1.0mg/L of APAM with ~64% of lignin removal. At concentration of 4 mg/L, the removal of lignin for APAM and polyDADMAC is similar. This result shows that the calcium lactate has potential as a coagulant and the efficiency can be enhanced with an addition of polymeric flocculant aids.

Performance Enhancement of Mixed Matrix Membranes through the Incorporation of Alkanolamines for CO2/CH4 Separation Rizwan Nasir; Hilmi Mukhtar; Zakaria Man; Maizatul Shima Bt. Shaharun; Mohamad Zailani Abu Bakar
ASEAN Journal of Chemical Engineering Vol 14, No 2 (2014)
Publisher : Department of Chemical Engineering, Universitas Gadjah Mada

Diethanolamine (DEA) solution was used in this study to enhance the performance of polyethersulfone (PES) – carbon molecular sieve (CMS) mixed matrix membrane (MMMs). These new amine mixed matrix membranes (A3Ms) were fabricated at room temperature by using fixed concentration of PES, CMS and different concentrations (5, 10 wt. %) of DEA. The developed mixed matrix membranes were characterized by using field emission scanning electron microscope (FESEM) and thermogravimetric analyser (TGA) in order to investigate the effect of DEA addition on morphology and thermal stability. Gas performance tests were also performed to measure the permeance and selectivity. The characterization results showed that the membranes were thermally stable, dense and non-porous. The gas performance tests showed that the permeance and selectivity of A3Ms is higher than the native PES membrane. CO2 permeance increases with the increase of DEA concentration. Hence it was found that with an addition of 10% (wt. %) DEA at a pressure of 2 bars, the CO2 permeance was increased from 50.86 to 127.06 GPU and the CO2/CH4 selectivity was also increased from 3.08 to 12.30.

A Morphological Study of Poly (Vinylidene Fluoride) Pvdf Membranes: In Perspective of Membrane Pervaporation Process Adil Hatem Rashid; M. D. Irfan Hatem; Muhammad Syarhabil Ahmad; Mohd. Hafiz Dzarfan Othman
ASEAN Journal of Chemical Engineering Vol 14, No 2 (2014)
Publisher : Department of Chemical Engineering, Universitas Gadjah Mada

Membrane separation plays an important role in chemical industry (Prabhat et al. 2011). Pervaporation is one of the most promising membrane separation processes which is used in a wide range of applications such as separation of organic mixtures and dehydration of solvents. This study investigated the effect of polymer concentration on the morphology of pervaporation membrane, where polyvinylidene fluoride (PVDF) was chosen as the base polymeric material while phase inversion method was employed as a technique to prepare an asymmetric PVDF membrane. The polymer concentration in dope solution was varied from 16 to 20wt% and the prepared membranes were characterized in terms of its structure, porosity, contact angle, and pore size. Five PVDF membrane samples were prepared (without any post-treatment) with polymer concentration of 16, 17, 18, 19, and 20wt% respectively. Depending on permeating component, two main areas of pervaporation processes can be identified: hydrophobic and hydrophilic and consequently two types of membranes could be observed: hydrophobic and hydrophilic membranes. From the results, it was found that the increase in polymer concentration has produced membranes with low pore size and porosity and as a result, high contact angle (low hydrophilicity).The highest contact angle of 83º was found for membrane with highest polymer concentration of 20wt% with the lowest pore size and porosity of (0.4156µm and 65%) respectively. The lowest contact angle of 76º was found for membrane with the lowest polymer concentration of 16wt% with the highest pore size and porosity (0.8671µm and78%) respectively.

Synthesis and Performance of Deca- Dodecasil 3 Rhombohedral (DDR)-Type Zeolite Membrane In CO2 Separation– A Review Muhammad Mubashir; Yeong Yin Fong; Lau Kok Keong; Mohd. Azmi Bin Sharrif
ASEAN Journal of Chemical Engineering Vol 14, No 2 (2014)
Publisher : Department of Chemical Engineering, Universitas Gadjah Mada

CO2 capture technologies including absorption, adsorption, and cryogenic distillation are reported. Conventional technologies for CO2 separation from natural gas have several disadvantages including high cost, high maintenance, occupy more space and consume high energy. Thus, membrane technology is introduced to separate CO2 due to their several advantages over conventional separation techniques. Inorganic membranes exhibit high thermal stability, chemical stability, permeability and selectivity for CO2 and CH4 separation as compared to other type of membranes. Zeolite membranes are potential for CO2 separation due to their characteristics such as, well define the pore structure and molecular sieving property. Among the zeolite membranes, DDR membranes exhibit highest selectivity for CO2 and CH4 separation. DDR membranes are synthesized by conventional hydrothermal and secondary growth methods. These methods required very long synthesis duration (25 days) due to extremely low nucleation and crystal growth rate of DDR zeolite. In this review, synthesis and performance of DDR membrane in CO2 separation from CH4 reported by various researchers are discussed. Challenges and upcoming guidelines related to the synthesis DDR membrane and performance of DDR membrane also included.

Microwave – Assisted Extraction of Chlorogenic Acid from Coffee liberica L Josephine Q. Borja; Marylou M Uy; Jose Salvador Lim; Matthew Edson Ong; Alejandro Miguel Ros
ASEAN Journal of Chemical Engineering Vol 14, No 2 (2014)
Publisher : Department of Chemical Engineering, Universitas Gadjah Mada

This study applied microwave-assisted extraction of chlorogenic acid (CGA) from Coffee liberica L. using ethanol as solvent. It sought to determine the effects of temperature, extraction time, solvent-to-solid ratio, and solvent concentration on the CGA yield expressed as gallic acid equivalent per litre (mg GAE L-1). The values of these factors were varied at three levels each and experiments were implemented using the L934 orthogonal array of the Taguchi design of experiment. Results showed that increasing the solvent-to-solid ratio from 2.5 to 7.5 mL g--1decreased the yield significantly. Conversely, increasing the solvent concentration from 0.6 to 0.7 (v v-1) increased the yield, but beyond this, lower yield was obtained. Likewise, yield increased when the extraction time was increased from 5 to 7 minutes but decreased subsequently when extraction was extended to 10 minutes. Temperature did not show significant effect on yield. Among the factors tested the solvent- to-solid ratio has the most significant effect on yield, followed by solvent concentration and extraction time while temperature had no significant effect. In the Taguchi design the highest yield of 304.90±0.58 mg GAE L-1 was obtained at 90°C, extraction time of 7 minutes, solvent-to-solid ratio of 2.5 mL g-1 and solvent concentration of 0.8 (v v-1). Using the same extraction temperature and time and solvent-to-solid ratio but lower solvent concentration, the confirmatory run resulted is significantly higher yield of 854.35±3.35 mg GAE L-1. Chlorogenic acid was identified in the extract at a concentration of 3152 mg L-1. By applying Soxhlet extraction using the same solvent concentration and solvent-to-solid ratio at the same temperature as that of the confirmatory run the yield was significantly lower at 570.42±5.3 mg GAE L-1.

Effects of Retting Media Circulation and Temperature on the Fermentation Process in Soft-Texture and Low Cyanogenic Content Cassava Flour Production M.T.A.P. Kresnowati; Yazid Bindar; Lienda Aliwarga; Dianika Lestari; Nicholaus Prasetya; A. R. Tanujaya
ASEAN Journal of Chemical Engineering Vol 14, No 2 (2014)
Publisher : Department of Chemical Engineering, Universitas Gadjah Mada

A fermentation process to produce soft-texture and low cyanogenic content cassava flour had been studied, in particular the effects of temperature, circulation of the retting media, and scale to the reduction of cyanogenic content and the structure of cassava. Although the effects of retting media circulation and an increase in the fermentation temperature on cyanogenic content reduction were not clearly seen, they led to more damaged cassava structure and thus improving the overall cassava flour production. On the other hand small scale fermentation led to both cyanogenic content reduction and morphological changes, giving better fermentation performance.

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Ari Pramudyantoro

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+62274555320

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Jln. Grafika No. 2 Kampus UGM Yogyakarta Indonesia 55281

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Home Page

OAI Link

Editorial Team

Contact

Reviewer

Google Scholar

Contact Name Ari Pramudyantoro

Contact Email ajche.ft@ugm.ac.id

Phone +62274555320

Journal Mail Official ajche.ft@ugm.ac.id

Editorial Address Jln. Grafika No. 2 Kampus UGM Yogyakarta Indonesia 55281

Location Kab. sleman, Daerah istimewa yogyakarta INDONESIA

Abstract

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Abstract

Contact Name
Ari Pramudyantoro

Contact Email
ajche.ft@ugm.ac.id

Phone
+62274555320

Journal Mail Official
ajche.ft@ugm.ac.id

Editorial Address
Jln. Grafika No. 2 Kampus UGM Yogyakarta Indonesia 55281

Location
Kab. sleman,

Daerah istimewa yogyakarta

INDONESIA