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INDONESIA
Seminar Nasional Teknik Kimia Kejuangan
Published by Universitas Pembangunan Nasional Veteran Yogyakarta
ISSN : -     EISSN : -     DOI : -
Core Subject : Science, Social, Engineering,
Biochemistry, Genetics & Molecular Biology Chemical Engineering, Chemistry & Bioengineering Engineering Environmental Science
Prosiding Seminar Nasional Teknik Kimia Kejuangan adalah media online dari makalah yang telah diseminarkan pada acara Seminar Nasional Teknik Kimia “Kejuangan” (SNTKK). SNTKK merupakan agenda tahunan yang diselenggarakan oleh Program Studi Teknik Kimia FTI UPN ”Veteran” Yogyakarta. Seminar ini merupakan sarana komunikasi bagi para peneliti dari perguruan tinggi, institusi pendidikan, serta lembaga penelitian maupun industri, dalam mengembangkan teknologi kimia untuk pengolahan sumber daya alam Indonesia.
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Articles 76 Documents
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Search results for , issue "2017: PROSIDING SNTKK" : 76 Documents clear
Ekstrak Daun Erpa (Aerva sanguinolenta) sebagai Pewarna Alami pada Kain Batik Febrian Ardi Pramuditya; Ayu Jamilatulhumairah Noor; Tutik Muji Setyaningrum; Siswanti Siswanti
Prosiding Seminar Nasional Teknik Kimia "Kejuangan" 2017: PROSIDING SNTKK
Publisher : Seminar Nasional Teknik Kimia Kejuangan

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Abstract

Until now, the use of natural dyes for coloring textiles continues to increase, so the search for natural dye sources need to be improved. Erpa leaf (Aerva sanguinolenta) contain natural dyes that have the potential to be used as a textile dye. This study aims to determine the optimum extraction conditions Erpa leaves and calculate the mass transfer coefficient will then be applied and tested on the fabric. The parameters studied were extraction temperature, the ratio of leaf with a solvent, application and test on the fabric. extraction is done at 30oC, 40oC, 50oC, 60oC and 70oC. Variations in the use of leaf Erpa was 5, 10, 15, 20 and 25 grams with 350 ml of solvent. The results showed the optimum conditions for the extraction of leaves Erpa at 70 ° C with a ratio of weight and volume 25 g / 350 ml of ethanol with the mass transfer coefficient obtained 25,29 x10- 3 l / min. The effect of sunlight on the durability of the color gets the number 2 and the leaching effect on the durability of the colors got number 3.
Penggunaan Mordan Akhir Terusi terhadap Hasil Celupan Kain Batik dengan Ekstrak Kayu Secang Dwi Suheryanto
Prosiding Seminar Nasional Teknik Kimia "Kejuangan" 2017: PROSIDING SNTKK
Publisher : Seminar Nasional Teknik Kimia Kejuangan

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Abstract

Batik cloth color durability is a prerequisite for improving the competitiveness of the product, as the number of consumer complaints on the subject. How many treatments that can be done to address and improve fastness, is to perform the process of perfecting the end of the fabric that has been dyed using the final mordant materials, namely “terusi” or cupric sulfate (CuSO4) .5H2O. The use of extracts of the wooden cup on a batik cloth, batik cloth produces the erosion resistance value is low, so it is rarely used in the singular in batik dyeing, but mixed with wood extract Cleaner or other materials, but the results did not show its true colors. The purpose of this activity is to improve the quality of batik cloth with increased power results dye color fastness. The materials used, namely cotton fabric primisima, silk fabric T56, wax batik, wood shavings cup, alum, and cupric sulfate, as for the procedure include, extract manufacture wooden cup (1:8), mordant early cotton cloth with alum, batik dyeing with extract solution wooden cup, then made the final refinement using variation cupric sulfate concentration, that is 15 g/l, 20 g/l, and 25 g/l, wax removing, and test color fastness. From the results of the test color fastness to washing, good value at terusi concentration of 25 g / l is 4-5, with a strong color intensity values (the most powerful), the wave had a value of 26 with a length of 0.6637.
Sintesa dan Karakterisasi Biokomposit Poly(L-Lactid Acid)/Cellulose Acetate dan Aplikasinya sebagai Adsorben Bead Nugrahaning Dwi Prastiwi; Eko Vindy Utami; Hikmatun Ni’mah; Eva Oktavia Ningrum
Prosiding Seminar Nasional Teknik Kimia "Kejuangan" 2017: PROSIDING SNTKK
Publisher : Seminar Nasional Teknik Kimia Kejuangan

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Abstract

Biocomposite materials comprised of poly(L-lactic acid) (PLLA) and cellulose acetate (CA) were preparedthrough solvent blending technique. The obtained biocomposite films were characterized by using dynamicmechanical analysis (DMA) and thermogravimetric analysis (TGA). The biocomposites were then applied asadsorbent bead for dye separation. The properties and adsorption performance of the biocomposite beadswere also observed in term of morphology, surface area and adsorption capacity. The composition ofPLLA/CA in weight ratio was varied: 100/0; 75/25; 50/50; 25/75; 0/100. The dye used in this research foradsorption analysis was methylene blue (MB). The MB adsorption was done in two pH conditions which areneutral and base (pH=10) conditions. The mechanical properties of biocomposites PLLA/CA films showedthe slightly decrease in tensile strength after the addition of CA until 50 wt% and then increased again forhigher CA content. However, the young modulus continuously increased with CA content. The elongation atbreak of biocomposite PLLA/CA films showed higher value of elongation at break compared to the pristinePLLA and CA. On the other hand, the thermal stability of biocomposites increased with the increasing of CAcontent compared to that of pristine PLLA. The increase in thermal stability was caused by the specificproperty of CA which is high thermal resistant. For its application, the beads could only be obtained fromthe biocomposite with higher CA composition, PLLA/CA (25/75) and (0/100). The morphology of PLLA/CAbeads showed spherical shape with porous structure on their surface. Adsorption performance measurementshowed that the adsorption capacity and % removal of the PLLA/CA (25/75) bead increase compared to thepure CA bead.
Pengaruh Sudut Masuk Impeller Terhadap Pola Alir Dalam Reaktor Biogas dengan Side Entering Mixer Mochammad Murtadho; Yukh Ihsana; Ni’am Nisbatul Fathonah; Sugeng Winardi; Tantular Nurtono; Kusdianto .
Prosiding Seminar Nasional Teknik Kimia "Kejuangan" 2017: PROSIDING SNTKK
Publisher : Seminar Nasional Teknik Kimia Kejuangan

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Abstract

Side-entering impeller is widely used in the biogas plant. Liquid effluent is processed anaerobically in a hugetank with a relatively small impeller-to-tank diameter ratio.The purpose of this research is to study the sideeffects of entering angle against the flow characteristics in a stirred tank with side-entering mixers (SEM)using flow visualization techniques. This work was conducted on the tank cylinder with a diameter of 40 cmand 40 cm high liquid. Impeller 3-blade propeller which made from stainless steel with 3 and 4 cm indiameter. Variable speed rotary impeller used is 100 to 400 rpm. Side entry angle used are 5 °, 10 °, and 15 °right and left side.Visualization techniques used in this research, specifically focus on the light liquid layervertically and horizontally desired then photographed with a DSLR camera and observation in order tocharacterize the flow pattern. In the type of impeller propeller with an increase in rotational speed, thegeneral layout circulation flow getting to the top is almost half of the liquid level. The changes of side entryangle does not really give much influence over the location of the circulation flow that occurs in the tank.
Perbaikan Mutu Minyak Kelapa Sawit Curah dengan Metode Adsorpsi dalam Tangki Berpengaduk Dena Sukantala Dewi; Ainun Farah Baiqfirlana; Bambang Sugiarto; Zubaidi Achmad
Prosiding Seminar Nasional Teknik Kimia "Kejuangan" 2017: PROSIDING SNTKK
Publisher : Seminar Nasional Teknik Kimia Kejuangan

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Abstract

This research objective is to improve the quality of Crude Palm Oil (CPO). In general, CPO contain free fatty acid known as FFA. CPO purification is necessary to eliminate FFA. In this research, CPO purification conducted by using adsorption method with various adsorbent. The adsorbent has to be activated with NaOH 0,087 N before being used. The variable used are variation of adsorbent (zeolite, bioceramics, and carbon active), adsorbent size (mesh of 20,30, 40,80, 100), and mixing time (10, 20, 30, 40, and 50 minutes). CPO quality can be analyzed by acidic-alkaline method to measure the number of acid, proxyde, saponification, iodine, and water value. The result showed that the optimum condition occurred when using zeolite of 100 mesh and 50 minutes mixing time. Before adsorption, the measurement for number of acid, peroxide, saponification, iodine and water value are respectively 1,9889; 16; 150,0675; 19,6695; and 6,572%. While the measurement result after adsorption are 0,1989 for acid number; 2 for peroxide number; 200,5575 for saponification number; 45,684 for iodine number; and 0,242% for water value. Compare to SNI 01-3741-1995 Standar Mutu Minyak Goreng, the result showed that CPO quality is improved and in line with the SNI requirement.
Karakterisasi Bio-Oil dari Hasil Pirolisis terhadap Biomasa Dewi Selvia Fardhyanti; Astrilia Damayanti; Amalia Larasati
Prosiding Seminar Nasional Teknik Kimia "Kejuangan" 2017: PROSIDING SNTKK
Publisher : Seminar Nasional Teknik Kimia Kejuangan

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Abstract

The utilization of biomass as a source of new and renewable energy is being carried out. One of the technologies to convert biomass as an energy source is pyrolysis which is converting biomass into more valuable products, such as bio-oil. Bio-oil is a liquid which produced by steam condensation process from the pyrolysis of coconut shell. The composition of biomass such as hemicellulose, cellulose and lignin will be oxidized to phenol, alcohol, and acetate acid as the main content of the bio-oil. The experiments typically occurred at the atmospheric pressure in a laboratory furnace at temperatures ranging from 300 to 550oC with a heating rate of 10oC/min and a holding time of 1 hour at the pyrolysis temperature. The Gas Chromatography-Mass Spectroscopy (GC-MS) was used to analyze the bio-oil components. The obtained bio-oil has the viscosity of 1.185 cp (coconut husk), 1.133 cp (coffee husk), 1,094 cp (sawdust); the density of 1.008 g/cm3 (coconut husk), 0.994 g/cm3 (coffee husk), 0.98 g/cm3 (sawdust);the caloric value of 3500kcal/kg (coconut husk),4200 kcal/kg (coffee husk), 1500 kcal/kg (sawdust); and the moisture content of 16% (coconut husk),31% (coffee husk),13% (sawdust). The analysis of GC-MS result showed that the bio-oil from coconut husk contained ethyl ester (37.60%), phenol (40.01%); bio-oil from coffee husk contained acetic acid (26%), phenol (34%); and bio-oil from sawdust contained acetaldehyde (26.15%), acetic acid (20.90%).

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