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Jurnal Riset Kimia
Published by Universitas Andalas
ISSN : 1978628X     EISSN : 24768960     DOI : -
Core Subject : Science,
Chemistry
Arjuna Subject : -
Articles 12 Documents
 1   2 
Search results for , issue "Vol 12, No 2 (2021): September" : 12 Documents clear
Fabrication and Characterization of Chitosan/N-Phthaloyl Composite Membrane for DMFC Application Nugraeni, Christine Dyta; Atmaja, Lukman; Hayati, Nur; Purwanto, Mochammad; Santoso, Mardi; Kusumawati, Yuli
Jurnal Riset Kimia Vol 12, No 2 (2021): September
Publisher : Universitas Andalas

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.25077/jrk.v12i2.408

Abstract

Modified chitosan membrane is one of the promising membranes for polymer electrolyte membrane. Chitosan/N-phthaloyl chitosan composite membranes were fabricated to obtain high proton conductivity and low methanol permeability. Membranes were fabricated by casting method and solvent evaporation. Surface morphology, mechanical analysis, methanol permeability, and proton conductivity were used to characterize the overall properties. FT-IR spectra exhibited the presence of interaction of chitosan and n-phthaloyl/chitosan. SEM analysis showed that the surface roughness of composite membrane increases as the n-phthaloyl loading increases. The highest proton conductivity of synthesized membrane is at 2.4 mS.cm-1 and is higher than pristine chitosan membrane at 1.6 mS.cm-1. Moreover, with n-phthaloyl/chitosan addition, the methanol permeability was also improved. The correlation between proton conductivity and methanol permeability in composite membranes suggests that the blend has its potential in DMFC application.
Production of Starch-Based Bioplastic from Durio zibethinus Murr Seed Using Glycerol as Plasticizer Jannah, Nanda Raudhatil; Jamarun, Novesar; Putri, Yulia Eka
Jurnal Riset Kimia Vol 12, No 2 (2021): September
Publisher : Universitas Andalas

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.25077/jrk.v12i2.398

Abstract

Bioplastics are bio-based plastics from natural resources, made to replace conventional plastics. The utilization of biopolymers in bioplastics provide a faster degradation compared to petroleum-based plastics. Starch-based bioplastic from mixing Durio zibethinus Murr starch and glycerol as plasticizer have been conducted. In this research, the concentration of glycerol has been varied to study the effect on starch-based bioplastics mechanical properties. The tensile strength for Durio zibethinus Murr starch-based bioplastic with 20% glycerol was 50.28 MPa with 13.3% elongation. The functional group found on the Fourier transform infrared spectroscopy (FTIR) spectra indicated the presence of O-H stretch, C-H stretch, C=O stretch, and C-O stretch which stated the formation of bioplastic. The image results gained from scanning electron microscope (SEM) showed that the morphology surface of bioplastic was less homogenous and rough. The soil burial test for biodegradability showed Durio zibethinus Murr starch-based bioplastic achieved 38.9% weight loss in a 5-day observation.

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