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Azhar, Aqil Maulana
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Chemical Engineering, Chemistry & Bioengineering Control & Systems Engineering Energy Engineering Environmental Science

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CHOLINE CHLORIDE BASED NATURAL DEEP EUTECTIC SOLVENTS FOR THE SELECTIVE EXTRACTION OF HESPERIDIN FROM ORANGE PEEL WASTE: A REVIEW Azhar, Aqil Maulana
Jurnal Chemurgy Vol 10, No 1 (2026): Jurnal Chemurgy-Juni 2026
Publisher : Universitas Mulawarman

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.30872/cmg.v10i1.26659

Abstract

Industrial citrus processing generates massive volumes of by-products, including peels and seeds, which are rich sources of the bioactive flavonoid hesperidin. This study utilizes a review of Scopus-retrieved secondary data to evaluate the effectiveness of choline chloride-based natural deep eutectic solvents (NADES) for selective hesperidin recovery. Results indicate that specific NADES formulations can outperform traditional organic solvents in yield, while polyol-based hydrogen bond donors provide superior recovery and long-term stability for hesperidin compared to acidic alternatives. Extraction performance is optimized by managing solvent viscosity and mass transfer through a controlled water content of 20% to 30% (w/w) and temperatures between 50°C and 80°C. Finally, high recyclability and retention rates exceeding 96% over multiple cycles demonstrate the economic and environmental feasibility of these green solvents, supporting the transition toward a sustainable circular bioeconomy.
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