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All Journal TELKOMNIKA (Telecommunication Computing Electronics and Control)
Le Thi Ngoc Tu
Dong Thap University
Computer Science & IT

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Synthesis of reduced graphene oxide decotate Cu2S nanoparticles for cathode of quantum dot solar cell Le Doan Duy; Le Thi Ngoc Tu; Le Tien Dat
TELKOMNIKA (Telecommunication Computing Electronics and Control) Vol 22, No 1: February 2024
Publisher : Universitas Ahmad Dahlan

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.12928/telkomnika.v22i1.25238

Abstract

In this paper, the results of making a reduced graphene oxide cathode electrode with Cu2S nanoparticles are shown so that it can be used as a counter electrode in quantum dot solar cells to replace other counter electrodes. An rGO-Cu2S paste obtained by hydrolysis was scanned onto the surface of the fluorine-doped tin oxide (FTO) conductive substrate when bound to Cu2S nano by a screen-printing process, then calcined at 350 °C to crystallize the film. Following calcination, the film was examined for structure using energy-dispersive X-ray (EDX) and X-ray diffraction (XRD) spectroscopy, as well as for type and particle size using scanning and transmission electron microscopy and transmission electron microscopy, respectively. Mott-schottky measurement is used to determine the semiconductor and carrier concentrations in the film, and an electrochemical device is used to assess the electrodes redox capacity in a polysulfide electrolyte solution. The operability of the rGO-Cu2S cathode at the peak of the current density in the C-V curve was 24 mA/cm2, a 30-fold increase compared to that of the Cu2S electrode. This result shows that the efficiency, Voc, FF, Jsc are 4.92%, 0.525 V, 0.418, and 22.4 mA/cm2, respectively.
Impact of CuS counter electrode calcination temperature on quantum dot sensitized solar cell performance Le Thi Ngoc Tu; Ha Thanh Tung
TELKOMNIKA (Telecommunication Computing Electronics and Control) Vol 21, No 5: October 2023
Publisher : Universitas Ahmad Dahlan

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.12928/telkomnika.v21i5.25118

Abstract

In place of the commercial Pt electrode used in quantum sensitized solar cells, the low-cost CuS cathode is created using electrophoresis. High resolution scanning electron microscopy and X-ray diffraction were used to analyze the structure and morphology of structural cubic samples with diameters ranging from 40 nm to 200 nm. The conversion efficiency of solar cells is significantly impacted by the calcination temperatures of cathodes at 100 °C, 120 °C, 150 °C, and 180 °C under vacuum. The fluorine doped tin oxide (FTO)/CuS cathode electrode reached a maximum efficiency of 3.89% when it was calcined at 120 °C. Compared to other temperature combinations, CuS nanoparticles crystallize at 120 °C, which lowers resistance while increasing electron lifetime. In place of the commercial Pt electrode used in quantum sensitized solar cells, the low-cost CuS cathode is created using electrophoresis. High resolution scanning electron microscopy and X-ray diffraction were used to analyze the structure and morphology of structural cubic samples with diameters ranging from 40 nm to 200 nm. The conversion efficiency of solar cells is significantly impacted by the calcination temperatures of cathodes at 100 °C, 120 °C, 150 °C, and 180 °C under vacuum. The fluorine doped tin oxide (FTO)/CuS cathode electrode reached a maximum efficiency of 3.89% when it was calcined at 120 °C. Compared to other temperature combinations, CuS nanoparticles crystallize at 120 °C, which lowers resistance while increasing electron lifetime.
Co-Authors Ha Thanh Tung Le Doan Duy Le Tien Dat