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Conversion of waste polypropilene (pp) using the zeolite Ni/ZSM-5 to liquid fuel Thahir, Ramli; Kusuma, Imam Fatwa; Aprilia, Nursyam; Alam, Ahmad Noor; Halim, Abd; Alwathan, Alwathan; Marlinda, Marlinda; Kurniawan, Andri; Puspasari, Febriyati; Rahman, Abdul; Irwan, Muh
Konversi Vol 12, No 2 (2023): OKTOBER 2023
Publisher : Universitas Lambung Mangkurat

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.20527/k.v12i2.15972

Abstract

Fuel oil from plastic waste is a promising alternative fuel because of its carbon chaincharacteristics and physical properties which is similar to the crude oil. In addition, the demand for plastic is still increasing which eventually becomes plastic waste. The aim of this study was to determine the quality and application of liqui0d oil produced by pyrolysis catalytic cracking assisted Ni/ZSM-5 from polypropylene (PP) plastic waste. The obtained products were liquid, gas, and char. The optimal yield of fuel oil at 390oC was 239 ml of fuel oil/250 g of PP with a conversion of 79.20 %,wt (72%, liquid and 7.20% gas) and the remaining product was char. The characteristics of the fuel oil products are in the range of gasoline and kerosene fuel types. The average yield value of oAPI in the range of 51-42 for kerosene-type fuel in trays 1 and 2. Furthermore, gasoline-type fuel was resulted in trays 3 and 4 with oAPI value in the range of 52-63.
Synthesis of Fe3O4/Hydroxyapatite Nanocomposites: Structural, Surface, and Magnetic Characterization Fadli, Ahmad; Prabowo, Agung; Drastinawati, Drastinawati; Wandika Putra, Bima; Sugesti, Heni; Puspasari, Febriyati
Indonesian Journal of Chemistry Vol 26, No 2 (2026)
Publisher : Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.22146/ijc.107697

Abstract

Magnetite/hydroxyapatite (Fe3O4/HA) nanocomposites are promising materials for biomedical applications, particularly in targeted drug delivery. This study investigates the effects of hydrothermal reaction time and FeCl3 precursor concentration on the structural, morphological, and magnetic properties of Fe3O4/HA composite powders synthesized via a one-pot hydrothermal method. The resulting composites exhibit biphasic structures comprising magnetite (cubic phase) and hydroxyapatite (hexagonal phase) crystallites, with average sizes ranging from 22 to 30 nm. Both increased reaction time and FeCl3 concentration contributed to the growth of crystal size. A notable enhancement in specific surface area was observed, increasing from 48.21 to 67.41 m2/g as FeCl3 concentration decreased from 0.15 to 0.05 M at a fixed reaction time of 15 h. Magnetic characterization revealed that the composites exhibited superparamagnetic behavior, with the highest saturation magnetization (Ms) reaching 17.27 emu/g. These results demonstrate that tuning synthesis parameters can optimize the structural and magnetic properties of Fe3O4/HA nanocomposites, making them strong candidates for use in controlled drug delivery systems.