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All Journal Jurnal Teknik Kimia USU Warta Perkaretan Jurnal Teknik Kimia USU Jurnal Teknologi Kimia Mineral
Agustian, Mertza Fitra
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Agriculture, Biological Sciences & Forestry Biochemistry, Genetics & Molecular Biology Chemical Engineering, Chemistry & Bioengineering Chemistry Engineering Environmental Science Industrial & Manufacturing Engineering Materials Science & Nanotechnology

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PENGARUH PAPARAN MICROWAVE TERHADAP DERAJAT IKATAN SILANG PADA VULKANISASI KARET STIRENA BUTADIENA Saputra, Andri; Rahmawati, Atiqa; Arifin, Uma Fadzilia; Agustian, Mertza Fitra
Warta Perkaretan Vol. 43 No. 1 (2024): Volume 43, Nomor 1, Tahun 2024
Publisher : Pusat Penelitian Karet - PT. Riset Perkebunan Nusantara

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.22302/ppk.wp.v43i1.978

Abstract

Vulkanisasi karet diperlukan untuk meningkatkan sifat kekuatan dan elastisitas suatu produk karet. Selain mempersingkat waktu proses, kelebihan vulkanisasi menggunakan radiasi elektromagnetik dari microwave adalah panas yang seragam yang tidak tergantung pada ketebalan produk. Penelitian ini bertujuan mengetahui karakteristik vulkanisasi karet stirena butadiena pada berbagai waktu paparan radiasi microwave. Kompon karet stirena butadiena dimasukkan dalam microwave dan diberi paparan radiasi elektromagnetik menggunakan daya 5 W pada berbagai waktu (10, 30, 50, 60, dan 70 menit). Derajat ikatan silang vulkanisat diuji menggunakan metode Flory-Rehner. Hasil penelitian diketahui bahwa tahap induksi vulkanisasi karet stirena butadiena pada daya 100 W membutuhkan durasi paparan yang lama sekitar 50 menit dengan derajat ikatan silang sebesar 0,52x10-8 mol/cm3. Tren hasil menunjukkan bahwa lama paparan radiasi berbanding lurus dengan nilai derajat ikatan silang karet stirena butadiene. Derajat ikatan silang karet stirena butadiene pada waktu 50, 60, dan 70 menit secara berurutan adalah 0,52x10-8 mol/cm3, 4,65x10-8 mol/cm3, dan 29,41x10-8 mol/cm3. Paparan radiasi elektromagnetik dari microwave di atas menit ke-70 diperkirakan masih dapat menyebabkan terbentuknya ikatan silang antar karet stirena butadiene hingga titik maksimum pada menit tertentu.
Pengaruh Urutan Pencampuran Pemlastis pada Komponding Karet Terhadap Kinetika Vulkanisasi Menggunakan Model Deng-Isayev dan Kamal-Sorour Saputra, Andri; Agustian, Mertza Fitra
Jurnal Teknik Kimia USU Vol. 13 No. 2 (2024): Jurnal Teknik Kimia USU
Publisher : Talenta Publisher (Universitas Sumatera Utara)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.32734/jtk.v13i2.15550

Abstract

Plasticizers play an important role in the rubber industry to facilitate the dispersion of additives into rubber. This research aims to study the effect of plasticizer mixing sequence on vulcanization kinetics. This relates to its effect on printing time and energy, as well as the cost of electricity used. Compound A was made by adding plasticizer at the mastication stage and compound B was made by adding plasticizer at the masterbatch stage. Kinetic parameters were determined using Deng-Isayev and Kamal-Sorour models. The results show that the Deng-Isayev model is closer to the experimental data than the Kamal-Sorour model. Compound A has a k value (3.0635x10-6 sec-1) and cure index (0.8403) slightly lower than compound B with a k value 3.3511x10-6 sec-1 and cure index 0.9260. However, the mixing order of the plasticizers did not significantly affect the vulcanization performance, either the reaction speed constant, reaction order, induction time, optimal vulcanization time, and cure index.
Pengaruh Urutan Pencampuran Pemlastis pada Komponding Karet Terhadap Kinetika Vulkanisasi Menggunakan Model Deng-Isayev dan Kamal-Sorour Saputra, Andri; Agustian, Mertza Fitra
Jurnal Teknik Kimia USU Vol. 13 No. 2 (2024): Jurnal Teknik Kimia USU
Publisher : Talenta Publisher (Universitas Sumatera Utara)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.32734/jtk.v13i2.15550

Abstract

Plasticizers play an important role in the rubber industry to facilitate the dispersion of additives into rubber. This research aims to study the effect of plasticizer mixing sequence on vulcanization kinetics. This relates to its effect on printing time and energy, as well as the cost of electricity used. Compound A was made by adding plasticizer at the mastication stage and compound B was made by adding plasticizer at the masterbatch stage. Kinetic parameters were determined using Deng-Isayev and Kamal-Sorour models. The results show that the Deng-Isayev model is closer to the experimental data than the Kamal-Sorour model. Compound A has a k value (3.0635x10-6 sec-1) and cure index (0.8403) slightly lower than compound B with a k value 3.3511x10-6 sec-1 and cure index 0.9260. However, the mixing order of the plasticizers did not significantly affect the vulcanization performance, either the reaction speed constant, reaction order, induction time, optimal vulcanization time, and cure index.
KINETIKA VULKANISASI KARET MENGGUNAKAN BIOPLASTICIZER MINYAK KAKAO TEREPOKSI Satwikanitya, Pani; Saputra, Andri; Sya’bani, Muh Wahyu; Agustian, Mertza Fitra
JURNAL TEKNOLOGI KIMIA MINERAL Vol 2 No 1 (2023): JURNAL TEKNOLOGI KIMIA MINERAL
Publisher : Politeknik ATI Makassaar

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (458.135 KB) | DOI: 10.61844/jtkm.v2i1.460

Abstract

Kinetika vulkanisasi karet menggunakan bioplasticizer minyak kakao terepoksi dipelajari berdasarkan data output moving die rheometer. Data percobaan didekati dengan beberapa model kinetika, yaitu model reaksi orde 1, orde 2, dan Deng-Isayev. Konstanta laju reaksi (k) pada model reaksi orde 1 dan orde 2 dihitung dari data torsi yang merupakan fungsi waktu (M = f(t)). Sedangkan pada model Deng-Isayev, nilai k dan orde reaksi (n) ditentukan menggunakan optimasi multivariable dengan tools Solver pada aplikasi Excel. Nilai energi aktivasi (Ea) diperoleh dari persamaan Arrhenius. Hasil penelitian memperlihatkan model Deng-Isayev dapat merepresentasikan data percobaan dengan baik. Konstanta laju reaksi sebanding dengan kenaikan suhu vulkanisasi. Reaksi vulkanisasi karet menggunakan minyak kakao terepoksi berlangsung pada orde (n) 3 dengan energi aktivasi (Ea) sebesar 157,55 kJ/mol.
Co-Authors Muh. Wahyu Syabani Rahmawati, Atiqa RR. Ella Evrita Hestiandari Satwikanitya, Pani Uma Fadzilia Arifin, Uma Fadzilia