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All Journal CHEMICA Jurnal Teknik Kimia Journal of Natural Sciences and Mathematics Research Jurnal Sains & Teknologi Lingkungan Indonesian Journal of Chemical Analysis (IJCA) REACTOR : Journal of Research On Chemistry And Engineering Jurnal Rekayasa Proses JURNAL REKAYASA KIMIA & LINGKUNGAN
Teguh, Dedi
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Agriculture, Biological Sciences & Forestry Biochemistry, Genetics & Molecular Biology Chemical Engineering, Chemistry & Bioengineering Chemistry Computer Science & IT Education Energy Engineering Environmental Science Materials Science & Nanotechnology Physics

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Advanced oxidation processes technology using the Fenton method in Bakung landfill leachate treatment Teguh, Dedi; Cendekia, Devy; Wulandari, Yeni Ria; Putri, Cynthia Eka; Ramandani, Adityas Agung
Journal of Natural Sciences and Mathematics Research Vol. 10 No. 2 (2024): December
Publisher : Faculty of Science and Technology, Universitas Islam Negeri Walisongo Semarang

Show Abstract | Download Original | Original Source | Check in Google Scholar

Abstract

The primary issue at the Bakung final processing location was the high organic and inorganic material concentration. Toxicity, high chemical oxygen demand (COD), a black hue, and an unpleasant smell can usually identify landfill leachate; it can be hazardous if spilled directly into a body of water. Consequently, the implementation of an efficient leachate treatment was necessary. One use of this cutting-edge oxidation process technology consists of the Fenton method for treating leachate. The goals of this study involve implementing the Fenton technique to leachate treatment and ascertaining the impact of reaction time (30, 60, 90, or 120 min) and Fenton molar ratio (1:150, 1:200, or 1:250) on color degradation and chemical oxygen demand (COD). A Fenton molar ratio of 1:150 and a 120-min reaction period were ideal, resulting in maximum color and COD degradation percentages of 91.4% and 92.4%, respectively. The study's findings demonstrate how well the Fenton approach works to reduce COD and color in leachate while also meeting leachate water quality requirements for enterprises and/or ultimate waste processing operations.
Efektivitas Metode Fenton-TiO2-UV Terhadap Degradasi Warna dan Chemical Oxygen Demand Pada Pengolahan Palm Oil Mill Effluent Teguh, Dedi; Hanifah, Windia; Cendekia, Devy; Phelia, Arlina; Sari, Nita Pita; Adib, Asraf Wa
REACTOR: Journal of Research on Chemistry and Engineering Vol 5, No 2: December 2024
Publisher : Politeknik ATI Padang

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.52759/reactor.v5i2.160

Abstract

The palm oil industry produces POME (Palm Oil Mill Effluent) liquid waste. POME is generally brownish, has an odor, and contains dissolved and suspended solids in the form of colloids and oil residue with a high Chemical Oxygen Demand (COD) content. Currently, the POME processing system still uses a conventional system known as the open pond system. This research aims to reduce the burden of organic materials related to removing COD levels, and color. It can solve the technical and operational obstacles of conventional processing systems. One of the extensive efforts to process POME is to develop Fenton-based photocatalytic technology, namely the Fenton-TiO2-UV method. Photocatalytic technology has several general processes involving semiconductor photocatalysts such as TiO2 and photon (UV) energy sources. In this study, the Fenton-TiO2-UV method was used with variations in the Fenton molar ratio of 1:100, 1:200, 1:300 (v/v), reaction times of 30, 60, and 90 minutes with TiO2 concentration 0.6% and uses 2 UV lamps (15 watts). This study achieved the maximum color degradation percentage at a Fenton molar ratio of 1:100 with a reaction time of 30 minutes, namely 95.28%. Meanwhile, the maximum COD degradation percentage was achieved at a Fenton molar ratio of 1:100 with a reaction time of 90 minutes, namely 98.88%.
The Optimization Ratio and Size of Raw Materials in Patchouli Oil Extraction Process Using Hydrodistillation Method with Addition of MgCl2 Afifah, Dian Ayu; Cendekia, Devy; Teguh, Dedi
Indonesian Journal of Chemical Analysis (IJCA) Vol. 7 No. 2 (2024): Indonesian Journal of Chemical Analysis
Publisher : Universitas Islam Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.20885/ijca.vol7.iss2.art7

Abstract

This research focuses on optimizing patchouli oil yield using the hydrodistillation method and adding MgCl2 as the main component. The RSM method is used to analyze model variance, including the sum of squares model, less of the fit model, and ANOVA analysis. The research results show that adding MgCl2 can increase the yield of patchouli oil by reducing water content and undesirable non-volatile elements, thereby producing more stable patchouli oil. ANOVA analysis of patchouli oil yield was carried out to determine the optimal results from factors such as F/S, material size, and time. The extraction time factor had a p-value of less than 0.05, indicating that the model was suitable for explaining the results. The research results showed that the yield of patchouli oil was optimal with an F/S ratio of 0.075, material size of 20 mesh, and extraction time of 5 hours, with a yield of 0.1 gr/mL being the best choice. The research results showed that the use of specific methods, namely distilled water and MgCl2 in the extraction process, was effective in increasing the yield of patchouli oil
Synergistic ultrasonic-microwave assisted extraction (UMAE) for enhanced fat extraction from nutmeg seeds Afifah, Meita; Teguh, Dedi; Shintawati; Ramandani, Adityas Agung
Jurnal Rekayasa Proses Vol 19 No 1 (2025): Volume 19, Number 1, 2025
Publisher : Jurnal Rekayasa Proses

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.22146/jrekpros.16283

Abstract

Nutmeg seeds contain essential oils and fats, are widely used in the cosmetic and pharmaceutical industries. This research aims to determine the yield, physicochemical characteristics and fat composition of nutmeg seeds extracted from Ultrasonic-Microwave Extraction (UMAE). The research used a factorial completely randomized design (CRD) method with the independent variables, length of extraction time (45, 90, 135 minutes) and microwave power (300 and 450 watts). The dependent variables in this research are yield, melting point, specific gravity, acid number and saponification number. The results showed that the highest fat yield of nutmeg was 30.48% at 300 Watts and 135 minutes. The physicochemical characteristic of nutmeg fat was yellow with specific gravity, melting point, acid number and saponification number were 0.96, 52.4 °C, 16.69 mg KOH/g fat and 254.96 mg KOH/gram fat. GCMS results show that the fat composition is trichloromethyl, isopropyl phosphoranidothioic acid and lauric acid triglyceride which have potential as cosmetic raw materials.
Advanced oxidation processes technology using the Fenton method in Bakung landfill leachate treatment Teguh, Dedi; Cendekia, Devy; Wulandari, Yeni Ria; Putri, Cynthia Eka; Ramandani, Adityas Agung
Journal of Natural Sciences and Mathematics Research Vol. 10 No. 2 (2024): December
Publisher : Faculty of Science and Technology, Universitas Islam Negeri Walisongo Semarang

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.21580/jnsmr.v10i2.20987

Abstract

The primary issue at the Bakung final processing location was the high organic and inorganic material concentration. Toxicity, high chemical oxygen demand (COD), a black hue, and an unpleasant smell can usually identify landfill leachate; it can be hazardous if spilled directly into a body of water. Consequently, the implementation of an efficient leachate treatment was necessary. One use of this cutting-edge oxidation process technology consists of the Fenton method for treating leachate. The goals of this study involve implementing the Fenton technique to leachate treatment and ascertaining the impact of reaction time (30, 60, 90, or 120 min) and Fenton molar ratio (1:150, 1:200, or 1:250) on color degradation and chemical oxygen demand (COD). A Fenton molar ratio of 1:150 and a 120-min reaction period were ideal, resulting in maximum color and COD degradation percentages of 91.4% and 92.4%, respectively. The study's findings demonstrate how well the Fenton approach works to reduce COD and color in leachate while also meeting leachate water quality requirements for enterprises and/or ultimate waste processing operations.
Degradasi Warna dan COD pada Pengolahan Air Lindi TPA Bakung dengan Metode Fenton Teguh, Dedi; Cendekia, Devy; Sari, Nita Pita; Putri, Cynthia Eka
Jurnal Sains dan Teknologi Lingkungan Vol. 16 No. 2 (2024): SAINS & TEKNOLOGI LINGKUNGAN
Publisher : Teknik Lingkungan Universitas Islam Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.20885/jstl.vol16.iss2.art5

Abstract

The main problem in the Bakung final processing place is the infiltration of leachate with high concentrations of organic and inorganic substances. Leachate from landfills is usually characterized by a foul odor, a black color, high COD values, and toxicity. This is very dangerous if it is directly flown into the ground or water body because it can pollute the environment. Therefore, it is necessary to carry out effective leachate treatment. One way to treat leachate is using Fenton method, which is a development of  advanced oxidation processes technology. The objectives of this research are to treat leachate using the Fenton method and determine the effect of the Fenton molar ratio (1:150, 1:200, 1:250) and reaction time (30, 60, 90, 120 minutes) on color and COD degradation. Optimum conditions were achieved at a Fenton molar ratio of 1:150 and a reaction time of 120 minutes, with maximum color and COD degradation percentages of 91.4% and 92.4%, respectively. The results of this research show that the Fenton method is very effective on color and COD degradation in leachate and has met the leachate water quality standards for businesses and/or final waste processing activities.
Pengolahan Limbah Logam Berat Kromium Hexavalen Menggunakan Reagen Fenton dan Adsorben Keramik Zeolit Agustina, Tuty Emilia; Faizal, Muhammad; Aprianti, Tine; Teguh, Dedi; Rif'at, Aditya M; Putra, Imam Gunawan; Prayesi, Mutiara Rizki; Fitrializa, Ulfa
Jurnal Rekayasa Kimia & Lingkungan Vol 13, No 1 (2018): Jurnal Rekayasa Kimia & Lingkungan (June, 2018)
Publisher : Chemical Engineering Department, Syiah Kuala University, Banda Aceh, Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.23955/rkl.v13i1.10109

Abstract

Kromium diketahui sebagai salah satu polutan beracun yang menyebabkan masalah lingkungan dan kesehatan masyarakat. Kromium Heksavalen Cr(VI) merupakan logam berat, dimana dalam konsentrasi yang kecil dapat menghasilkan tingkat keracunan yang tinggi pada makhluk hidup. Jika senyawa kromium (VI) terbuang ke lingkungan dan masuk ke dalam tubuh makhluk hidup maka akan sangat berbahaya, sehingga penting untuk mengolah limbah tersebut. Penelitian ini difokuskan pada proses pengolahan Cr(VI) dengan metode kombinasi yaitu secara kimia dan secara fisika. Penelitian ini bertujuan untuk mengolah air limbah yang mengandung Cr(VI) menggunakan reagen Fenton yang dilanjutkan adsorpsi menggunakan adsorben berbahan dasar zeolit dan tanah liat yang dibentuk menjadi keramik. Air limbah yang mengandung Cr(VI) dikontakkan dalam reaktor berpengaduk sehingga terjadi reaksi reduksi oksidasi, selanjutnya air limbah ini dilewatkan ke dalam kolom adsorpsi yang berisi adsorben keramik zeolit. Kondisi terbaik dari pengolahan air limbah yang mengandung Cr(VI) dengan metode kombinasi ini dicapai pada konsentrasi limbah krom 200 ppm, rasio molar reagen Fenton 1:30, dan pH 6. Dimana persentase maksimum penurunan Cr(VI) dengan proses Fenton sebesar 30,15% dan dilanjutkan dengan adsorpsi sehingga penurunan Cr(VI) total mencapai 99,99%. Hal ini menunjukkan bahwa pengolahan limbah logam berat kromium dengan menggunakan reagen Fenton dilanjutkan adsorpsi menggunakan adsorben keramik zeolit mampu menurunkan kadar Cr(VI) pada limbah cair mencapai 0,0033 ppm dari baku mutu yaitu 0,1 ppm, sehingga hasil penelitian ini telah memenuhi baku mutu lingkungan
Utilization of Bamboo Waste by Engineering Acid Hydrolysis (H2SO4) to Produce Furfural Compounds Fitri, Nur Hidayatul; Ramandani, Adityas Agung; Cendekia, Devy; Teguh, Dedi
CHEMICA: Jurnal Teknik Kimia Vol. 10 No. 2 (2023): August 2023 [Available online since October 02, 2023]
Publisher : Universitas Ahmad Dahlan

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.26555/chemica.v10i2.26609

Abstract

Bamboo waste containing lignocellulosic can be used as a material for forming furfural compounds. Furfural is an intermediate product that is widely needed by the chemical industry in the manufacture of finished products such as resins, disinfectants, lubricating oils, synthetic rubber, and so on. This product can be produced from materials containing pentosan. The purpose of this study was to determine the effect of the delignification process on pentosan levels,yield and characterization of the resulting furfural, as well as the potential of pentosan to become furfural compounds. In this study the formation of furfural from bamboo waste was carried out using the acid hydrolysis method, with the independent variables namely cooking temperatures of 90 oC, 100 oC and 110 oC, H2SO4 concentrations of 5%, 10% and 15% and cooking times of 60 minutes, 90 minutes , and 120 minutes. Based on the results of research that has been done, it is known that the delignification process has an influence on the pentosan level, where the sample without delignification obtained a pentosan level of 11.10% and using the delignification process obtained a pentosan level of 14.67%. Characterization of furfural analysis results by color test showed a change in color to red and based on the results of GC-MS analysis at retention time 24.
Co-Authors Adib, Asraf Wa Afifah, Dian Ayu Afifah, Meita Aprianti, Tine Cendekia, Devy Fitri, Nur Hidayatul Fitrializa, Ulfa Hanifah, Windia Muhammad Faizal Phelia, Arlina Prayesi, Mutiara Rizki Putra, Imam Gunawan Putri, Cynthia Eka Ramandani, Adityas Agung Rif'at, Aditya M Sari, Nita Pita Shintawati Tuty Emilia Agustina Wulandari, Yeni Ria