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PEMBUATAN DAN KARAKTERISASI KATALIS ZEOLIT ZSM-5 UNTUK KONVERSI BIOETANOL MENJADI BIOETILENA Nurdin, Ali; Saputra, Hens; Arfiana, Arfiana; Yunilawati, Retno; Finalis, Era Restu
Majalah Ilmiah Pengkajian Industri Vol 12, No 2 (2018): Majalah Ilmiah Pengkajian Industri
Publisher : BPPT

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (679.284 KB) | DOI: 10.29122/mipi.v12i2.2741

Abstract

Etilen sebagai produk petrokimia yang penting dapat dibuat dari bioetanol menggunakan katalis ZSM5. Zeolit sintetis ZSM5 dapat dibuat menggunakan zeolit alam yang banyak tersedia di Indonesia. Proses pembuatan ZSM5 menggunakan metode hidrotermal pada temperatur 180°C selama 24 jam. Sebagai agen pengarah terbentuknya struktur ZSM-5 tersebut digunakan template TPABr (Tetra Prophyl Ammonium Bromide). Kalsinasi produk ZSM5 dilakukan pada temperatur 600°C selama 1 jam. Karakterisasi ZSM-5 yang dilakukan antara lain analisis struktur dan kristalinitas, observasi morfologi permukaan menggunakan metode Difraksi Sinar X, Scanning Electron Microscopy, dan physisorption untuk mempelajari sifat pori. Hasil penelitian menunjukkan bahwa dihasilkannya ZSM-5 dengan kristalinitas sekitar 110 %. Kristal ZSM-5 yang dihasilkan berbentuk kubus dengan luas permukaan spesifik BET 300 m2/g, volume pori sekitar 0,13 Cm3/g. Distribusi ukuran pori yang sempit mengindikasikan ukuran pori yang seragam dengan ukuran rata-rata 0.55 nm.
DESIGN OF BIOGAS COOLING PROCESSING FROM POME FOR (CSTR) CONTINUOUS STIRRED TANK REACTOR SYSTEM tjahjono, endro wahju; Arfiana, Arfiana; Finalis, Era Restu; Nurdin, Ali
Majalah Ilmiah Pengkajian Industri Vol. 14 No. 2 (2020): Majalah Ilmiah Pengkajian Industri
Publisher : Deputi TIRBR-BPPT

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.29122/mipi.v14i2.3856

Abstract

POME (Palm Oil Mill Effluent) can be used as for biogas production, with the main content of (65%) methane gas (CH4) and 35% Carbon Dioxide (CO2), H2S, and H2O gases. Apart from being a gas fuel and a source of electricity generation, biogas from POME waste as well as a waste processor becomes more environmentally friendly (according to quality standards). In order to support the process production of biogas from POME by using Continuous Stirred Tank Reactors (CSTR), it is necessary to decrease POME’s temperature to meet the requirements of the reactor operating conditions. Cooling process by using a Cooling Tower through direct contact between fluids can be a good alternative to be used as a POME cooling method because of its effectiveness in heat exchange and smaller area needed than an open ponds. The type of cooling tower used is the Induced Draft Cooling Tower. In cooling tower design, the steps involved in determining the basic design, calculation of tower dimensions, basin, fan power, losses, and cooling air requirements. Based on the calculation, the tower dimensions determine a height of 5 m, length of 3.6 m, and width of 2.5 m, while the basin cooling tower dimensions determine a height of 2.7 m, length of 3.6 m, and width of 2.5 m, fan power of 5 hp. The cooling air requirement for the POME cooling process is 82,895.14 kg/hour. Keywords : POME; Cooling Tower; CSTR; Fuel; Biogas
Development of Carbon Based NPK Slow Release Fertilizer using Biochar from Oil Palm Empty Fruits Bunch Finalis, Era Restu; Sri Djangkung, Sumbogo Murti; Arfiana; Noor, Ilhamsyah; Suratno, Hadi; Rosyadi, Erlan; Saputra, Hens; Noda, Reiji
Indonesian Journal of Energy Vol. 3 No. 1 (2020): Indonesian Journal of Energy
Publisher : Purnomo Yusgiantoro Center

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.33116/ije.v3i1.45

Abstract

Biochar is a solid material produced by thermochemical conversion of biomass under oxygen-limited conditions. It has a wide surface and contains many pores so that it can be used as a material for making fertilizer. Biochar based slow release NPK fertilizer was formulated and developed to reduce nutrient leaching and greenhouse gas emissions. In this research, biochar which was a by-product of biomass gasification using oil palm empty fruit bunches was processed to make slow release biochar NPK fertilizer. Sources of nitrogen (N) were derived from urea, phosphate (P) from diamonium phosphate (DAP) and potassium (K) derived from potassium chloride (KCl). Zeolite was added as a matrix to improve fertilizer characteristics. All materials were formulated to make slow release biochar NPK fertilizer used for red onion (Allium sepa) plant applications. Several micronutrients were also added including Mg (MgSO4 fertilizer) and S (ZA fertilizer) to support plant growth. The characterization of fertilizer products was carried out by using SEM, BET etc. to determine physical properties including surface area, pore volume, morphology and composition. Furthermore, biochar NPK fertilizer was applied to the red onion plant which was a high-value crop in Indonesia. The application of NPK biochar fertilizer on red onion plant showed its superiority compared to commercial NPK fertilizers. In addition, the use of Magnesium and sulfur micronutrients could support the growth of red onion bulbs so that they produced more and bigger bulbs.*The paper has been selected from a collaboration with IPST and 7th ICFCHT 2019 for a conference entitled "Innovation in Polymer Science and Technology (IPST) 2019 in Conjunction with 7th International Conference on Fuel Cell and Hydrogen Technology (ICFCHT 2019) on October 16th - 19th at The Stones Hotel Legian, Bali, Indonesia"