Adu, R. E. Y.
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OPTIMALISASI PROSES MORDANTING PADA PEWARNAAN ALAMI KAIN TENUN TIMOR DENGAN TANIN KULIT BIJI ASAM SEBAGAI BIOMORDAN Tea, M. T. D.; Adu, R. E. Y.; Moruk, L. D.
Jurnal Kimia (Journal of Chemistry) Vol. 17, No.2, Juli 2023
Publisher : Program Studi Kimia, FMIPA, Universitas Udayana (Program of Study in Chemistry, Faculty of Mathematics and Natural Sciences, Udayana University), Bali, Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.24843/JCHEM.2023.v17.i02.p04

Abstract

Pewarnaan kain tenun Timor menggunakan pewarna alami menghasilkan warna kain yang kurang intens dan kurang stabil terhadap pencucian, sehingga membutuhkan proses mordanting menggunakan biomordan tannin dari kulit biji asam (Tamarindus indica L.). Beberapa faktor dapat mempengaruhi proses mordanting untuk memperoleh karakteristik warna kain yang tidak mudah luntur terhadap pencucian yaitu konsentrasi mordan, lama waktu, suhu dan teknik mordanting yang digunakan. Pada penelitian ini dilakukan optimalisasi terhadap proses mordanting pada pewarnaan kain tenun Timor untuk mengetahui kondisi optimum dalam pewarnaan dengan mordan tanin dari kulit biji asam. Ekstraksi zat warna dan biomordan tanin dilakukan terlebih dahulu. Optimalisasi dilakukan terhadap teknik mordanting seperti pra, meta dan pasca mordanting. Variabel lain yang dioptimasi yaitu konsentrasi biomordan, suhu dan lama waktu mordanting. Parameter kualitas kain yang ditentukan setelah proses pewarnaan adalah ketahanan luntur terhadap pencucian yang diuji menggunakan Staining Scale Standard. Hasil penelitian menunjukkan bahwa karakteristik ketahanan luntur kain tenun Timor yang diperoleh melalui pewarnaan secara alami menggunakan biomordan tanin kulit biji asam dipengaruhi oleh kondisi mordanting. Ketahanan luntur yang baik diperoleh pada penggunaan teknik pra-mordanting, konsentrasi biomordan 15%, waktu 120 menit dan suhu 95oC. Kata kunci: biomordan, kulit biji asam, tanin, tenun Timor, warna alami ABSTRACT The natural dyeing of Timor woven fabrics produces products with less color intensity and less stability to washing, so it requires a mordanting process using bio-mordant tannin from tamarind seed coat (Tamarindus indica L.). Several factors can affect the mordanting process to obtain the characteristics of high color fastness of fabrics namely the mordant concentration, length of time, temperature and mordanting technique. In this study, optimization of the mordanting process for dyeing Timor woven fabrics was carried out to determine the optimum conditions for staining with tannin mordant from the tamarind seed coat. The extraction of dyestuffs and tannin bio-mordant was carried out first. Optimization is carried out on mordanting techniques such as pre, meta, and post-mordanting. Other variables that were optimized were concentration of bio-mordant, temperature, and length of mordanting time. The parameter of the fabric quality after the dyeing process is the color fastness to washing which is tested using the Staining Scale Standard. The results showed that the fastness characteristics of Timor woven fabrics obtained through natural dyeing using tamarind seed coat tannin bio-mordant were affected by mordanting conditions. A good color fastness was achieved by using the pre-mordanting technique, 15% bio-mordant concentration, 120 minutes, and 95oC temperature. Keywords: bio-mordant, tamarind seed coat, tannin, Timor weaving, natural color
PENGGUNAAN EKSTRAK METANOL DAUN KALIANDRA (Calliandra calothyrsus M.) SEBAGAI INHIBITOR KOROSI PADA MEDIA HCl Batu, M. S.; Adu, R. E. Y.; De Fretes, M.
Jurnal Kimia (Journal of Chemistry) Vol. 18, No.2, Juli 2024
Publisher : Program Studi Kimia, FMIPA, Universitas Udayana (Program of Study in Chemistry, Faculty of Mathematics and Natural Sciences, Udayana University), Bali, Indonesia

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Abstract

Penelitian mengenai penggunaan ekstrak metanol daun kaliandra sebagai inhibitor korosi logam besi telah dilakukan. Tujuan dari penelitian ini adalah untuk mengetahui senyawa metabolit sekunder yang terkandung dalam ekstrak daun kaliandra (Calliandra calothyrsus M.) dan kondisi optimum pada variasi waktu perendaman, konsentrasi dan suhu pada proses inhibisi logam besi dalam media HCl. Ekstrak daun kaliandra diperoleh melalui ekstraksi maserasi dengan pelarut metanol. Uji inhibisi korosi dilakukan menggunakan metode pengurangan berat dengan variasi waktu perendaman, konsentrasi ekstrak daun kaliandra, dan suhu untuk mengetahui laju korosi per tahun dan % efisiensi inhibisi. Hasil penelitian menunjukkan bahwa ekstrak metanol daun kaliandra mengandung senyawa metabolit sekunder alkaloid, flavonoid, tanin, dan saponin. Kondisi optimum untuk proses inhibisi logam besi pada media korosif HCl dengan ekstrak daun kaliandra diperoleh pada waktu peredaman 6 hari dengan efisiensi inhibisi dan nilai laju korosi sebesar 86,49% dan 0,00119 mm/tahun, serta pada konsentrasi 13.000 ppm dan suhu 26? dengan efisiensi inhibisi dan nilai laju korosi sebesar 91,60 % dan 0,00073 mm/tahun. Pada perendaman menggunakan variasi suhu, semakin tinggi suhu yang digunakan maka efisiensi inhibisinya semakin menurun dan laju korosinya semakin meningkat sehingga logam besi mengalami korosi lebih cepat. Kata kunci: Besi, Korosi, Ekstrak Metanol, Inhibitor, Daun Kaliandra. ABSTRACT In this research, the use of methanol extract from calliandra leaves as an iron metal corrosion inhibitor has been conducted. The purpose of this study was to determine the type of secondary metabolite compounds contained in the extract of calliandra leaves (Calliandra calothyrsus M.) and to determine the optimum conditions at variations (immersion time, concentration, and temperature) in the process of iron metal inhibition using calliandra leaf extract in the HCl corrosion media. The calliandra leaves were extracted using the maceration method with a methanol solvent. The corrosion inhibition test was carried out using the weight loss method with variations in soaking time, the concentration of calliandra leaf extract, and temperature to determine the optimum corrosion rate per year and inhibition efficiency. The results showed that the methanol extract of calliandra leaves contained secondary metabolite compounds of alkaloids, flavonoids, tannins, and saponins. The optimum conditions for the inhibition process of iron metal in HCl corrosive media with calliandra leaf extract were at the soaking time of 6 days with the inhibition efficiency and corrosion rate of 86.49% and 0.00119 mm/year, and the concentration of 13,000 ppm and temperature of 26? with the inhibition efficiency and corrosion rate of 91.60% and 0.00073 mm/year. In immersion using temperature variation, the higher the temperature used, the lower the inhibition efficiency and the higher the corrosion rate obtained so that the iron metal corroded faster. Keywords: Iron, Corrosion, methanol extract, Inhibitor, Calliandra Leaf.