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All Journal IJFAC (Indonesian Journal of Fundamental and Applied Chemistry) Science and Technology Indonesia International Journal of Sustainable Transportation Technology
Amelia, Icha
Center of Research Excellent in Fuel Cell and Hydrogen, Universitas Sriwijaya, Indonesia
Automotive Engineering Biochemistry, Genetics & Molecular Biology Chemical Engineering, Chemistry & Bioengineering Chemistry Control & Systems Engineering Engineering Environmental Science Industrial & Manufacturing Engineering Materials Science & Nanotechnology Physics Transportation

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A Review on Production of Hydrogen from Renewable Sources and Applications for Fuel Cell Vehicles Rohendi, Dedi; Rahmah, Dea; Yulianti, Dwi; Amelia, Icha; Sya'baniah, Nyimas; Syarif, Nirwan; Rachmat, Addy
http://dx.doi.org/10.31427/IJSTT.2018.1.2.5
Publisher : Unijourn Publisher

Show Abstract | Download Original | Original Source | Check in Google Scholar

Abstract

Hydrogen gas is an energy carrier that has many advantages, including energy density for high mass and environmentally friendly. Hydrogen can be produced from various sources by numerous methods. Hydrogen production from renewable sources is interesting, due to the sustainable and inexpensive supply of the raw materials. Among the sources of renewable raw materials for hydrogen production are water and biomass with various production methods. It consists of the electrolysis of water with acidic and basic conditions, as well as thermochemical and biochemical biomass conversion.
Hydrogen Adsorption/desorption on lithium Alanat Catalyzed by Ni/C for Sustainable Hydrogen Storage Icha Amelia; Dedi Rohendi; Addy Rachmat
IJFAC (Indonesian Journal of Fundamental and Applied Chemistry) Vol 6, No 2 (2021): June 2021
Publisher : IJFAC (Indonesian Journal of Fundamental and Applied Chemistry)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.24845/ijfac.v6.i2.59

Abstract

 LiAlH4 alloy has been believed to have the potential to become one of the hydrogen storages with high storage capacity. In this research, the formation of LiAlH4 alloys with dope and undope Ni/C catalysts and characterization and testing of hydrogen adsorption/desorption capacities using these alloys have been carried out. The alloy was made by the milling method and the resulting alloy was characterized using XRD analysis. The adsorption capacity test of the alloy was carried out by the gravimetric method at various pressures. The adsorption capacity of the LiAlH4 alloy by adding additives in the form of Ni/C as much as 5%w/w was proven to increase the hydrogen adsorption capacity compared to undope a catalyst with the highest storage capacity at a pressure of 3 bar of 13.06%w/w compared to undope a catalyst of 9.84%w/w at the same pressure. Meanwhile, the highest hydrogen desorption capacity was 53.56% w/w (dope catalyst) and 41.75% w/w (undope catalyst).
The Electrochemical Conversion of CO2 into Methanol with KHCO3 Electrolyte Using Membrane Electrode Assembly (MEA) Dedi Rohendi; Nyimas Febrika Sya’baniah; Edy Herianto Majlan; Nirwan Syarif; Addy Rachmat; Dwi Hawa Yulianti; Icha Amelia; Dimas Ardiyanta; Isya Mahendra; Rr. Whiny Hardiyati Erliana
Science and Technology Indonesia Vol. 8 No. 4 (2023): October
Publisher : Research Center of Inorganic Materials and Coordination Complexes, FMIPA Universitas Sriwijaya

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.26554/sti.2023.8.4.632-639

Abstract

The electrochemical conversion process of CO2 into methanol using Membrane Electrode Assembly (MEA) has been done. The MEA consists of a Pt/C catalyst in the cathode and a Cu2O ZnO/C catalyst in the anode. The electrodes were made using the spraying method and then characterized using Cyclic Voltammetry (CV) and Electrochemical Impedance Spectroscopy (EIS) methods to determine the ECSA (Electrochemical Surface Area) and electrical conductivity values. Besides that, also X-Ray Diffraction (XRD) and Scanning Electrode Microscopy – Energy Dispersive X-Ray (SEM-EDX) analysis was to determine the crystal and morphological structure. The voltammogram from CV analysis indicated that the ECSA value on the Pt/C electrode was 7.2 m2/g and the Cu2O-ZnO/C electrodes as 0.69 m2/g. The electrode’s electrical conductivity value with Pt/C catalyst was 1.15 x 10−3 S/cm, and the electrode with Cu2O-ZnO/C catalyst was 0.80 x 10−3 S/cm. The results of the XRD analysis confirmed the presence of Cu2O and ZnO on the Cu2O-ZnO/C electrode and Pt on the Pt/C electrode. Meanwhile, the results of the SEM-EDX analysis showed that the Pt/C catalyst was spread more evenly with a larger percentage than Cu2O and ZnO. The result of the conversion of CO2 to methanol was measured using a methanol analyzer with variations in KHCO3 electrolyte concentration, variation of temperature operation, and variation of time operation. The best methanol concentrations after distillation process were 79.06 w/v %, with 1 M KHCO3, at room temperature and 2 hours operation.
The Influence of Catalyst Loading on Electrocatalytic Activity and Hydrogen Production in PEM Water Electrolysis Rohendi, Dedi; Amelia, Icha; Sya'baniah, Nyimas Febrika; Yulianti, Dwi Hawa; Syarif, Nirwan; Rachmat, Addy; Fatmawati; Majlan, Edy Herianto
Science and Technology Indonesia Vol. 9 No. 3 (2024): July
Publisher : Research Center of Inorganic Materials and Coordination Complexes, FMIPA Universitas Sriwijaya

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.26554/sti.2024.9.3.556-564

Abstract

The climate change caused by the widespread and continuous use of fossil fuels is a problem that needs to be addressed urgently. One of the solutions offered is through an energy transition towards the use of new or renewable and low-carbon fuels. Hydrogen gas as a carrier of energy is an alternative solution that has attracted the attention of researchers, due to its high combustion energy and environmental friendliness. The production of hydrogen gas using the Proton Exchange Membrane Water Electrolysis (PEMWE) method is considered effective for large-scale production. This study investigates the impact of catalyst loading and various current densities on hydrogen production in the PEM water electrolysis process, utilizing the Cu2O/C catalyst. This study investigates the impact of catalyst loading and different current densities on hydrogen production in the PEM water electrolysis process, utilizing the Cu2O/C catalyst. The electrode catalytic properties were evaluated using the Cyclic Voltammetry (CV) method to determine the Electrochemical Surface Area (ECSA) and the Electrochemical Impedance Spectroscopy (EIS) method to determine the electrical conductivity. The ECSA and EIS measurements demonstrated that the best results were obtained at a higher catalyst loading of 2 mg/cm2 with an ECSA value of 0.21 m2/g and electrical conductivity of 3.04 × 10−6 S/cm. The production of hydrogen results showed that the highest hydrogen production rate was 3.75 mL/s with a catalyst loading of 2.5 mg/cm2, indicating that increasing the load could lead to a higher rate of hydrogen gas production, but this is highly dependent on the surface area utilized. Additionally, at higher current densities, the cell resistance in the electrolysis process may decrease, leading to reduced electrode efficiency for hydrogen production. Thus, the use of high currents may not always be advantageous in hydrogen production using the PEM water electrolysis method.
Hydrogen Production from Aluminum Waste Using the Aluminum-Water Method with Potassium as Activator Amelia, Icha; Rohendi, Dedi; Rachmat, Addy; Syarif, Nirwan; Yulianti, Dwi Hawa; Sya'baniah, Nyimas Febrika; Adhiyanti, Nurmalina; Adelia, Ory; Normah, Normah
IJFAC (Indonesian Journal of Fundamental and Applied Chemistry) Vol 9, No 2 (2024): June 2024
Publisher : IJFAC (Indonesian Journal of Fundamental and Applied Chemistry)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.24845/ijfac.v9.i2.111

Abstract

Research on hydrogen production from aluminum waste using the aluminum-water method using potassium as an activator has been successfully carried out. This research aims to determine the performance of the potassium activator in hydrogen production with variable water volume and potassium percentage. Hydrogen gas production is carried out using 60 mesh aluminum waste. Optimum conditions were achieved when a mass of 1 gram of aluminum was reacted with an additional volume of water of 1.5 mL, and 7% w/w of the activator mass, with the production of hydrogen gas of 553 mL at a production rate of 69 mL/minute.
Co-Authors Addy Rachmat Addy Rachmat Adelia, Ory Adhiyanti, Nurmalina Dedi Rohendi Dedi Rohendi Dimas Ardiyanta Dwi Hawa Yulianti Edy Herianto Majlan Edy Herianto Majlan, Edy Herianto Fatmawati Fatmawati Isya Mahendra Nirwan Syarif Nirwan Syarif, Nirwan Normah Normah, Normah Rahmah, Dea Rr. Whiny Hardiyati Erliana Sya'baniah, Nyimas Syabaniah, Nyimas Febrika Syarif, Nirwan Yulianti, Dwi Yulianti, Dwi Hawa