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Kinerja Membran Plat Berpori Berbasis Selulosa Asetat yang Disintesis Secara Inversi Fasa untuk Ultrafiltrasi Bakteri E.coli di PDAM Surabaya Ariyanti, Dhita; Widiastuti, Nurul; Safarina, Nourma
Jurnal Teknologi Lingkungan Vol. 21 No. 2 (2020)
Publisher : Center for Environmental Technology - Agency for Assessment and Application of Technology

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (394.054 KB) | DOI: 10.29122/jtl.v21i2.3945

Abstract

ABSTRACTThe lack of consumable water in urban and industrial-dense areas encourages research on clean water treatment methods. Some current treatment methods, such as precipitation, adsorption, and UV light irradiation are ineffective for water with high levels of suspended solids, organic matter, and turbidity.  Therefore, alternative approaches are required to support the availability of clean and consumable water. The membrane technology is an alternative filtration method proposed in the East Surabaya's municipal waterworks area. The membrane filtration method is quite simple and easy to operate. This study aimed to determine the performance of cellulose acetate-based porous plate membranes synthesized by phase inversion for E. coli bacteria's ultrafiltration. As a raw material, cellulose acetate is preferred because of its high hydrophilicity and good biocompatibility. Membrane synthesis was carried out through the phase inversion method with acetone solvents and non-solvent water in the coagulation bath. The positive test for E. coli bacteria was carried out through the MPN (Most Probable Number) method on the municipal waterworks water samples before and after filtering with membranes. The results showed that the synthesis of cellulose acetate membrane had good homogeneity. This result was supported by the results of ANOVA single factor statistical data analysis. Also, cellulose acetate membrane had good permeability and flux performance as ultrafiltration of E. coli bacteria with a flux of 37.25 L/m2.hour.bar at a sufficient pressure of 5 bar. Test results for the presence of E. coli bacteria in PDAM water samples using the MPN method gave an initial indication that the water sample after filtration with cellulose acetate membrane was negative. Keywords: membrane, cellulose acetate, permeability, water fluxABSTRAKMinimnya air bersih yang layak konsumsi di daerah perkotaan dan padat industri mendorong penelitian tentang metode pengolahan air bersih. Kurangnya efektivitas metode pengolahan sebelumnya seperti pengendapan, adsorbsi, dan penyinaran dengan sinar UV untuk air dengan kadar suspended solids, zat organik, dan kekeruhan yang tinggi, diperlukan metode alternatif untuk mendukung ketersediaan air bersih layak konsumsi. Metode filtrasi alternatif yang ditawarkan di PDAM di kawasan Surabaya Timur. Metode filtrasi dengan membran sangat sederhana dan mudah dalam operasionalnya. Penelitian ini bertujuan untuk mengetahui kinerja membran plat berpori berbasis selulosa asetat yang disintesis secara inversi fasa untuk ultrafiltrasi bakteri E.coli. Selulosa asetat dipilih sebagai bahan baku membran karena selulosa asetat merupakan bahan polimer yang memiliki hidrofilitas tinggi dan biokompatibilitas yang baik. Sintesis membran dilakukan melalui metode inversi fasa dengan pelarut aseton dan nonpelarut air dalam bak koagulasi. Uji positif bakteri E.coli dilakukan melalui metode MPN (Most Probable Number) pada sampel air PDAM sebelum dan sesudah difiltrasi dengan membran. Hasil penelitian menunjukkan bahwa sintesis membran selulosa asetat memiliki homogenitas baik yang ditunjukkan oleh hasil analisis data statistika ANOVA single factor. Selain itu, membran selulosa asetat memiliki kinerja permeabilitas dan fluks yang baik sebagai ultrafiltrasi bakteri E.coli dengan ketercapaian fluks sebesar 37,25 L/m2.jam.bar pada tekanan efektif sebesar 5 bar. Hasil uji keberadaan bakteri E.coli pada sampel air PDAM dengan metode MPN memberikan indikasi awal bahwa sampel air setelah filtrasi dengan membran selulosa asetat adalah negatif.Kata kunci: membran, selulosa asetat, permeabilitas, fluks air 
Pengukuran Nilai pH Dan Kadar BOD (Biological Oxygen Demand) di Telaga Belahan Rejo Sebagai Pemantauan Kualitas Air Di Kabupaten Gresik Sa'adah, Nafiatus; Zummah, Atiqoh; Teguh Pribadi, Eko; Safarina, Nourma
INDONESIAN JOURNAL OF CHEMICAL RESEARCH Vol. 9 No. 2 (2024): Volume 9, ISSUE 2,2024
Publisher : Chemistry Department, Universitas Islam Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.20885/ijcr.vol9.iss2.art8

Abstract

Belahan Rejo Lake is one of the water bodies in Gresik Regency. Belahan Rejo lake water is used by the surrounding community for daily purposes such as irrigation of rice fields, plantations, fisheries, domestic, and so on. Activities carried out by the community around Belahan Rejo lake can affect water quality and can even cause water pollution. The purpose of this study is to determine the quality of Belahan Rejo lake water in terms of pH and BOD (Biological Oxygen Demand) parameters. Analysis of pH values is carried out based on the SNI 6989.11: 2019 method using a pH meter tool while analysis of BOD levels is carried out based on the SNI 6989.72: 2009 method by looking at the value of dissolved oxygen using a DO meter tool. The results of the analysis show that Telaga Water in Belahan Rejo Hamlet, Gresik Regency is in accordance with quality standards with a pH value of 6.5 and Biological Oxygen Demand (BOD) levels of 5.1 mg/L.
Pengukuran Kadar Kromium Heksavalen (Cr (VI)) dan Fenol di Telaga Dusun Belahan Rejo Sebagai Pemantauan Kualitas Air di Kabupaten Gresik Andini, Eka Andini San Putri; Zummah, Atiqoh; Teguh Pribadi, Eko; Safarina, Nourma
INDONESIAN JOURNAL OF CHEMICAL RESEARCH Vol. 9 No. 2 (2024): Volume 9, ISSUE 2,2024
Publisher : Chemistry Department, Universitas Islam Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.20885/ijcr.vol9.iss2.art9

Abstract

The decline in water quality is caused by increasing human activities. Likewise, human activities around the Belahan Rejo Hamlet lake affect water quality and can potentially reduce the quality of the lake water itself. This research was conducted to determine the levels of Hexavalent Chromium (Cr (VI)) and Phenol from the water of Belahan Rejo Hamlet Lake as monitoring and supervision to determine the condition of water quality. Analysis of Hexavalent Chromium (Cr (VI)) levels was carried out using UV-Vis Spectrophotometry referring to the SNI 6989.71: 2009 method and obtained an average value of 0.0148 mg/L, while Phenol levels were carried out using the HACH DR1900 Portable Vis Spectrophotometer referring to the DOC 316.53.01108 method and obtained a result of 0.018 mg/L. Based on the quality standards stipulated in Government Regulation of the Republic of Indonesia Number 22 of 2021 concerning the Implementation of Environmental Protection and Management, Appendix VI concerning the quality standards for Lake Water and the like, class 4, the quality standard for the Hexavalent Chromium (Cr (VI)) parameter is 1 mg/L and for the Phenol parameter is 0.02 mg/L. The levels of Hexavalent Chromium (Cr (VI)) and Phenol from this test are below the standard water quality limits, meaning that the lake water can still be used to irrigate crops and/or for other purposes that require the same water quality as these uses.