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All Journal Journal of Bioprocess Chemical and Environmental Engineering Science
Febriantoni, Febriantoni
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Chemical Engineering, Chemistry & Bioengineering Control & Systems Engineering Decision Sciences, Operations Research & Management Environmental Science Industrial & Manufacturing Engineering Materials Science & Nanotechnology

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Kinetika Reaksi Upgrading Bio-oil Melalui Proses Esterifikasi dengan Katalis Biochar Tersulfonasi Febriantoni, Febriantoni; Sunarno; Panca Setia Utama
Journal of Bioprocess, Chemical and Environmental Engineering Science Vol 7 No 1 (2026): Journal of Bioprocess, Chemical, and Environmental Engineering
Publisher : Department of Chemical Engineering, Faculty of Engineering, UNRI

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.31258/jbchees.7.1.1-12

Abstract

Development and research related to the utilization of biomass is currently motivated by the depletion of fossil fuel resources. Bio-oil from palm fronds, which is expected to be a renewable energy, can be produced through pyrolysis. However, bio-oil cannot be used directly as fuel because it contains many mixed compounds. Therefore, upgrading with esterification process using variable temperature and sulfonated biochar catalyst is a solution offered in improving the quality of bio-oil. This research studied the kinetics of esterification reaction using sulfonated biochar catalyst and temperature variations (40 °C, 50 °C, 60 °C and 70 °C), 4% catalyst concentration, 5:1 molar ratio of methanol: bio-oil to obtain the effect of catalyst use on the temperature used and obtain the reaction rate equation from the use of catalyst based on the validated reaction order. The results concluded that the sulfonated biochar catalyst characterized by SEM test and FTIR test, showed the success of -SOɜH bond and showed the expected changes in surface morphology. The esterification reaction kinetics for bio-oil upgrading with sulfonated biochar catalyst is a pseudo second-order reaction with a value of R² = 0.9483 (valid at a reaction time of 0-60 minutes, if more than that time does not describe the initial kinetic phase) with the reaction rate equation "r" _"A" "=-" 〖"dC" 〗_["AA" ] /"dt" "=" ["16.568.270 " "exp" ⁡("-58.475,7" /"RT" ) 〖"C" _"AA" 〗^"2" ] . Upgraded bio-oil after esterification process has a density of 1.039 g/mL (previously 1.2160 g/mL), viscosity of 4.0331 cP (previously 7.5247 cP), heating value of 15.499 MJ/kg (previously 71.38 J/g) and pH of 7 (previously 3).
Co-Authors SUNARNO Utama, Panca Setia