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All Journal Jurnal Akademika Kimia
Abram, Paulus H.
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Coagulant Capacity of Moringa (Moringa Oleifera) Seed on NaCl Solution Sibulo, Vanesa; Abram, Paulus H.
Jurnal Akademika Kimia Vol. 12 No. 4 (2023)
Publisher : Universitas Tadulako

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.22487/j24775185.2023.v12.i4.pp2242-246

Abstract

Moringa seeds are one of the natural coagulant ingredients that contain protein and carbohydrates that can be used in water purification, especially in reducing turbidity. This study aims to determine the level of NaCl coagulated by Moringa seed powder. The capacity or coagulation ability of Moringa seed powder is measured by the percentage of NaCl in the solution coagulated by Moringa seed powder. To achieve this purpose, several experiments have been used, namely variations in the concentration of NaCl as samples including; 0.5 %, 1 %, 3%, and 5% with treatment using Moringa seed powder as much as 1 g, 3 g and 5 g—determination of NaCl content using Flame Photometers BWB Technologies. The results of this study indicate that the optimum level of NaCl coagulated by Moringa seed powder is 3 %. The concentration can increase the effectiveness of reducing NaCl levels by obtaining a coagulated percentage value of 95.30 %.
The Utilization of Avocado Seed Powder (Persea americana Mill) as a Metal Adsorbent of Cu(II) Juliyanto, Juliyanto; Abram, Paulus H.
Jurnal Akademika Kimia Vol. 12 No. 1 (2023)
Publisher : Universitas Tadulako

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.22487/j24775185.2023.v12.i1.pp39-43

Abstract

Avocado is a fruit that has a high nutritional value are beneficial for human health. In the fruit of the avocado are seeds of avocado that are still less utilization thus discarded and become waste. The content in avocado seeds can be used as an adsorbent. This research utilizes avocado seed powder (Persea americana Mill). As Metal Cu(II) Adsorbent. This study aims to determine the water content, ash content, and optimum pH of the adsorption of Cu(II) metal using avocado seed powder. Determining the concentration of Metal Cu(II) using the tool spectrophotometry Atomic Absorption (AAS). Determination of the optimum pH is done by varying the pH 2, pH 3, and pH 4. This research results show that the water content is 4.88% and the ash content is 1.94%. The results of the analysis of the optimum pH to adsorb Cu(II) metal is pH 4 with a percentage of metal that is absorbed by 65.515%. Based on the results of the study showed that avocado seeds can be used as adsorbents.
Analysis of Nitrogen and Potassium in Liquid Organic Fertilizer from Rice Washing and Mature Coconut Water Bolang, Pinkan K.; Tiwow, Vanny M. A.; Abram, Paulus H.; Nurmayanti, Yuli
Jurnal Akademika Kimia Vol. 14 No. 2 (2025)
Publisher : Universitas Tadulako

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.22487/j24775185.2025.v14.i2.pp64-69

Abstract

Mature coconut and rice washing water contain nitrogen and potassium, which are helpful for plants. This study aims to determine the levels of nitrogen and potassium in liquid organic fertilizer from a mixture of mature coconut water and rice washing water. Nitrogen content was analyzed using the Kjeldahl method. Potassium levels were analyzed using a flame photometer. The results indicated that the best nitrogen and potassium levels were obtained in liquid organic fertilizer with a mixture ratio 50:50, namely N 1.26% and K 1.27%. The highest nitrogen content was obtained in liquid organic fertilizer (LOF) with a mixture ratio of 25:75, 1.40%, and the highest potassium content was obtained in liquid organic fertilizer with a mixture ratio of 50:50, 1.27%. When mixed, the increase in nitrogen and potassium levels was caused by the bacteria in the liquid organic fertilizer, which breaks down protein during digestion.
Epoxidation of Eugenol from Clove Oil (Syzygium aromaticum) Using H₂O₂ Oxidizer and H₃PO₄ Catalyst Gheje, Walburga E.; Abram, Paulus H.; Tiwow, Maria V.; Rahmawati, Sitti
Jurnal Akademika Kimia Vol. 14 No. 2 (2025)
Publisher : Universitas Tadulako

Show Abstract | Download Original | Original Source | Check in Google Scholar

Abstract

Clove oil (Syzygium aromaticum) contains 80–90% eugenol. Eugenol is a pale yellow liquid with several active functional groups, such as hydroxyl, aromatic rings, and allyl groups, which allow it to be modified to produce various eugenol derivative compounds. This study aims to characterize eugenol epoxy resin synthesized from clove oil eugenol using hydrogen peroxide (H₂O₂) and phosphoric acid (H₃PO₄) as a catalyst. The resulting eugenol epoxide was in the form of a yellowish-white gel with a distinctive clove aroma. It was soluble in benzene and chloroform but insoluble in ethanol. FTIR analysis showed that the epoxy compound contained an ether group (C-O-C) at absorption peaks of 1266.07 cm⁻¹ to 1018.66 cm⁻¹, a hydroxyl group (─OH) at 3347.08 cm⁻¹, a methyl group (-CH₃) at 1470 cm⁻¹ to 1350 cm⁻¹, an alkene group (C=C) at 1637.39 cm⁻¹, and a vinyl group at 910.2 cm⁻¹.