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All Journal JKPK (Jurnal Kimia dan Pendidikan Kimia)
Febriana, Rani
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Chemical Engineering, Chemistry & Bioengineering Chemistry

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Biosynthesis and Characterization of SiO-Cochineal Dye Nanoparticles Based on Salak Frond Silica for Fingerprint Visualization Applications Sari, Sri Adelila; Kabeakan, Feri Yuni Asiyah; Febriana, Rani
JKPK (Jurnal Kimia dan Pendidikan Kimia) Vol 10, No 2 (2025): JKPK (Jurnal Kimia dan Pendidikan Kimia)
Publisher : Program Studi Pendidikan Kimia FKIP Universitas Sebelas Maret

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.20961/jkpk.v10i2.106785

Abstract

Latent fingerprint visualization is a critical technique in modern forensic science that requires effective and environmentally sustainable coloring agents. This study reports synthesizing and characterizing a novel dyeing agent based on Cochineal insect extract combined with silica derived from salak (Salacca zalacca) bunch waste. It evaluates its application in fingerprint visualization. Cochineal extract was obtained via stepwise heating in a polar solvent, while silica was synthesized through carbonization, demineralization, destruction, and neutralization. The SiO–Cochineal nanoparticles were prepared using a stepwise thermal immobilization method, resulting in covalent bonding between the pigment and silica matrix. Structural and functional group characterization using FTIR confirmed the presence of Si–O–Si, O–H, and C=O groups, indicating successful integration. Application tests on latent fingerprints demonstrated that the composite powders produced sharp and distinct ridge patterns, particularly on non-porous substrates such as glass and optical discs. These findings suggest that SiO-Cochineal-based powders are effective for forensic applications and represent a promising green alternative for latent fingerprint visualization.
Eco-Friendly Revolution in Fingerprint Detection: Synthesis of Zno Nanoparticles Using Durian (Durio Zibethinus) Peel Extract Pakpak Bharat Sari, Sri Adelila; Febriana, Rani; Kabeakan, Feri Yuni Asiyah
JKPK (Jurnal Kimia dan Pendidikan Kimia) Vol 10, No 3 (2025): JKPK (Jurnal Kimia dan Pendidikan Kimia)
Publisher : Program Studi Pendidikan Kimia FKIP Universitas Sebelas Maret

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.20961/jkpk.v10i3.106878

Abstract

Fingerprints are a reliable means of forensic identification because ridge patterns are unique and permanent. Conventional fingerprint powders, however, may contain hazardous ingredients that pose health and environmental risks. This study synthesized zinc oxide (ZnO) nanoparticles via a green route using durian peel (Durio zibethinus) extract and evaluated their potential as an eco-friendly latent fingerprint developer. ZnO nanoparticles were characterized by FTIR to identify functional groups, SEM to examine morphology and particle size, and EDX to verify elemental composition. The biosynthesized ZnO showed semi-spherical to granular particles with sizes of 40–90 nm and no severe agglomeration. FTIR indicated hydroxyl and carbonyl groups from durian peel biomolecules, suggesting their role as reducing and stabilizing agents. EDX confirmed dominant Zn (72.5%) and O (15.2%) signals, supporting high purity ZnO formation. Latent fingerprint development was tested using prints from 40 respondents on porous surfaces (black cardboard and oil paper) and nonporous surfaces (microscope slide, aluminum foil, and compact disc). The ZnO nanopowder produced clear ridge patterns and higher contrast on nonporous substrates, while conventional powders tended to leave residues and may require less safe reagents. These results indicate that durian peel derived ZnO nanoparticles are a promising, economical, and environmentally friendly alternative for latent fingerprint visualization and provide added value for agricultural waste utilization in forensic applications.
Co-Authors Kabeakan, Feri Yuni Asiyah Sri Adelila Sari