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All Journal Journal of Engineering and Technological Sciences Chemistry Indonesian Journal of Chemical Research

Danu Ariono

Chemical Engineering Department, Faculty of Industrial Technology, Institut Teknologi Bandung, Jalan Ganesa No. 10 Bandung 40132

Author-ID : 232940

Biochemistry, Genetics & Molecular Biology Chemistry Engineering Environmental Science

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The Influence of PEG400 and Acetone on Polysulfone Membrane Morphology and Fouling Behaviour Aryanti, P.T.P.; Joscarita, Shelli R.; Wardani, Anita K.; Subagjo, S.; Ariono, Danu; Wenten, I Gede
Journal of Engineering and Technological Sciences Vol 48, No 2 (2016)
Publisher : ITB Journal Publisher, LPPM ITB

Modification of polysulfone ultrafiltration membrane was conducted by blending polysulfone with PEG400 and acetone as additives. The influence of each additive on the resulted membrane morphology and fouling characteristics were investigated. The experimental results showed that the hydrophilicity of the polysulfone membrane was improved by the increase of PEG400 in the polysulfone membrane. The water contact angle of the membrane was decreased from 76.1Â° to 38.31Â° when 35 %wt of PEG400 was added into the polysulfone solution, while the water content of the membrane was increased by around 38%. The high concentration of PEG400 in the polysulfone solution led to the formation of longer finger-like cavities in the membrane structure and resulted in a thicker membrane skin layer. The high concentration of PEG400 also contributed to the increase in hydraulic resistance of the membrane due to organic matter fouling. This problem could be minimized by the addition of acetone into the polysulfone solution, which resulted in a lower fouling resistance of organic matter during up to five hours of peat water filtration.

Brine Effluents: Characteristics, Environmental Impacts, and Their Handling Ariono, Danu; Purwasasmita, Mubiar; Wenten, I Gede
Journal of Engineering and Technological Sciences Vol 48, No 4 (2016)
Publisher : ITB Journal Publisher, LPPM ITB

Brine discharge is one of the largest sources of wastewater from industrial processes. Because of the environmental impacts arising from improper treatment of brine discharge and more rigorous regulations of pollution control, industries have started to focus on waste minimization and improving the process of wastewater treatment. Several approaches have been proposed to provide a strategy for brine handling by recovering both brine and water or to remove pollutant components so it complies with environmental regulations when discharged. One of the most promising alternatives to brine disposal is reusing the brine, which results in reduction of pollution, minimizing waste volume and salt recovery. The brine may also contain valuable components that could be recovered for profitable use. Also, water recovery from brine effluent is generally performed to save water. In the case of rejected brine from desalination plants, water recovery from higher brine concentrations has huge potential for salt production. This paper gives an overview of different types of brine effluents, their sources and characteristics. Also discussed are impacts of brine on the environment and management options related to their characteristics.

Analysis of Protein Separation Mechanism in Charged Ultrafiltration Membrane Ariono, Danu; Aryanti, Putu Teta P.; Wardani, Anita Kusuma; Wenten, I Gede
Journal of Engineering and Technological Sciences Vol 50, No 2 (2018)
Publisher : ITB Journal Publisher, LPPM ITB

The separation mechanism of proteins on a charged ultrafiltration membrane was analyzed using the extended NernstâPlanck (N-P) model. The model was solved numerically based on experimental data during ultrafiltration of bovine serum albumin/BSA and hemoglobin at various pH (between 5 and 8) to obtain the flux parameter (Jv). The flux parameter was used to determine the effective charge of the membrane (f) and the actual membrane porosity (Ak). These two parameters were then used to predict the transport mechanism of proteins through the charged membrane. Higher flux was obtained during the ultrafiltration of BSA compared to hemoglobin. The most effective separation of mixed proteins occurred at pH 5 (aalbumin= 5). In addition, the mobility of a single protein was lower than when it was mixed with other proteins that had different charges. The effective charges of the membranes were varied between 0.99996 to 1.0000, which means that the fixed charge on the membrane structure was higher than the concentration of proteins, thus the effective charge of the membrane was not influenced by the presence of protein charge at various pH. On the contrary, the value of Ak was influenced by the type and charge of the proteins. A decrease of negative charge along with an increase of solution pH increased the porosity of the membrane, thus reducing the rejection of proteins.

Co-Authors Adhi, Tri Partono Anita K. Wardani, Anita K. I Gede Wenten Japri, Veronica Japri, Veronica P.T.P. Aryanti, P.T.P. Purwasasmita, Mubiar Putu Teta Prihartini Aryanti Raksajati, Anggit S. Subagjo Shelli R. Joscarita, Shelli R. TATI NURHAYATI Wardani, Anita Kusuma

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