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All Journal Wood Research Journal : Journal of Indonesian Wood Research Society Wood Research Journal : Journal of Indonesian Wood Research Society
Joko Sulistyo
Dept. of Forest Products Technology, Faculty of Forestry, Universitas Gadjah Mada
Agriculture, Biological Sciences & Forestry

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Green Aromatics from Catalytic Fast Pyrolysis of Fast Growing Meranti Biomass Joko Sulistyo; Toshimitsu Hata; Sensho Honma; Ryohei Asakura; Sri Nugroho Marsoem
Wood Research Journal Vol 4, No 1 (2013): Wood Research Journal
Publisher : Masyarakat Peneliti Kayu Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.51850/wrj.2013.4.1.13-18

Abstract

The study on catalytic pyrolysis decomposition of Shorea leprosula wood biomass to form aromatic compounds in fast pyrolysis was performed by pyrolytic-gas chromatography/mass spectroscopy (Py-GC/MS) and transmission electron microscope (TEM) - electron energy-loss spectroscopy (EELS) to analyze the chemical compound and solid residue microstructure. Py-GC/MS and TEM-EELS analysis showed that the fast pyrolysis increased the decomposition of hardwood, in which in the presence of ZSM-5 catalyst, the liquid products from wood decomposition was then diffused into the pore of ZSM-5 catalyst to form aromatics including benzene, toluene, styrene, naphthalenes and indanes. The carbonaceous solid compounds or cokes were not deposited on the surface of pores of ZSM-5 catalyst in the fast pyrolysis, as shown by the EELS spectrum that exhibited no detection of any solid carbonaceous compound in the solid residue.
Green Aromatics from Catalytic Fast Pyrolysis of Fast Growing Meranti Biomass Joko Sulistyo; Toshimitsu Hata; Sensho Honma; Ryohei Asakura; Sri Nugroho Marsoem
Wood Research Journal Vol 4, No 1 (2013): Wood Research Journal
Publisher : Masyarakat Peneliti Kayu Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.51850/wrj.2013.4.1.13-18

Abstract

The study on catalytic pyrolysis decomposition of Shorea leprosula wood biomass to form aromatic compounds in fast pyrolysis was performed by pyrolytic-gas chromatography/mass spectroscopy (Py-GC/MS) and transmission electron microscope (TEM) - electron energy-loss spectroscopy (EELS) to analyze the chemical compound and solid residue microstructure. Py-GC/MS and TEM-EELS analysis showed that the fast pyrolysis increased the decomposition of hardwood, in which in the presence of ZSM-5 catalyst, the liquid products from wood decomposition was then diffused into the pore of ZSM-5 catalyst to form aromatics including benzene, toluene, styrene, naphthalenes and indanes. The carbonaceous solid compounds or cokes were not deposited on the surface of pores of ZSM-5 catalyst in the fast pyrolysis, as shown by the EELS spectrum that exhibited no detection of any solid carbonaceous compound in the solid residue.
Thermoelectric Properties of Porous SiC/SiO2/C Composite from Carbonized Cryptomeria japonica Wood Joko Sulistyo; Hiroyuki Kitagawa; Sri Nugroho Marsoem
Wood Research Journal Vol 12, No 2 (2021): Wood Research Journal
Publisher : Masyarakat Peneliti Kayu Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.51850/wrj.2021.12.2.61-68

Abstract

Electric power generation by thermoelectric material utilizing radiated heat of from roof’s house, engine and others is potential clean energy in tropical areas such as Indonesia. In this study, thermoelectric materials such as silicon carbide (SiC/SiO2/C) composites were developed from carbonized Cryptomeria japonica wood infiltrated ethyl silicate-40 by sintering at 1400, 1600 and 1800 ºC for 30 min under N2 atmosphere. This study aimed to examine the morphology, microstructure and thermoelectric properties of porous SiC/SiO2/C composites. SiC/SiO2/C composites sintered at 1600 ºC with low value of thermal conductivity was potential for the development of thermoelectric material. The oxidation of SiC/SiO2/C composite sintered at 1600 °C which removed parts of residual silica and carbon, transformed the composite exhibiting p-type semiconductor with low values of Seebeck coefficient of to that exhibiting n-type semiconductor with high values Seebeck coefficient. A maximum of figure of merit of 6.25 x 10--5 K-1 was obtained at 140 ºC in the oxidized SiC/SiO2/C composite sintered at 1600 °C. The comparatively high figure of merit indicates the potentiality the material for thermoelectric purpose.
Co-Authors Hiroyuki Kitagawa Ryohei Asakura Sensho Honma Sri Nugroho Marsoem Toshimitsu Hata