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The Effect of Wood Tar and Molasses Composition on Calorific Value and Compressive Strength in Bio-coke Briquetting Erlina Yustanti; Abrar Muharman; Anggoro Tri Mursito
International Journal of Renewable Energy Development Vol 11, No 3 (2022): August 2022
Publisher : Center of Biomass & Renewable Energy, Diponegoro University

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.14710/ijred.2022.39298

Abstract

Biomass-based materials have the potential to replace conventional cokes for blast furnaces in the steel manufacturing study. Biomass as a renewable energy source can reduce the consumption of coking coal. The current challenge is saving fossil energy and waste management. The steelmaking industry with environmentally friendly processes and high energy efficiency is expected today. Many researchers have partially developed biomass as an alternative renewable resource to replace fossil fuels. This study aimed to determine the effect of composition the blending ratio of wood tar and molasses as a binder on the calorific value and compressive strength of bio-coke. The carbonization of redwood waste to produce high-quality charcoal was carried out at 500 °C with a kiln rotation speed of 20 rpm and a slope of 5°. The resulting charcoal showed a promising result with a 23.87 MJ/kg calorific value. The carbonization process of the redwood increased the fixed carbon value by up to 130% and the calorific value by 40%. The second part of this study focuses on bio-coke production by blending coking coal with redwood charcoal at 90:10 wt%. The coking coal and the redwood charcoal particle sizes were 40 and 50 mesh, respectively. A 15 wt% binder was added to increase the compressive strength of the bio-coke. The binder composition ratios of molasses: wood tar were 15:0, (12.5:2.5), and 10:5 wt%. The briquette was pressed using a cylinder die with a height: diameter ratio of 2.7:5.0 cm, then compacted up to 20 MPa followed by heating at 1100 °C for four hours. The bio-coke with a binder composition of 2.5 wt% wood tar + 12.5 wt% molasses produced a compressive strength of up to 5.57 MPa with a sulfur content of 0.8 wt% and produced a calorific value of 31.25 MJ/kg with an ash content of 9.6%. The study showed that the bio-coke produced meets some requirements for steelmaking industry.
The Effect of Wood Tar and Molasses Composition on Calorific Value and Compressive Strength in Bio-coke Briquetting Erlina Yustanti; Abrar Muharman; Anggoro Tri Mursito
International Journal of Renewable Energy Development Vol 11, No 3 (2022): August 2022
Publisher : Center of Biomass & Renewable Energy, Diponegoro University

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.14710/ijred.2022.39298

Abstract

Biomass-based materials have the potential to replace conventional cokes for blast furnaces in the steel manufacturing study. Biomass as a renewable energy source can reduce the consumption of coking coal. The current challenge is saving fossil energy and waste management. The steelmaking industry with environmentally friendly processes and high energy efficiency is expected today. Many researchers have partially developed biomass as an alternative renewable resource to replace fossil fuels. This study aimed to determine the effect of composition the blending ratio of wood tar and molasses as a binder on the calorific value and compressive strength of bio-coke. The carbonization of redwood waste to produce high-quality charcoal was carried out at 500 °C with a kiln rotation speed of 20 rpm and a slope of 5°. The resulting charcoal showed a promising result with a 23.87 MJ/kg calorific value. The carbonization process of the redwood increased the fixed carbon value by up to 130% and the calorific value by 40%. The second part of this study focuses on bio-coke production by blending coking coal with redwood charcoal at 90:10 wt%. The coking coal and the redwood charcoal particle sizes were 40 and 50 mesh, respectively. A 15 wt% binder was added to increase the compressive strength of the bio-coke. The binder composition ratios of molasses: wood tar were 15:0, (12.5:2.5), and 10:5 wt%. The briquette was pressed using a cylinder die with a height: diameter ratio of 2.7:5.0 cm, then compacted up to 20 MPa followed by heating at 1100 °C for four hours. The bio-coke with a binder composition of 2.5 wt% wood tar + 12.5 wt% molasses produced a compressive strength of up to 5.57 MPa with a sulfur content of 0.8 wt% and produced a calorific value of 31.25 MJ/kg with an ash content of 9.6%. The study showed that the bio-coke produced meets some requirements for steelmaking industry.
PURIFICATION OF PREGNANT SOLUTION RESULTED FROM SPHALERITE CONCENTRATE EXTRACTION USING SULFATE ACID FOR ZINC OXYDE PRODUCTION Yuhelda Yuhelda; Dessy Amalia; Putri Dewi Novianti; Erlina Yustanti
Indonesian Mining Journal Vol 22 No 2 (2019): INDONESIAN MINING JOURNAL, Vol. 22 No. 2, October 2019
Publisher : Balai Besar Pengujian Mineral dan Batubara tekMIRA

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.30556/imj.Vol22.No2.2019.1050

Abstract

Purification of pregnant solution from sphalerite concentrate extraction using sulfate acid to produce zinc oxide was meant to prepare zinc oxide production technology utilizing existing internal sphalerite mineral raw material. The pregnant solution used to produce zinc oxide contains 29.84% zinc (Zn), with the biggest impurities iron (Fe) 11.68%. In order to obtain high purity zinc oxide, the pregnant solution should be recovered. It was done through solvent extraction method, in two process steps: extraction and stripping. The extraction was applying ligan bis di2ethylhexyle phosphate acid (D2EHPA) in toluene solvent, through ligan concentrate variation, pH and comparison of aqueous volume with organic volume (VA:Vo) and its excess. Stripping was carried out using sulphate acid through variation of concentration, pH and Vo:VA. To obtain optimum recovery, thus extraction and stripping should be carried out in many steps. The extractions and the strippings were calculated using McCabe Thiele diagram. Furthermore, zinc oxide was resulted from deposition and calcination of pure pregnant solution at temperature 700°C. Purification results show that the best extraction occurred at concentration D2EHPA 1 M, pH 3 and Vo:Va 2:1, through 4 step processes obtained recovery 97.50% with distribution coefficient 77.9; while the best stripping was obtained at H2SO4 concentration 2 M, VO:VA 2:1 through 3 step processes which obtained stripping percent 98.22% with stripping coefficient 1.51. On the other hand, zinc oxide solution resulted from purification was obtained Zn 93.31% in the form of hexagonal crystals (wurtzite).