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Pembuatan Zat Warna Alami dalam Bentuk Serbuk untuk Mendukung Industri Batik di Indonesia Paryanto; Agus Purwanto; Endang Kwartiningsih; Endang Mastuti
Jurnal Rekayasa Proses Vol 6, No 1 (2012)
Publisher : Departemen Teknik Kimia Fakultas Teknik Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (92.772 KB) | DOI: 10.22146/jrekpros.2454

Abstract

Zat warna sintetis sangat praktis digunakan serta dapat menimbulkan warna yang mencolok pada produk. Namun limbah buangan zat warna sintetis dapat mencemari lingkungan. Saat ini zat warna alami mulai digunakan kembali. Untuk memudahkan pemakaian, zat warna alami berbentuk cair dikeringkan menjadi serbuk. Ekstrak zat warna alami dari biji kesumba dalam penelitian ini dikeringkan menggunakan spray dryer sehingga terbentuk serbuk. Zat warna kesumba diekstraksi dengan pelarut larutan NaOH dan Ca(OH)2. Pengeringan dilakukan dengan laju umpan rata – rata 0,13 ml/detik dengan suhu umpan 70°C dan suhu pengering 120°C. Pelarut NaOH memberikan hasil yang lebih baik dibanding pelarut Ca(OH)2. Kondisi yang relatif baik dicapai pada penggunaan pelarut NaOH 0,4 M, suhu 90C dan waktu 180 men. Serbuk yang dihasilkan 19,6 g/L larutan ekstrak. Kata Kunci : zat warna alam, serbuk, biji kesumba, pengering sembur, batik. Synthetic dyes are very practical to use and can lead to a striking color on the products. However, synthetic dye effluent may pollute the environment. For this reason, currently natural dyes have been used again for coloring. In order to ease the use of natural dyes, the liquid form of the dyes is dried into powder. In the present study, natural dyes extracted from kesumba seeds were dried using a spray dryer to form a powder. The Kesumba dye was extracted in an alkaline solutions of NaOH and Ca(OH)2. Drying was carried out with a feed having an average rate of 0.13 ml/sec at a temperature of 70°C. Meanwhile, dryer temperature was 120C. Experimental results showed that extraction using NaOH solution offered better results than that using Ca(OH)2 solution. The extraction using NaOH solution was optimum at NaOH concentration of 0.4 M, temperature of 90C and duration of 180 min. With this condition, the resulting powder was 19.6 g/L extract solution. Keywords : natural dye, powder, kesumba seed, spray dryer, batik.
Pembuatan Zat Warna Alami dalam Bentuk Serbuk untuk Mendukung Industri Batik di Indonesia Paryanto; Agus Purwanto; Endang Kwartiningsih; Endang Mastuti
Jurnal Rekayasa Proses Vol 6, No 1 (2012)
Publisher : Departemen Teknik Kimia Fakultas Teknik Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.22146/jrekpros.2454

Abstract

Zat warna sintetis sangat praktis digunakan serta dapat menimbulkan warna yang mencolok pada produk. Namun limbah buangan zat warna sintetis dapat mencemari lingkungan. Saat ini zat warna alami mulai digunakan kembali. Untuk memudahkan pemakaian, zat warna alami berbentuk cair dikeringkan menjadi serbuk. Ekstrak zat warna alami dari biji kesumba dalam penelitian ini dikeringkan menggunakan spray dryer sehingga terbentuk serbuk. Zat warna kesumba diekstraksi dengan pelarut larutan NaOH dan Ca(OH)2. Pengeringan dilakukan dengan laju umpan rata – rata 0,13 ml/detik dengan suhu umpan 70°C dan suhu pengering 120°C. Pelarut NaOH memberikan hasil yang lebih baik dibanding pelarut Ca(OH)2. Kondisi yang relatif baik dicapai pada penggunaan pelarut NaOH 0,4 M, suhu 90C dan waktu 180 men. Serbuk yang dihasilkan 19,6 g/L larutan ekstrak. Kata Kunci : zat warna alam, serbuk, biji kesumba, pengering sembur, batik. Synthetic dyes are very practical to use and can lead to a striking color on the products. However, synthetic dye effluent may pollute the environment. For this reason, currently natural dyes have been used again for coloring. In order to ease the use of natural dyes, the liquid form of the dyes is dried into powder. In the present study, natural dyes extracted from kesumba seeds were dried using a spray dryer to form a powder. The Kesumba dye was extracted in an alkaline solutions of NaOH and Ca(OH)2. Drying was carried out with a feed having an average rate of 0.13 ml/sec at a temperature of 70°C. Meanwhile, dryer temperature was 120C. Experimental results showed that extraction using NaOH solution offered better results than that using Ca(OH)2 solution. The extraction using NaOH solution was optimum at NaOH concentration of 0.4 M, temperature of 90C and duration of 180 min. With this condition, the resulting powder was 19.6 g/L extract solution. Keywords : natural dye, powder, kesumba seed, spray dryer, batik.
PENGARUH KONSENTRASI ABSORBEN (Fe-EDTA) TERHADAP PENURUNAN KANDUNGAN H2S DALAM BIOGAS PADA LAJU ALIR UDARA REGENERASI YANG BERBEDA Endang Kwartiningsih; Arif Jumari; Adrian Nur; Danu Nugroho; Umi Sarwanti; Slamet Sapto; Endah Ari
Eksergi Vol 9, No 1 (2008): Versi Cetak
Publisher : Prodi Teknik Kimia, Fakultas Teknologi Industri, UPN "Veteran" Yogyakarta

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.31315/e.v9i1.7553

Abstract

Bíogas is very potential to be used as fuel because of its high content of methane. Biogas had also been developed and used by several industries as alternative fuels to substitute mineral oil, The disadvantage of biogas as fuel was its high content of hydrogen sulfide which is potentíal to pollute the ervironment. Because of this, biogas should be purified first before being used as fuel. Generally, the content of H2S can bereduced physically, chemically or biologically methods, but these methods have many disadvantages. Biogas purílìcation(also other gases) from the content of H2S using Fe-EDTA(Iron Chelated Solution) gave several advantages. The advantages were the absorbent solution can be regenerated that means a cheap operation cost, the separated sulfur was asolid (that is an economic commodity) or resídue that is easy to handle and is save to be disposal to environment. Iron Chelated Solutionwas made by solving the substance of salted iron to EDTA solution. The salt of FeCl2, was made by solving iron waste obtained from lathe machine to hydrochloric acid solution. The research of reduction of the content of H2S in biogas was conducted by contacting Fe-EDTA solution with biogas in an absorber column of 1 m height and 0. I m diameter The rich H2S solution from absorber was then flowed to the separator column to separate the solid of sulfur and its solution. The solution from separator column was then regenerated by oxidation in regenerator column. In regenerator column solution which is rich of iron reacted with oxygen from air to be Fe3. . The solution which is rich of Fe was then used again to absorb H2S in biogas. Biogas used during experiment was obtained from PT Indo Acidatama Tbk. The content of H2S in raw biogas was 2.8235 %. The result of the research showed that the concentration of absorbent influenced the reduction of the content of H2S. Absorbent solution with concentration of 0.2 M of Fe-EDTA was able to absorb 99 % of all H2S from 2.8235 % to 0.02 % in a column of I m height and 0.1 m diameter Absorbent solution with concentratíon of 0.1 M of Fe-EDTA was only able to absorb 59% of all H2S from 2.8235% to 1.2 %. The regeneration air flow rate also influence the reduction of the content of H2S in biogas. The higher the regeneration airflow rate the higher the reduction of the content of H2S.