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All Journal INDONESIAN JOURNAL OF APPLIED PHYSICS Jurnal Kimia Terapan Indonesia
Kiagus Dahlan
Departemen Fisika, FMIPA, Institut Pertanian Bogor, Darmaga, Bogor 16880, Indonesia
Astronomy Biochemistry, Genetics & Molecular Biology Chemical Engineering, Chemistry & Bioengineering Chemistry Energy Materials Science & Nanotechnology Physics

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Synthesis of Nanofiber from Polyvinyl Alcohol (PVA)-Collagen Using Electrospinning Methods Sudirman Sudirman; Aloma Karo Karo; Sulistiyoso Giat Sukaryo; Karina Dwi Adistiana; Kiagus Dahlan
Jurnal Kimia Terapan Indonesia Vol 21, No 2 (2020)
Publisher : Research Center for Chemistry - LIPI

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.14203/jkti.v21i2.428

Abstract

Polyvinil alcohol (PVA) polymer can be used as matrix to be mixed with collagen in the subtance of primary wound dressing material to cover wound that prevents growth of bacteria and enhanced tissue formation. Collagen fiber is fragile, so important to combined with PVA to obtain better mechanical properties. The PVA-collagen fibers are prepared in aqueous solutions with PVA (10%) and collagen concentration (1% and 2%) using electrospinning method and the effect of voltage 15 kV, 19 kV, and 23 kV. Analysis of functional groups show that the presence of identical compounds produced and new functional groups are not formed. SEM data show that the effect of variation of voltage and collagen concentration on the resulting morphology of fiber. PVA-collagen 2% fibers produce continuous fibers, has a diameter 284-426 nm, thickness 0.0324-0.0483 mm and has a high percent of elongation so it can be used as a wound dressing material.
Perhitungan Energi Disosiasi Gugus Fungsi OH- dan PO43- Hidroksiapatit dengan Pemodelan Spektroskopi Inframerah Berbasis Particle Swarm Optimization (PSO) Khusnul Yakin; Sidikrubadi Pramudito; Kiagus Dahlan
INDONESIAN JOURNAL OF APPLIED PHYSICS Vol 3, No 01 (2013): April
Publisher : Department of Physics, Sebelas Maret University

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.13057/ijap.v3i01.1236

Abstract

Hydroxyapatite Ca10(PO4)6(OH)2 is a calcium phosphate compound having biocompatibility properties. FTIR (Fourier Transform Infrared Spectroscopy) was used to determine the characteristics of the hydroxyapatite group. Modeling the functional groups of hydroxyapatite can be used to obtain vibrational frequencies and spring constants. Analysis of energy release function is performed by calculating the dissociation energy. In this paper will be shown the results of theoretical modeling of hydroxyl and phosphate using spring models. Modeling the functional groups OH- obtained spring constant 524,4559 N/m and the absorption wave number 3497,5677 cm-1. Modelling functional groups PO43-obtained spring constant 612,2704 N/m and the wave number 1085,2559 cm-1 absorption. The constant and absorption wave numbers obtained are used to calculate the dissociation energy. OH- dissociation energy obtained by 566,5637 kJ/mol and the dissociation energy of PO43- is 567,6248 kJ/mol. Absorption wave numbers are obtained in accordance with experimental results on sometrik stretch modes, and the dissociation energy derived functional group is also close to the value of literature.
Co-Authors Aloma Karo Karo Arief Budi Witarto Karina Dwi Adistiana Khusnul Yakin Permai Sari Molyana Yusuf Sidikrubadi Pramudito Sudirman Sudirman Sulistiyoso Giat Sukaryo