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INFLUENCE OF CARBON AND NITROGEN ADDITION ON THE CORROSION RESISTANCE OF Co-28Cr-6Mo-0,8Si-0,8Mn-0,4Fe-0,2Ni ALLOYS Fendy Rokhmanto; Cahya Sutowo; Ika Kartika
Widyariset Vol 4, No 1 (2018): Widyariset
Publisher : Pusbindiklat - LIPI

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (1236.98 KB) | DOI: 10.14203/widyariset.4.1.2018.1-8

Abstract

Cobalt alloys is one of the implant materials that is used in orthopedic and dentistry, because of its biocompatibility, good mechanical properties, and high corrosion resistance. The mechanical properties and corrosion resistance can be enhanced by thermomechanical treatment and addition of alloying element. Carbon and nitrogen were added to enhance mechanical properties and high corrosion resistance. Effect of carbon variation and nitrogen to the corrosion resistance in Co-Cr-Mo (CCM) alloys were measured by corrosion measurement system (CMS) device in Hank’s Solutions after thermomechanical treatment process. Corrosion rate of Co-Cr-Mo alloys with carbon variation dropped to 5.8 x 10-4 mmpy and 5.2 x 10-4 mmpy with carbon variation and nitrogen. Decreasing corrosion rate indicated that the corrosion resistance of alloys is increased with the addition of carbon and nitrogen.
CORROTION RATE AND MORPHOLOGY OF POROUS METAL ALLOY Mg-Ca-Zn WITH CaCO3 AS FOAMING AGENT Aprilia Erryani; Franciska Pramuji Lestari; Dhyah Annur; Muhammad Ikhlasul Amal; Ika Kartika
Widyariset Vol 4, No 1 (2018): Widyariset
Publisher : Pusbindiklat - LIPI

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (2043.584 KB) | DOI: 10.14203/widyariset.4.1.2018.9-20

Abstract

Magnesium alloy is a material that has been developed as a biodegradable implant material in orthopedic applications. Magnesium alloys have good biocompatibility, biodegradability, and good mechanical properties which make them have the potential to be used as a biomedical material. The main objective of this paper is to investigate corrotion rate and morphology after corrotion of biocompatibility of implant-based alloys Mg-Ca-Zn with CaCO3 as a foaming agent. Mg-Ca-Zn Alloy was made by the method of powder metallurgy with the addition of CaCO3 as a foaming agent with three variations of composition (96Mg-Ca-3Zn-CaCO3, 91Mg-Ca-3Zn-5 CaCO3, and 86Mg-Ca-3Zn-10 CaCO3 wt%). Sintering process was carried out at 600 °C and 650 °C with a holding time of five hours. Corrosion test was performed using G750 Gamry Instrument in accordance with ASTM standard G5-94. Simulated body fluid electrolyte used is Hank's solution with a pH value of 7.4 and a temperature of 37 °C. Then the analysis of the microstructure after corrosion test was conducted using scanning electron microscopy (JEOL, JSM-6390A Japan) equipped with energy dispersive spectrometry data (EDS). Alloy corrosion rate of Mg-Ca-Zn-CaCO3 increases with the amount of CaCO3 in the alloy and the temperature rise in the sintering. From the test results, the smallest corrosion rate is in the alloy 91Mg-Ca-3Zn-CaCO3 at 600 °C sintering (58.3045 mpy) and the highest occurs in alloy 86Mg-Ca-3Zn-10CaCO3 at 650 °C sintering (91.4007 mpy). Surface morphology of the alloy after the corrosion process is the type of volcano. This localized corrosion occurs where an electrochemical reaction takes place to form a distinctive structure with a circle and a hole in the middle.
CORROTION RATE AND MORPHOLOGY OF POROUS METAL ALLOY Mg-Ca-Zn WITH CaCO3 AS FOAMING AGENT Aprilia Erryani; Franciska Pramuji Lestari; Dhyah Annur; Muhammad Ikhlasul Amal; Ika Kartika
Widyariset Vol 4, No 1 (2018): Widyariset
Publisher : Pusbindiklat - LIPI

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (2043.584 KB) | DOI: 10.14203/widyariset.4.1.2018.9-20

Abstract

Magnesium alloy is a material that has been developed as a biodegradable implant material in orthopedic applications. Magnesium alloys have good biocompatibility, biodegradability, and good mechanical properties which make them have the potential to be used as a biomedical material. The main objective of this paper is to investigate corrotion rate and morphology after corrotion of biocompatibility of implant-based alloys Mg-Ca-Zn with CaCO3 as a foaming agent. Mg-Ca-Zn Alloy was made by the method of powder metallurgy with the addition of CaCO3 as a foaming agent with three variations of composition (96Mg-Ca-3Zn-CaCO3, 91Mg-Ca-3Zn-5 CaCO3, and 86Mg-Ca-3Zn-10 CaCO3 wt%). Sintering process was carried out at 600 °C and 650 °C with a holding time of five hours. Corrosion test was performed using G750 Gamry Instrument in accordance with ASTM standard G5-94. Simulated body fluid electrolyte used is Hank's solution with a pH value of 7.4 and a temperature of 37 °C. Then the analysis of the microstructure after corrosion test was conducted using scanning electron microscopy (JEOL, JSM-6390A Japan) equipped with energy dispersive spectrometry data (EDS). Alloy corrosion rate of Mg-Ca-Zn-CaCO3 increases with the amount of CaCO3 in the alloy and the temperature rise in the sintering. From the test results, the smallest corrosion rate is in the alloy 91Mg-Ca-3Zn-CaCO3 at 600 °C sintering (58.3045 mpy) and the highest occurs in alloy 86Mg-Ca-3Zn-10CaCO3 at 650 °C sintering (91.4007 mpy). Surface morphology of the alloy after the corrosion process is the type of volcano. This localized corrosion occurs where an electrochemical reaction takes place to form a distinctive structure with a circle and a hole in the middle.
INFLUENCE OF CARBON AND NITROGEN ADDITION ON THE CORROSION RESISTANCE OF Co-28Cr-6Mo-0,8Si-0,8Mn-0,4Fe-0,2Ni ALLOYS Fendy Rokhmanto; Cahya Sutowo; Ika Kartika
Widyariset Vol 4, No 1 (2018): Widyariset
Publisher : Pusbindiklat - LIPI

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (1236.98 KB) | DOI: 10.14203/widyariset.4.1.2018.1-8

Abstract

Cobalt alloys is one of the implant materials that is used in orthopedic and dentistry, because of its biocompatibility, good mechanical properties, and high corrosion resistance. The mechanical properties and corrosion resistance can be enhanced by thermomechanical treatment and addition of alloying element. Carbon and nitrogen were added to enhance mechanical properties and high corrosion resistance. Effect of carbon variation and nitrogen to the corrosion resistance in Co-Cr-Mo (CCM) alloys were measured by corrosion measurement system (CMS) device in Hank’s Solutions after thermomechanical treatment process. Corrosion rate of Co-Cr-Mo alloys with carbon variation dropped to 5.8 x 10-4 mmpy and 5.2 x 10-4 mmpy with carbon variation and nitrogen. Decreasing corrosion rate indicated that the corrosion resistance of alloys is increased with the addition of carbon and nitrogen.
Co-Authors Aprilia Erryani Cahya Sutowo Dhyah Annur Fendy Rokhmanto Franciska Pramuji Lestari Muhammad Ikhlasul Amal