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Kinetic And Equilibrium Studies On The Adsorption Of Pb2+ And Zn2+ From Aqueous Solution Using Coco-Peat By Batch Experiment Kukuh Jalu Waskita; Augustus C. Resurreccion; Wawan Budianta
Journal of Applied Geology Vol 4, No 1 (2012)
Publisher : Geological Engineering Department Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (362.493 KB) | DOI: 10.22146/jag.7194

Abstract

The presence of heavy metals in surface water, which is common in mining area pose harmful effect to human health and the environment. Recently, cocopeat has been studied as an effective sorbent material for removing heavy metals from wastewater. In this study, kinetic was done by analyzing the distribution of the heavy metal in sorbent material and liquid phase after mixing 50 mg/L solution of lead (Pb2+) and zinc (Zn2+)in single solute system with 0.1 g of coco-peat, that were consequently shaken at 5, 10, 15, 30, 60, 120, 180 and 360 minutes. To determine the equilibrium adsorption isotherm for each heavy metal, the solutions of 10, 20, 30,40 and 50 mg/L of Pb2+ and Zn2+ were prepared separately. Two different pH levels (natural pH, and pH 4) were setto describe the sorption behavior of Pb2+ and Zn2+ of each heavy metal.Using data from batch experiments, appropriate kinetic (time dependency) and equilibrium (isotherm) models were fitted on the sorbent material and liquid phase concentrations to determine adsorption parameters. Pseudo second-order kinetic model fitted well to the kinetic data due to chemisorption that happened during experiments. In other hand, Langmuir model fitted well to the equilibrium, this indicates that the sorption of lead and zinc on coco peat is monolayer and that the adsorbent’s surface is homogenous. The increase of heavy metals adsorption following the increase of pH might be due to negative charge of coco peat surface. Pb2+ adsorbed more than Zn2+ because ion with high hydration enthalpy will have smaller amount of ion adsorbed. The hydration enthalpies for Pb2+ and Zn2+ are 23 kJ/kg and 113 kJ/kg, receptively. Considering all the factors that we have discussed, cocopeat has high efficiency to remove the heavy metals from wastewater. Keywords: Coco-peat, adsorption, batch experiment, kinetic, equilibrium.
Lead Contamination In Soil Of Yogyakarta City, Indonesia Wawan Budianta
Journal of Applied Geology Vol 4, No 2 (2012)
Publisher : Geological Engineering Department Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (920.856 KB) | DOI: 10.22146/jag.7200

Abstract

This paper investigates on Pb concentrations and mobility in soil of overall Yogyakarta City, Indonesia. The objectives of this study include to investigate Pb concentrations in the surface soil throughout Yogyakarta and to study their possible sources and potential environmental impacts. The soil samples from 168 locations in Yogyakarta was obtained, representing different land use and traffic conditions. Spatial analysis and sequential extraction analysis were performed. Generally, contour pattern of Pb value clearly shows that high value is concentrated in the middle and few north part of the study area, confirmed by traffic condition in the study area. In general, the results of sequential extraction analysis shows that Pb was predominantly associated with exchangeable fraction. The presence of lead in the exchangeable fractions may pose a serious environmental concern since they are highly soluble and potentially bio-available in the soil of study area. Keywords: Soil, lead contamination, GIS, sequential extraction.
IMPROVEMENT OF EXPANSIVE SOIL BY ELECTRO-KINETIC METHOD Tran Thi Thanh Thuy; Doni Prakasa Eka Putra; Wawan Budianta; Hemanta Hazarika
Journal of Applied Geology Vol 5, No 1 (2013)
Publisher : Geological Engineering Department Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (829.251 KB) | DOI: 10.22146/jag.7207

Abstract

The roadway in Karangjati, Ngawi Regency, East Java, Indonesia, which is underlain by expansive soil, is susceptible to damage due to volume change. This research aims to improve the engineering properties, such as consistency limits, compressibility, and undrained shear strength of the montmorillonite dominated soil in this area using an electrokinetic stabilization method. Four electro-kinetic experiments were conducted using different electrolytes (calcium chloride or pure water) under different conditions (no-flow or flow water). The results show that, pH values of all soil samples decreased at anolyte and increased at catholyte. Atterberg limits of the soil samples were found to increase, where the liquid limit (LL) range of 79.72– 86.14%, plastic limit (PL) 25.22–30.80%, and plasticity index (PI) 53.28–60.92, liquidity Index (LI) 0.91–1.08. The compression index Cc was 0.50– 0.742. Undrained shear strength of treated soil range of 7–11 kPa. Moreover, strengthening degree of the treated soils achieve 304–556%. The soil improvement was achieved by decreasing the Atterberg limits, and compressibility and increasing the undrained shear strength. Applying calcium chloride and flow water condition were the most effective methods for the soil improvement. The mineralogical compositions of the soil samples did not change after the treatment. Keywords: Electro-kinetic stabilization, electro chemical injection, clayey soil improvement.
Geo-mechanics and Hydraulic Conductivity Study of Claystone in Boyolali, Central Java, Indonesia Wawan Budianta; Monika Aprianti Popang; Widyawanto Prastistho; Jiro Takemura
Journal of Applied Geology Vol 4, No 1 (2019)
Publisher : Geological Engineering Department Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (2671.096 KB) | DOI: 10.22146/jag.48738

Abstract

Claystone middle Miocene age were found in Wonosegoro sub-district, Boyolali region, Central Java, Indonesia. The purpose of the paper is to examine and discuss the geology and typical behavor of this claystone and its micro-level mechanism. The hydraulic conductivity was assessed using consilidated apparatuses; 150 mm diameter column mound using aggregated sample and 60 mm oedometer mould using slurry sample as a reference. Claystone materials used were treated under various conditions. In long term test under constand vertical stress and hydraulic gradient, the hydraulic conductvity decreases with time although the volume of void volume of the sample increased by swelling. Water contens of the individul aggregated increased by swelling, by which strength of particles decreases with and aggregate breakdown was enchanced. As a result, large void created by large particles could be redused in its size, leading the reduction of hydraulic conductuvity. The hydralic conductivities (K values) obtained from the aggregated sample varied in a broad range compared with those from slurry sample. In the test using the higher percentage of gravel-sized aggregate (up until couarse gravel-sized; retained in 26.5 mm sieve), K values changed from 10-5 to 10-7 m/s under vertical stresses from 5 up to 245 kPa. The test was repeated using smaller percentage of gravel-sized aggregate (up until fine gravel-sized, retained in 4.75 mm sieve) and the observed K values changed from 10-5 to 10-10 m/s. While the K values obtained in the specimen made from surry under same vertical stresses was 10-9 to 10-11 m/s. All of the extruded aggregate samples had higher water content than the initial ones, which suggest the alteration mechanism of soled consolidation phase to more deformable plastic phase, whice enables thesample to decrease the void size. These results conclude that using coarse gravel-sized aggregated, which is a reasonable scenario of a practically feasible aggregate size in a field, may noy produce the aimed hydraulic conductivity by the regulated standard. Therefore, breakdown of the aggrgate size and enchament of swelling are crucial factors for the application of the clay stones as a barrier material.
Phytoremediation of Heavy Metals Contaminated Soil in Artisanal Gold Mining at Selogiri, Wonogiri District, Central Java, Indonesia Bambang Suryo Madyo Pranoto; Wawan Budianta
Journal of Applied Geology Vol 5, No 2 (2020)
Publisher : Geological Engineering Department Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (11834.112 KB) | DOI: 10.22146/jag.54586

Abstract

Artisanal gold mining (ASGM) is commonly found in Indonesia, particularly in Wonogiri District, Central Java. One of the impacts of ASGM activity is soil contamination influence by mining waste. The objective of this study to investigate the potential use of Amaranthus spinosus L. and Jatropha curcas for remediation of Pb and As in contaminated soil. Phytoremediation experiment was conducted by using Amaranthus spinosus L. and Jatropha curcas and evaluate the effectiveness of both plants as a hyperaccumulator. The result shows that the higher Pb and As concentration was found in roots rather than shoots in both plants, however, the use of Jatropha curcas seems more effective on reducing Pb and As concentrations more than Amaranthus spinosus L in both shoots and roots. Generally, the use of both hyperaccumulator plants was more effective in Pb remediation compared to As. This phytoremediation experiment revealed that the use of both hyperaccumulator plants reduces the concentrations of Pb and As in contaminated soil, which of the critical point leading to the entry of Pb and As into the food chain.
Assessment of heavy metal contamination in soil around Piyungan Landfill, Yogyakarta, Indonesia Mufid Muyassar; Wawan Budianta
Journal of Applied Geology Vol 6, No 2 (2021)
Publisher : Geological Engineering Department Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (530.069 KB) | DOI: 10.22146/jag.65651

Abstract

One of the negative impacts of the landfill as solid waste disposal is soil contamination by heavy metals. This study assessed heavy metals impact, especially Pb, Cu, Zn, and Cd, in the soil in Piyungan landfill, Bantul, Yogyakarta, Indonesia. The assessment was conducted by analyzing 15 soil samples from 25 cm depth in the study area, which was divided into three-zone. The study results showed that generally, the highest content of metals was found in zone II, which is located near or directly situated in a landfill site. The pollution index (PI) calculated showed in order Cd>Cu>Pb>Zn. The result also indicates that Cd has the highest pollution index and even the highest risk compared to Pb, Cu, and Zn. The eco-risk index (RI) calculation showed that the value was 29 to 70 demonstrating a low class. The result also indicates that the accumulation of heavy metals investigated in this study was normal, and that the ecological risk was relatively low.
Assessment of groundwater leakage source using hydrochemical data and isotopes in the Pandanduri dam tunnel, Lombok Island, Indonesia Heru Hendrayana; Doni Prakasa Eka Putra; Hendy Setiawan; I Gde Budi Indrawan; Wawan Budianta; Wahyu Wilopo
Journal of Degraded and Mining Lands Management Vol 10, No 1 (2022)
Publisher : Brawijaya University

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.15243/jdmlm.2022.101.3961

Abstract

Leakage or seepage in reservoirs and dams has the potential for structural instabilities persuaded by water leakage pathways and linked to economic consequences. An environmental isotopic and hydrochemical research was conducted to determine the source and origin of seepages on the tunnel of Pandanduri dam, Lombok Island, Indonesia. This study aimed to examine the source of the tunnel leak on the dam site and the origin or source of water at the point of leakage based on water chemistry data and stable isotopes. To identify the source of the leakage water in the tunnel dam, 33 samples of the leakage water, groundwater, reservoir water, river water, and rainfall water were taken for chemical and isotopic composition analysis. The field measured the reservoir level, spring discharges, and physicochemical parameters (EC, pH, TDS, TSS). The physicochemical parameters show that the leakages water is similar to reservoir water. The types of leakage water in the tunnel belong to alkaline water, predominantly sulfate-chloride. This type of water is deep groundwater with a higher sulfate and chloride concentration than surface water or shallow groundwater. Hydrochemical and isotope analysis showed that water origin at leakage points is dominated by groundwater.
Stabilisasi merkuri pada limbah tambang dengan menggunakan zeolit alam Wawan Budianta; Arifudin Idrus; Winarto Kurniawan; Widyawanto Prastistho
Al-Ard: Jurnal Teknik Lingkungan Vol. 8 No. 2 (2023): Maret
Publisher : Department of Environmental engineering, Faculty of Science and Technology, Islamic State University Sunan Ampel Surabaya

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.29080/alard.v8i2.1779

Abstract

Mercury contamination caused by artisanal gold mining waste would become an environmental problem if there were no remediation actions. This study aimed to investigate the ability of natural zeolite obtained from Gunungkidul Yogyakarta to stabilize mercury in mining waste or tailing. Tailing samples were obtained from three locations on Kulon Progo, Wonogiri, and Banyumas, and the natural zeolite sample was obtained from Gunungkidul, Yogyakarta. The batch experimental study was conducted to test the ability of the effectiveness of natural zeolite in stabilizing mercury in tailing. The result of the study shows that the natural zeolite used in the experimental study can be used to reduce the mercury concentration in tailing. The natural zeolite's ability for stabilization varies and depends on the initial mercury concentration in tailing and the natural zeolite dose.
PENCEMARAN TANAH OLEH Pb DAN Cd DI SEKITAR TEMPAT PEMBUANGAN AKHIR (TPA) PUTRI CEMPO, KOTA SURAKARTA Afra Ghaida Fathassabilla; Wawan Budianta
KURVATEK Vol 8 No 1 (2023): Energy Management and Sustainable Environment
Publisher : Institut Teknologi Nasional Yogyakarta

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.33579/krvtk.v8i1.3919

Abstract

One of the impacts of rapid population growth is the problem of waste management. One of the impacts of waste disposal at the landfill is soil contamination due to heavy metals originating from waste disposed of. This study aims to determine the concentration and distribution of heavy metals in the soil laterally and vertically around Putri Cempo Landfill through spatial analysis. Sampling was carried out at 14 points with 3 different depths, namely 10 cm, 30 cm, and 60 cm. Data analysis was performed on 42 soil samples, including analysis of grain size, pH and organic content, heavy metal content, and distribution of heavy metals. The results showed that the concentrations of Pb and Cd at the three depths of the soil samples were mostly above the background values of each heavy metal. The distribution patterns of the two heavy metals laterally in the study area were relatively different, while the vertical distribution of contaminants decreased in concentration as the distance from the soil surface increased.
PENGARUH KARAKTERISTIK MINERALOGI TERHADAP KAPASITAS TUKAR KATION ZEOLIT ALAM PACITAN, JAWA TIMUR Wawan Budianta; I Wayan Warmada; Makruf Nurudin
KURVATEK Vol 8 No 1 (2023): Energy Management and Sustainable Environment
Publisher : Institut Teknologi Nasional Yogyakarta

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.33579/krvtk.v8i1.4004

Abstract

The study aimed to investigate the influence of mineralogical and chemical composition on the cation exchange capacity of natural zeolite obtained from Pacitan, East Java. Ten natural zeolite samples were analyzed for mineralogical and chemical composition and cation exchange capacity. The result of the study showed that the natural zeolite samples have a mordenite-type mineral in dominant, with the percentage in vary between 32% to 38%. Based on chemical analysis, the natural zeolite samples consist of SiO2 ranging from 61% to 66% and Al2O3 ranging from 9% to 11%, which are then calculated to obtain for Si/Al ratio. The value of cation exchange capacity obtained ranges from 70 meq/100 g to 91 meq/100 g, with 82 meq/100 g on average. This variation was most probably influenced by the difference in zeolite mineral type presence and other minerals. Moedenite mineral type was suspected as the most dominant, which influenced the cation exchange capacity value obtained in this study. The cation exchange capacity of the samples gives a positive correlation to the content of the mordenite mineral, total microporous mineral, and Si/Al ratio. The result of the study is expected to contribute to the information on the natural zeolite in the area for agricultural and environmental fields.