Eko Hanudin
Departemen IImu Tanah, Fakultas Pertanian, Universitas Gadjah Mada, Jalan Flora No 1, Bulaksumur, Yogyakarta

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Journal : Journal of Tropical Soils

Leaching Characteristics of Udipsamment Ameliored by Mineral Soil and Adhesive Polymer Fibrianty Fibrianty; Eko Hanudin; Azwar Ma’as
JOURNAL OF TROPICAL SOILS Vol 27, No 1: January 2022
Publisher : UNIVERSITY OF LAMPUNG

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.5400/jts.2022.v27i1.17-25

Abstract

Udipsamment  is  characterized  by  sand  fraction  > 95%,  loose,  and  very  high  leaching. This  study  aimed  to determine  the  effect  of  mineral  soil  ameliorants  and  adhesive  polymers  on  the character  of  nutrient leaching  in  Udipsamment.  The  leaching   study  in  lysimeters  used  a completely  randomized  design  with three  replications.  The  treatments  consist  of  bagasse  (B),  mineral  soil included  Inceptisol  (I)  and Vertisol  (V),  and adhesive  polymers included tapioca  1% and 2% (T1  and  T2),  tapioca  dregs  1%  and  2  %  (A1 and  A2),  Polyvinylalcohol  0.1%  and  0.2%  (P1  and  P2).  Combination  of  treatments  are  IB,  VB,  IBT1, IBT2,  VBT1,  VBT2,  IBA1,  IBA2, VBA1 ,  VBA2 , IBP1,  I BP2, VBP1,  and  VBP2.  Observations  were made  before  and  after  leaching.  The  research  showed  that  VBT2  increases moisture-holding  capacity. Amelioration improved the ability of  Udipsamment  to  hold  nutrients,  after leaching  for  six  months,  there was  a  decrease  in  organic  C,  total  N,  and  available  P  compared to before  leaching.  Amelioration increased the  soil  CEC,  even up  to  the  sixth  month  leaching,  the soil  CEC  showed  a  higher value  than  before  leaching.  The  amount  of  clay  fraction  was  relatively  uniform  between  the  surface  and  the  bottom of  the lysimeter,  indicating that   the adhesive   polymer  successfully  bonding  the  clay-sand  particles  and prevented clay leaching.
Phosphate Adsorption Capacity of Allophane from Two Volcanic Mountains in Indonesia Tandaditya Ariefandra Airlangga; Naoto Matsue; Eko Hanudin; Erni Johan
JOURNAL OF TROPICAL SOILS Vol 25, No 1: January 2020
Publisher : UNIVERSITY OF LAMPUNG

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.5400/jts.2020.v25i1.39-46

Abstract

Allophane is known as clay mineral with high capacity of phosphate adsorption via ligand-exchange mechanism. This study aims to compare the phosphate adsorption characteristics by allophane from Mt. Merapi and Mt. Lawu in relation to its chemical and mineralogical properties. The results  of X-Ray Flourescence analysis shows that both allophane samples from Merapi and Lawu have low Si/Al ratio, i.e. 1.18 and 1.16, respectively. Infrared spectral characteristics of the allophane materials indicated that the main adsorption bands appeared at the range of 2700-3700 cm-1 (due to stretching vibration of all hydroxyl (OH) groups), 1400 – 1800 cm-1 (vibration of HOH deformation), and 650 - 1200 cm-1 (vibration between the Si-O-Al). Adsorption experiment of phosphate on allophane samples were conducted at initial adsorbate concentration of up to 2.0 mM and at pH 4.0 and 8.0. Phosphate adsorption capacity of allophane shows that both allophane from Merapi and Lawu are categorized as very high in adsorbing phosphate and fit well with the Langmuir adsorption equation. Phosphate adsorption increases with decreasing pH due to the positive charge sites such as Al-OH2+ in the allophane structure increase. Another reason is the negative charge of phosphate gradually decreases from -2 to -1 with decreasing pH, and the repulsive force between the negatively charged Si-O- in the allophane structure and phosphate anions decreases.