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Effect of UV Aging on Physical Properties of Vulcanized Rubber with the Addition of Reclaimed Rubber Muh. Wahyu Syabani; Yuli Suwarno; Mertza Fitra Agustian
Logic : Jurnal Rancang Bangun dan Teknologi Vol 19 No 3 (2019): November
Publisher : Pusat Penelitian dan Pengabdian kepada Masyarakat (P3M) Politeknik Negeri Bali

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (693.895 KB) | DOI: 10.31940/logic.v19i3.1469

Abstract

Rubber solid waste amount increased continuosly and caused environmental problem since it is very difficult to be naturally degraded. Therefore, the interest of using rubber waste as raw material for new rubber product is increased. Reclaimed rubber can be used as filler aditif for rubber processing. The aim of this research was to study the effect of UV aging on the rubber product as the reclaimed filler added. The mixing of the rubber and the additives used the kneader and open mill. The vulcanization process was done by hydraulic press. In this research, the reclaimed rubber addition was varied as follows: 12,5; 37,5 and 62,5 phr. The products quality differences before and after the UV aging evaluated using physical tests. The result of FTIR showed that the polymer chain were broken by ultraviolet radiation. The physical test gives result that the hardness and tensile strength decreased, but the elongation is increased after UV aging.
Pengaruh Waktu dan Suhu Penyimpanan Kompon Karet terhadap Karakteristik Vulkanisasi Muh. Wahyu Syabani; Suharyanto Suharyanto; Mertza Fitra Agustian; Lestari Hetalesi Saputri
Jurnal Teknologi Vol 10, No 2 (2023): Jurnal Teknologi
Publisher : Universitas Jayabaya

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.31479/jtek.v10i2.223

Abstract

A rubber compound is an intermediate product resulting from mixing rubber with other additives before being molded through a vulcanization process. Frequently, there is a delay between the compounding process and vulcanization, therefore proper storage procedures must be prepared. The presence of a vulcanizing agent, activator, and accelerator in the compound allows the vulcanization reaction to occur during the storage period. This study aims to analyze the effect of the storage time and temperature of rubber compounds on rubber vulcanization characteristics. The rubber compound is stored at room temperatures of 25oC and 32oC. On the 1st, 3rd, and 5th day of storage, the compounds were tested using a rheometer to obtain vulcanization parameter data. The values of MH, ML, ts2, tc90, cure rate index (CRI), and effective torque of each treatment were studied. The results showed that the storage time of the compound affected each of the observed parameters. In the range of 5 days, the longer time indicates the formation of polysulfide crosslinks in the rubber polymer chain network. Higher storage temperature also faster reaction rate during storage. The increasing number of cross-links resulting a longer induction period dan vulcanization time, lower CRI, and effective torque.