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Mustofa Mustofa
Department of Pharmacology and Toxicology, Faculty of Medicine, Universitas Gadjah Mada, Bulaksumur Yogyakarta 55281
Chemical Engineering, Chemistry & Bioengineering Chemistry

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SYNTHESIS, CHARACTERIZATION AND ADSORPTION TEST OF POLY-TETRA-p-PROPENYLTETRAHYDROXYCALIX[4]ARENE FOR CADMIUM ION Triana Kusumaningsih; Jumina Jumina; Dwi Siswanta; Mustofa Mustofa; Keisuke Ohto; Hidetaka Kawakita
Indonesian Journal of Chemistry Vol 11, No 2 (2011)
Publisher : Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (298.647 KB) | DOI: 10.22146/ijc.21408

Abstract

Synthesis, characterization and adsorption test of poly-tetra-p-propenyl-tetrahydroxycalix[4]arene for cadmium ion had been done. The synthesis was carried out in five steps, which were (1) synthesis of p-t-butylcalix[4]arene from p-t-butylphenol, (2) debutylation of p-t-butylcalix[4]arene, (3) tetraallylation of 25, 26, 27, 28 tetrahydroxycalix[4]arene with NaH and allylbromide in dry tetrahydrofuran, (4) Claissen rearrangement of 25, 26, 27, 28-tetrapropenyloxy- calix[4]arene, and (5) polymerization of tetra-p-propenyltetrahydroxycalix[4]arene to yield poly-tetra-p-propenyltetrahydroxycalix[4]arene. Analysis of products was performed using melting point analysis, FT-IR, and 1H NMR spectrometers. The yield of polymerization was 80.35% and m.p > 380 °C. Characterization of poly-tetra-p-propenyltetrahydroxycalix[4]arene was done using SEM and SAA. Structure of poly-tetra-p-propenyltetrahydroxycalix[4]arene was sparsely porous with crosslinked netty architectures, and possessed surface area of 46.572 m2/g. The application of poly-tetra-p-propenyltetrahydroxycalix[4]arene in the adsorption of Cd(II) cation had also been conducted. Adsorption parameters investigated included medium pH and contact time as well as adsorption isotherm. The resin could be applied as a good adsorbent in the adsorption of Cd(II) metal cation. The adsorption followed Langmuir isotherm model, where the measured adsorption capacity, adsorption constant (K), and adsorption energy were 8.5933 x 10-2 mmol/g, 485 L/mmol, and 32.653 KJ/mol, respectively.
ADSORPTION OF Pb(II), Cd(II), AND Cr(III) FROM AQUEOUS SOLUTION BY POLY-5-ALLYL-CALIX[4]ARENE TETRA CARBOXYLIC ACID Desi Suci Handayani; Jumina Jumina; Dwi Siswanta; Mustofa Mustofa; Keisuke Ohto; Hidetaka Kawakita
Indonesian Journal of Chemistry Vol 11, No 2 (2011)
Publisher : Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (303.103 KB) | DOI: 10.22146/ijc.21409

Abstract

The aim research is application of poly-5-allyl-calix[4]arene tetra carboxylic acid as adsorbent of heavy metal cations. Adsorption was carried out towards Pb(II), Cd(II) and Cr(III) ions in batch system. Several variables including pH, contact time and initial concentration of metal ions were determined. The optimum adsorption conditions were achieved at pH 6.0 for Cd(II) and Cr(III), while at pH 5.5 for Pb(II) ions. In addition, the optimum contact time of Pb (II), Cd(II) and Cr(III) ion adsorption were 180 min. The adsorption kinetics of Pb(II), Cd(II) and Cr(III) ions using the calixarene polymer adsorbent followed a pseudo 2nd order kinetics model, with adsorption rate constants of 2x10-2; 5x10-3, and 3.1x10-2 g mole-1 min-1, respectively. Furthermore, the adsorption isotherm of Pb(II) and Cd(II) ions tends to follow the Freundlich isotherm, whereas the adsorption of Cr (III) tends to follow the Langmuir isotherm. The adsorption capacity of Pb(II), Cd(II) and Cr(III) metal ions were 104.04, 61.78 and 228.69 μmole/g, with adsorption energy of 24.87; 21.62 and 31.07 KJ/mole, respectively.
SYNTHESIS OF TETRA-p-PROPENYLTETRAESTERCALIX[4]ARENE AND TETRA-p-PROPENYLTETRACARBOXYLICACIDCALIX[4]ARENE FROM p-t-BUTYLPHENOL Triana Kusumaningsih; Jumina Jumina; Dwi Siswanta; Mustofa Mustofa
Indonesian Journal of Chemistry Vol 10, No 1 (2010)
Publisher : Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (237.654 KB) | DOI: 10.22146/ijc.21491

Abstract

A research has been conducted to synthesize tetra-p-propenyltetraestercalix[4]arene and tetra-p-propenyltetracarboxylicacidcalix[4] arene using p-t-butylphenol as a starting material. The synthesis was carried out in following stages, i.e (1) synthesis of p-t-butylcalix[4]arene from p-t-butylphenol, (2) debutylation of p-t-butylcalix[4]arene, (3) tetraallilation of 25,26,27,28-tetrahydroxycalix[4]arene with NaH and allilbromida in dry tetrahydrofuran, (4) Claissen rearrangement of 25,26,27,28-tetrapropenyloxycalix[4]arene, (5) esterification of tetra-p-propenyltetrahydroxycalix[4]arene, (6) hydrolisis of tetra-p-propenyltetraestercalix[4]arene. The all structures of products were observed by means of melting point, FTIR, and 1H-NMR spectrometers. Tetra-p-propenyltetraestercalix[4]arene compound was obtained as yellow liquid product in 55.08% yield. Tetra-p-propenyltetracarboxylicacidcalix[4]arene compound was obtained as white solid product with the melting point 135-137 °C at decomposed and in 70.05% yield.
Co-Authors Desi Suci Handayani Dwi Siswanta Dwi Siswanta Hidetaka Kawakita Jumina Jumina Jumina Jumina Keisuke Ohto Triana Kusumaningsih Triana Kusumaningsih