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All Journal VALENSI JURNAL KIMIA SAINS DAN APLIKASI The Journal of Pure and Applied Chemistry Research Jurnal Riset Kimia EduChemia: Jurnal Kimia dan Pendidikan Science and Technology Indonesia ALCHEMY Jurnal Penelitian Kimia Indonesian Journal of Chemistry PRIMA: Journal of Community Empowering and Services Molekul: Jurnal Ilmiah Kimia

Triana Kusumaningsih

Department Of Chemistry, Faculty Of Mathematics And Natural Science,Universitas Sebelas Maret

Author-ID : 303203

Agriculture, Biological Sciences & Forestry Biochemistry, Genetics & Molecular Biology Chemical Engineering, Chemistry & Bioengineering Chemistry Education Energy Engineering Environmental Science Materials Science & Nanotechnology Medicine & Pharmacology Physics

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Isolation and Elucidation Structure of 28-Hydroxy-3-Friedelanone of Nyamplung (Callophyllum inophyllum, Linn.) Leaves Triana Kusumaningsih; Muhammad Widyo Wartono; Nais Puji Wijanarti
The Journal of Pure and Applied Chemistry Research Vol 9, No 2 (2020): Edition May-August 2020
Publisher : Chemistry Department, The University of Brawijaya

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.21776/ub.jpacr.2020.009.02.518

The isolation triterpenoid from Nyamplung (Callophyllum inophyllum, Linn.) leaves has been conducted. The isolation was employed by maceration using ethanol as solvent and liquids extraction using ethyl acetate. Ethyl acetate extract was partitioned successively using nonpolar solvent with hexane, dichloromethane, and diethyl ether, respectively. The diethyl ether extract was purified by column chromatography. The isolated compound of fraction D1 was obtained as white solids crystal with yield of 0.0035%. The isolated compound was determined based on the FTIR, 1HNMR, 13CNMR, HSQC, and HMBC spectra. The isolated compound was identified as 28-hydroxy-3-friedelanone.

SYNTHESIS OF TETRA-p-PROPENYLTETRAESTERCALIX[4]ARENE AND TETRA-p-PROPENYLTETRACARBOXYLICACIDCALIX[4]ARENE FROM p-t-BUTYLPHENOL Triana Kusumaningsih; Jumina Jumina; Dwi Siswanta; Mustofa Mustofa
Indonesian Journal of Chemistry Vol 10, No 1 (2010)
Publisher : Universitas Gadjah Mada

A research has been conducted to synthesize tetra-p-propenyltetraestercalix[4]arene and tetra-p-propenyltetracarboxylicacidcalix[4] arene using p-t-butylphenol as a starting material. The synthesis was carried out in following stages, i.e (1) synthesis of p-t-butylcalix[4]arene from p-t-butylphenol, (2) debutylation of p-t-butylcalix[4]arene, (3) tetraallilation of 25,26,27,28-tetrahydroxycalix[4]arene with NaH and allilbromida in dry tetrahydrofuran, (4) Claissen rearrangement of 25,26,27,28-tetrapropenyloxycalix[4]arene, (5) esterification of tetra-p-propenyltetrahydroxycalix[4]arene, (6) hydrolisis of tetra-p-propenyltetraestercalix[4]arene. The all structures of products were observed by means of melting point, FTIR, and 1H-NMR spectrometers. Tetra-p-propenyltetraestercalix[4]arene compound was obtained as yellow liquid product in 55.08% yield. Tetra-p-propenyltetracarboxylicacidcalix[4]arene compound was obtained as white solid product with the melting point 135-137 °C at decomposed and in 70.05% yield.

SYNTHESIS OF POLY-5,7-DIALLYL-25,26,27,28-TETRAHYDROXYCALIX[4]ARENE Desi Suci Handayani; Jumina Jumina; Maulidan Firdaus; Triana Kusumaningsih
Indonesian Journal of Chemistry Vol 10, No 1 (2010)
Publisher : Universitas Gadjah Mada

The synthesis of poly-5,7-diallyl-25,26,27,28-tetrahydroxycalix[4]arene were performed in experimental series as follows: (1) Cyclotetramerization of p-t-butylphenol with NaOH and paraformaldehyde to p-butylcalix[4]arene, (2) Debutylation of p-butylcalix[4]arene using AlCl3 and phenol to tetrahydroxycalix[4]arene, (3) Allylation reaction using allylbromide to diallyloxy-dihydroxycalix[4]arene, (4) Claisen rearrangement reaction, (5) Cationic polymerization to diallylcalix[4]arenes. All of the synthesized products were analyzed by means of IR spectrometer and 1H-NMR spectrometer. The result of 25,27-diallyloxy-26,28-dihydroxycalix[4]arene synthesis was white crystals having m.p. 205-207 °C in 80.95% yield. The synthesis of 5,7-diallyl-25,26,27,28-tetrahydroxy-calix[4]arene gave light yellow crystals having m.p. 214-216 °C in 78.67% yield. The polymerization gave poly(5,7-diallyl-25,26,27,28-tetra-hydroxycalix[4]arene) having m.p. 338-340 °C, in 60% yield. Its estimated has a relative molecular weight of 18,738 g/mol with the number of unit repetition about 37 monomer units.

Stigmasterol and Stigmasterone from Methanol Extract of Calophyllum soulattri Burm. F. Stem Bark Surya Dewi Marliyana; Fajar Rakhman Wibowo; Desi Suci Handayani; Triana Kusumaningsih; Venty Suryanti; Maulidan Firdaus; Ema Nur Annisa
Jurnal Kimia Sains dan Aplikasi Vol 24, No 4 (2021): Volume 24 Issue 4 Year 2021
Publisher : Chemistry Department, Faculty of Sciences and Mathematics, Diponegoro University

Stigmasterol and Stigmasterone from Methanol Extract of Calophyllum soulattri Burm. F. Stem Bark. Calophyllum soulattri Burm. F. has been widely used for herbal medicine. Phytochemical investigation of C. soulattri contains a secondary metabolite of the steroid class. Steroid compounds have various biological activities, such as anti-inflammatory, antioxidant, antiproliferative, antibacterial, antimalarial, and anticancer. Two secondary metabolites steroids have been isolated and identified from the stem bark extract of C. soulattri. Isolation was carried out through the extraction (maceration), fractionation, and purification stages. Maceration is carried out using methanol as a solvent. Fractionation was carried out by vacuum liquid chromatography (VLC), and purification was by flash column chromatography. Identification of combined fractions and determination of pure isolates were used through thin-layer chromatography (TLC). The solvent used in the chromatography methods was a mixture of n-hexane and ethyl acetate. The structure isolates were identified by FTIR, 1H NMR, and 13C NMR and compared with literature data. Secondary metabolites steroids that have been isolated are identical compounds to stigmasterol and stigmasterone.

Solvent-less Oxidation of Aromatic Alcohols Using CrO3/Al2O3 under Ultrasonic Irradiation Maulidan Firdaus; Triana Kusumaningsih; Ichsan Arifagama; Zuhdi Alqowamul Amin
Jurnal Kimia Sains dan Aplikasi Vol 25, No 8 (2022): Volume 25 Issue 8 Year 2022
Publisher : Chemistry Department, Faculty of Sciences and Mathematics, Diponegoro University

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.14710/jksa.25.8.280-285

Alcohol oxidation plays an essential contribution to the chemical industry. Innovative green techniques, such as ultrasound irradiation, could be economically remarkable by enhancing reaction yield. In this research, the design and improvement of a new green ultrasound-assisted oxidation of alcohols procedure using CrO3 supported by Al2O3 with the addition of a small amount of t- butanol were reported. The oxidation of alcohols was also done without ultrasound irradiation to study the sonochemical effect. Based on FTIR and GC/MS analyses, the alcohols were effectively oxidized into their corresponding aldehydes in satisfactory yields (74–93%). The yield of the obtained aldehydes was increased by applying the ultrasonic irradiation technique, and no over-oxidation products were found. Overall, the innovative procedure offers several benefits, such as being easy to use, environmentally friendly, capable of improving yields, and having shorter oxidation times.

Preparation and Characterization of PVA/Na-CMC Hydrogel from OPEFB Cross-Linked by Maleic Anhydride Triana Kusumaningsih; Abu Masykur; aulia Syifa Aninditha; Maryam Rahmi Utami
EduChemia (Jurnal Kimia dan Pendidikan) Vol 7, No 1 (2022)
Publisher : Department of Chemical Education Faculty of Teacher Training and Education Universitas Su

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.30870/educhemia.v7i1.12637

PVA/Na-CMC hydrogels were prepared from polyvinyl alcohol (PVA) and Na-CMC isolated from OPEFB. Maleic anhydrous (MA) was introduced as a crosslinking agent during the formation of the hydrogel process. The characterization of the PVA/Na-CMC hydrogels was carried out using Fourier Transform Infrared (FTIR), Scanning Electron Microscope (SEM), and physical characterization methods, including swelling ratio and gel fraction analysis. The addition of MA was observed to increase the number of crosslinks. The optimum PVA/Na-CMC hydrogel composition was achieved at a PVA: Na-CMC ratio of 5:3 (P5C3M), with a pore size of approximately 3.643 ± 0,913 μm, a swelling ratio of 3104%, and a gel fraction value of 72.72%.

Reduction on The Levels of Tannins from Stevia Rebaudiana Extract Using Activated Carbon Triana Kusumaningsih; Nur Jannah Asrilya; Suci Wulandari; Dewi Restu Tri Wardani; Khoirul Fatihin
ALCHEMY Jurnal Penelitian Kimia Vol 11, No 1 (2015): March
Publisher : UNIVERSITAS SEBELAS MARET (UNS)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.20961/alchemy.11.1.111.81-89

Extraction of tannins from leaves of Stevia rebaudiana using ethanol 30% with a temperature variation of 30, 50, 70 and 100oC for 3 hours was performed. Reduction on the levels of tannins in stevia extract is done by using activated carbon. The results showed the greatest weight of the extract at 70oC is 1.008 g and extract relatively alkaline pH. Reduction on the levels of tannins on stevia extracts done by passing the extract of stevia in the burette containing activated carbon as much as 4 times the cycle. Tannin concentration was reduced by 39.74%.

The Physicochemical Characterization, Gelatinization Profile, and Proximate Analysis of Sweet Potato Starch (Ipomoea batatas L.) White, Yellow, and Purple Triana Kusumaningsih; Maulidan Firdaus; Fyan Tri Istiqomah Juneasri
Molekul Vol 17 No 2 (2022)
Publisher : Universitas Jenderal Soedirman

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.20884/1.jm.2022.17.2.5186

Sweet potato (Ipomoea batatas L.) has a considerable potency to be developed in Indonesia because of its high nutritional content and spacious application of sweet potato starch in food and non-food fields. Physicochemical characterization, gelatinization profile, and proximate analysis of sweet potato starch white, yellow, and purple has been carried out. Initially, extraction of starch from white, yellow, and purple sweet potato flour was done using a maceration technique. The starch extract was then analysed to determine its physicochemical properties such as pH, density, boiling point, melting point, swelling capacity, and solubility in water, as well as morphological surface using Scanning Electron Microscopy (SEM). The gelatinization profile of sweet potato starch was measured using the Rapid Visco Analyzer (RVA). The proximate composition of sweet potato starch was also determined. The results showed that yellow sweet potato starch has a high amylose content of 28.17% which thus leads to difficulty in absorbing water, increasing the gelatinization temperature and affecting the structural stability of the starch. The molecular structure of amylose and amylopectin is the main factor influencing the determination of the physicochemical characterization of sweet potato starch. Proximate analysis of sweet potato starch showed high content of amylose (28.17%), water (17.03%), and protein (5.21%) with low amylopectin (71.83%), minerals (1.09%), fat (0.09%), and carbohydrates (76.9%) content. The three varieties of sweet potato show extraordinary potential in food industrial applications because they play a huge part in deciding the suitability of sweet potato starch for specific requirements and interest in developing new and remarkable starch sources.

Synthesis and Characterization of Anethole-lauryl Methacrylate Copolymer via Cationic Polymerization Handayani, Desi Suci; Tahara, Alfia Uke; Firdaus, Maulidan; Suryanti, Venty; Kusumaningsih, Triana; Marliyana, Soerya Dewi; Wibowo, Fajar Rakhman; Wartono, Muhammad Widyo
Molekul Vol 18 No 3 (2023)
Publisher : Universitas Jenderal Soedirman

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.20884/1.jm.2023.18.3.7078

The synthesis of anethole-lauryl methacrylate (LMA) copolymer had been carried out by cationic polymerization using BF3O(C2H5)2 as the initiator without the use of solvent at room temperature (28-30 °C) over atmospheric N2 conditions. Polymerization was conducted by varying LMA concentration i.e. 2%, 4%, and 6%, (w/w) with respect to the anethole weight. Structural determination of co-poly(anethole-LMA) was done using FTIR and 1H-NMR spectrophotometer. The relative molecular weight (Mv) of co-poly (anethole-LMA) was measured by an Ostwald Viscometer at room temperature. Morphological characterization and surface area analysis of co-poly(anethole-LMA) was performed using SEM and SAA, respectively. The successful synthesis of co-poly(anethole-LMA) was proven by the disappearance of vinyl group absorption at 1696, 1638, 965, and 938 cm-1 of the FTIR spectra, as well as the loss of vinyl group proton signals at 6.4-5.5 ppm in the 1H-NMR spectra. Increasing the weight of the LMA affected the characteristics of co-poly(anethole-LMA). The relative molecular weight of co-poly(anethole-LMA) was found to rise by increasing the weight of LMA. The Mv of co-poly(anethole-LMA) 2%, 4%, and 6% were 32378.62, 50611.05, and 65133.79 g/mol, respectively. The morphology of co-poly(anethole-LMA) showed that the surface distance between particles was getting tighter and the highest surface area in co-poly(Anethole-LMA) 6% was 233.80 m2/g.

Green Metrics Evaluation on The Cannizzaro Reaction of p-Anisaldehyde and Benzaldehyde Under Solvent-Free Conditions Firdaus, Maulidan; Firdausi, Nisrina Rahma; Rahmana, Desy Nila; Kusumaningsih, Triana
Jurnal Kimia Valensi Jurnal Kimia VALENSI Volume 9, No. 2, November 2023
Publisher : Syarif Hidayatullah State Islamic University

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.15408/jkv.v9i2.35641

In the pursuit of environmentally responsible chemical processes, we conducted a thorough assessment of the green metrics associated with the Cannizzaro reaction using p-anisaldehyde and benzaldehyde under solvent-free conditions. This research elaborates the application of two different methods i.e., reflux and ultrasonication, applying potassium hydroxide (KOH) as the reagent. The progress of the Cannizzaro reaction was methodically followed via thin-layer chromatography (TLC), and the resulting products were characterized using various techniques, including melting point analysis, Fourier-transform infrared spectroscopy (FTIR), and gas chromatography-mass spectrometry (GC/MS). To measure the environmental impact and sustainability of these reactions, a multifaceted approach was used. Green metrics were evaluated by the state-of-the-art Environmental Assessment Tool for Organic Syntheses (EATOS) software, combined with the Andraos algorithm. Moreover, energy consumption calculations were evaluated. Reasonable analysis of the green metrics results was undertaken in the framework of prevailing literature, permitting to measure the level of eco-friendliness attained. Experimental findings revealed optimal conditions for the Cannizzaro reaction concerning p-anisaldehyde at a temperature of 50 °C for 90 minutes, resulting in remarkable of p-anisyl alcohol and p-anisic acid in 95.16% and 95.04% yields, respectively. Likewise, the reaction involving benzaldehyde reached its peak performance at 50 °C for 2 hours, giving benzyl alcohol and benzoic acid in 96.17% and 97.22% yields, respectively. Overall, the green metrics assessment and energy consumption calculations reliably confirmed that the solvent-free Cannizzaro reaction, when performed via ultrasonication, offers a reasonably greener and more energy-efficient method than the traditional ones. This research highlights the importance of sustainable chemical synthesis practices and their potential to reduce the environmental footprint of chemical processes.

Co-Authors Abu Masykur Abu Masykur Abu Masykur Ali Triambodo, Ali Annisa Istiqomah Annisa Istiqomah, Annisa aulia Syifa Aninditha Desi Handayani Desi Suci Handayani Desi Suci Handayani Desi Suci Handayani Desi Suci Handayani Dewi Marliyana, Soerya Dewi Restu Tri Wardani Dhea Afrisa Darmawan Dian Endah Kusuma Astuti, Dian Endah Dwi Siswanta Dwi Siswanta Ema Nur Annisa Fajar Rakhman Wibowo Fajar Rakhman Wibowo Fastabiqul Khoirot Firdausi, Nisrina Rahma Fyan Tri Istiqomah Juneasri Hidetaka Kawakita Ichsan Arifagama Izati, Zhahira Nur Jumina Jumina Jumina Jumina Jumina Jumina Keisuke Ohto Khoirina Dwi Nugrahaningtyas Khoirul Fatihin Lestari Okstafiyanti Maryam Rahmi Utami Massardi, Adhie Maulidan Firdaus Maulidan Firdaus Maulidan Firdaus Muhamad Widyo Wartono Muhammad David Julian Syach Muhammad Widyo Wartono Mustofa Mustofa Mustofa Mustofa Nais Puji Wijanarti Ningsih, Dyah A F Nur Jannah Asrilya PRANOTO Prima Vinka Rahmayanti, Prima Vinka Qosrul Karimah Qurotul Aini Rahayu, Windi Vinata Rahmana, Desy Nila Rakhman Wibowo, Fajar Riska Azizawati Sholikh, Riska Azizawati Sabella Vegasty Sentot Budi Rahardjo Sevi Dwi Cahyani Soerya Dewi Marliyana Soerya Dewi Marliyana Suci Wulandari Surya Dewi Marliyana Tahara, Alfia Uke Tika Diah Utami Tri Martini Vegasty, Sabella Venty Suryanti Venty Suryanti Venty Suryanti Wahyu Eko Prasetyo Wisnu Permana, Wisnu Yuni Lestari Yunita, Ailsa Rahma Zainal Arifin Almaqqomul Amin Zainal Arifin Almaqqomul Amin, Zainal Arifin Zuhdi Alqowamul Amin

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