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THE EFFECT OF DISTILLATE STORING DISTILLED FROM FRUCTOSE SYRUPS TOWARD ITS ACETALDEHYDE CONCENTRATION MEASURED BY GAS CHROMATOGRAPHY Maria Monica Sianita Basukiwardojo
Indonesian Journal of Chemistry Vol 5, No 2 (2005)
Publisher : Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (172.058 KB) | DOI: 10.22146/ijc.21821

Abstract

Acetaldehyde is a compound of aldehyde group that is very volatile and toxic. This compound can be found in fructose syrups used in carbonate beverages. The syrups had been distilled then analysed using gas chromatography. The concentration of acetaldehyde was 289.78 g/g in the distillates kept for one week, 295.30 g/g in those kept for two weeks, 429.45 g/g in those kept for three weeks, and 449.38 g/g in those kept for four weeks. The optimum column temperature was programmed with initial temperature of 40 oC held on for four minutes, then increasing by 40 oC/minute to 200 oC. It can be concluded that the longer the distillates have been kept, the greater the concentration of acetaldehyde in the distillates. A further research to investigate the present of microbe in the distillates and the effect of pH should be conducted.
Analisa Kadar Kalori, Kadar Air, dan Masa Simpan dengan Menggunakan Teknologi Pengiris Guna Produktifitas Produk Keripik Singkong Handajani, Sri; Yasin, Ach; Basukiwardojo, Maria Monica Sianita; Kusumawati, Nita; Kurniawan, Muhammad Ridho Hafid; Rahayu, Nunik Tri; Estiningtyas, Indri Wasa
Abimanyu : Jornal of Community Engagement Vol 5 No 2 (2024): August 2024
Publisher : Universitas Negeri Surabaya

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Abstract

Cassava can be processed into chips, which have a special appeal with their distinctive flavour and crunchy texture. Cassava chip production creates profits for cassava farmers and is a major industry in some regions. Improving product quality involves various control measures, including handling and packaging of the final product. The frying and draining process is an important factor in extending the shelf life and inhibiting oxidation of a product. The purpose of this study was to determine the effect of the use of appropriate technology (TTG) draining machines on the nutrition and shelf life of cassava chips products. The results showed that the total fat, saturated fat, protein and carbohydrate content of cassava chips products as a result of TTG were 4.91%; 2.26%; 3.11%; 81.01%, respectively. The shelf life of the chips was 5.25 months (157.5 or 158 days). The results of the organoleptic test of cassava chips in terms of colour, aroma, texture and overall liking level received a positive response from the community, both teenagers and adults. The aspects of aroma, taste, texture and colour as well as the overall level of liking with a percentage level of 80% (seblak daun jeruk), 58% (fried chicken), 61% (rendang), and 56% (grilled chicken).
A SINTESIS KITOSAN DARI CANGKANG KERANG DARAH (Anadara granosa) SEBAGAI BIOSENSOR UNTUK DETEKSI PESTISIDA MENGGUNAKAN MEMBRAN Au/KITOSAN Pharnanda, Rossella; Prasetya, Predian Yudha; Handayani, Suci Tri; Fatehah, Aura Amalia; Basukiwardojo, Maria Monica Sianita
Unesa Journal of Chemistry Vol. 13 No. 1 (2024): Vol 13 No 1 (2024)
Publisher : Department of Chemistry, Faculty of Mathematics and Natural Sciences, Surabaya State University, located at Jl Ketintang, Surabaya, East Java, Indonesia

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Abstract

Pesticides are chemicals that can kill or control pests. However, the current use of pesticides poses a threat to humans and the environment. This research aims to develop a biosensor with Au/Chitosan membrane electrode using chitosan from blood clam shell waste which has high sensitivity to pesticides, fast response time, and long-term stability. So as to achieve the target of Sustainable Development Goals (SDG's) 3, namely health and well-being. The method used is the preparation of blood clam shells, synthesis of chitosan from blood clam shells, making Au/Chitosan membrane electrodes, characterisation of pesticide detection biosensors. The results of FTIR testing of chitosan obtained a degree of deacetylation of 86.3202%. The successfully made Au/Chitosan membrane electrode has an optimum concentration of 5% with the best measurement at pH 7, deposition time of 5 seconds, and scan rate of 0.1 V/s.  Characterisation of carbamate pesticide detection biosensor using Au/Kitosan electrode shows that the Nernst factor obtained is 35.46 mV/decade, detection limit is 2x10 -8 M, measurement range is 10-8 M to 10-2 M, response time is 5-7 minutes, and precision with coefficient of variation for 10-4 M and 10-2 M concentration is 1.095% and 0.412% so that the Au/Chitosan membrane electrode can be used to detect carbamate pesticides effectively.
Development of Active-Smart Packaging: Effect of Chitosan Nanofiber, Zinc Oxide Nanoparticles, and Anthocyanin on Gelatine-Based Halochromic Film for Meat Preservation Kusumawati, Nita; Bahar, Asrul; Basukiwardojo, Maria Monica Sianita; Samik, Samik; Rahayu, Nunik Tri; Estiningtyas, Indri Wasa; Kurniawan, Muhammad Ridho Hafid
Journal of Engineering and Technological Sciences Vol. 57 No. 3 (2025): Vol. 57 No. 3 (2025): June
Publisher : Directorate for Research and Community Services, Institut Teknologi Bandung

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.5614/j.eng.technol.sci.2025.57.3.7

Abstract

Gelatine-based smart active packaging has the potential to improve the quality of packaged meat and monitor its freshness without having to open it. This research aims to develop halochromic films by combining gelatine films with chitosan nanofibers (CHNF) and zinc oxide nanoparticles (ZnONPs). The addition of nanofillers such as CHNF and ZnONPs has been proven to improve mechanical properties (The humidity decreased by approximately 15.6%, while Young’s modulus increased tenfold) and provide active packaging properties, such as antioxidants (IC50 test decreased 13% from 33,12191 to 28,82021) and antimicrobials against S. aureus (increased from 9,40 to 19.73 for inhibition zone), E. coli (increased from 6.61 to 19.91 of inhibition zone), and P. aeruginosa (increased from 8.63 to 18.65 of inhibition zone). Meanwhile, the smart packaging properties are provided by anthocyanin from telang flowers, which can change color as the freshness of the meat decreases or the acidity of the meat changes. The quality of smart active packaging is reflected in the pH sensitivity, ammonia release, and anthocyanin release. The film's mechanical properties also showed improvement in humidity, Young's modulus, water vapor permeability (WVP), and water solubility. Fourier Transform Infra-Red (FTIR) characterization analysis showed good compatibility between the gelatine, anthocyanins, CHNF, and ZnONPs matrix. This research result demonstrates that gelatine-based films with a combination of CHNF and ZnONPs can be used to create eco-friendly and multifunctional packaging films for meat preservation.