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. Suwardi
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Journal : Journal of Tropical Soils

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Characteristics of Heavy Metals Adsorption Cu, Pb and Cd Using Synthetics Zeolite Zsm-5 Priyadi, .; Iskandar, .; Suwardi, .; Mukti, Rino Rakhmata
JOURNAL OF TROPICAL SOILS Vol. 20 No. 2: May 2015
Publisher : UNIVERSITY OF LAMPUNG

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.5400/jts.2015.v20i2.77-83

Abstract

It is generally known that zeolite has potential for heavy metal adsorption. The objectives of this study were to synthesize and characterize zeolite ZSM-5 and to figure out the adsorption capacity of zeolite ZSM-5 for heavy metals of Cu2+, Pb2+ and Cd2+. Characterization of zeolite ZSM-5 included some variables i.e. crystal structure (XRD), morphology (SEM), specific surface area and total pore volume (N2 physisorption). Adsorption capacity of zeolite ZSM-5 was analysed using a batch system with heavy metals of Cu2+, Pb2+ and Cd2+ in various concentrations (50, 100, 150, 200 and 250 ppm) with contact times 30, 60, 90, 120 and 250 minutes. Adsorption data was calculated by Langmuir and Freundlich isotherm. The results showed that the maximum adsorption capacity of zeolite ZSM-5 against heavy metals of Pb2+, Cu2+, and Cd2+, were 74.07, 69.93 and 60.24 mg g-1, respectively. These indicated that synthetic zeolite ZSM-5 had potential to adsorb heavy metals. The results also suggested that the adsorption capacity was affected by the pore size of zeolite, negative charge of zeolite, diameter of hydrated and electronegative ion.
Characterization of Several Paddy Soil Types in Bogor, West Java, Indonesia Kurniati, .; Sudarsono, .; Suwardi, .
JOURNAL OF TROPICAL SOILS Vol. 21 No. 1: January 2016
Publisher : UNIVERSITY OF LAMPUNG

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.5400/jts.2016.v21i1.27-32

Abstract

Paddy soil has different morphology and pedogenic characteristics compared to dry land, due to the influence of inundation during several months in a year. Puddling and drying that occurs in turns (redox cycle) in paddy soil can lead to the formation of concretions or rusty Fe and Mn. The main purpose of this study was to understand the changing of the morphological and chemical properties as a result of changing of the dry land to paddy soil. Besides, the study also aimed to understand plow pan layer formation in Podsolic, Latosol, Regosol, and Andosol soil type. Results showed that content of soil density (bulk density) of dry land ranged from 0.5  to 1.0, while paddy soil is 0.8 to 1.0 (g cm-3).  Bulk density values in all four types of soils increased after the changing. Observation also demonstrated that severity levels of paddy soil is higher than dry land, especially in the second and third soil layers or under the surface of soils. Acidity of dry land was likely to be higher than paddy soil. There were no significant differences in nutrient such as C-organic, P and N. Meanwhile, using dithionite as solvent, paddy soil has higher Fe, Mn, and Al content than that of dry land, and remain the same when extracted with pyrophosphate and oxalate. From the four types of soil observed,the paddy soil showed formation of plow pan layer. This was shown by the soil severity level higher than the topsoil or other layers. Paddy soil had unique properties due to redox reaction, thereby providing soil discoloration i.e darker due to high solubility of Fe, Mn, and Al.Keywords: Concretion of Fe and Mn, paddy soil, pedogenesis, plow pan layer [How to Cite: Kurniati, Sudarsono and Suwardi. 2016. Characterization of Several Paddy Soil Types in Bogor, West Java, Indonesia . J Trop Soils 21:. 27-32. Doi: 10.5400/jts.2016.21.1.27]
Utilization of Natural Zeolites as Cu (Ii) and Zn (Ii) Adsorbent Dewi, Evi Mutiara; Suwardi, .; Suryaningtyas, Dyah Tjahyandari; Anwar, Syaiful
JOURNAL OF TROPICAL SOILS Vol. 21 No. 3: September 2016
Publisher : UNIVERSITY OF LAMPUNG

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.5400/jts.2016.v21i3.153-160

Abstract

This research was aimed to determine the differences of physical and chemical characteristics from three natural zeolites from Tasikmalaya, Bayah and Lampung areas and to examine the characteristics of the natural zeolite adsorption capability to the micro-nutrients. The zeolite characterization analysis included some variables i.e. mineral types, morphologyand pH, CEC (Cation Exchange Capacity), BSP (Base Saturation Point), Cu and Zn content of zeolite. Analysis of natural zeolite adsorption characteristics were done by Batch System. Data interpretation were done by using the isothermal adsorption equation of Langmuir, Freundlich and Brunauer-Emmett-Teller (BET).The results showed that zeolite from Bayah and Tasikmalaya had a similiar morphology and it was categorized as mordenite types and platy structure, while zeolite from Lampung was a clinoptilolite type and tabular structure. The CEC of Tasikmalaya zeolite (137.58 cmol(-)kg-1) was higher than Bayah (96.75 cmol(-)kg-1) and Lampung (87.72 cmol(-)kg-1). Adsorption capability at the Langmuir equation of Cu by Bayah zeolite (47.619 mg g-1) was higher than Lampung (33.333 mgg-1) and Tasikmalaya (28.571 mg g-1). Effective adsorption of Zn by Bayah zeolite 19.417 mg g-1 was higher than Lampung (16.949 mg g-1) and Tasikmalaya (1.395 mg g-1).
Quality Improvement of Compost from Empty Oil Palm Fruit Bunch by the Addition of Boiler Ash and its effect on Chemical Properties of Ultisols and the Production of Mustard (Brassica juncea L.) Mulyani, Sri; Suryaningtyas, Dyah Tjahyandari; Suwardi, .; Suwarno, .
JOURNAL OF TROPICAL SOILS Vol. 21 No. 3: September 2016
Publisher : UNIVERSITY OF LAMPUNG

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.5400/jts.2016.v21i3.161-169

Abstract

Productions of crude palm oil (CPO) produce waste which include the empty oil palm fruit bunch (EOPFB), palm oil mill effluent, shells, and fiber. The combustions of shell and fiber as boiler feed produce waste in the form of boiler ash. Boiler ash is very potential to use as an additive to improve quality of the EOPFB compost. The objectives of this research were to study : 1) effect of boiler ash on the quality of the EOPFB compost, 2) effect of EOPFB compost on the chemical properties of Ultisol, and the yield of mustard. The first experiment was about quality improvement of compost from EOPFB by the addition of boiler ash. The treatments applied were four dose levels of boiler ash: K1= 0%, K2 = 15%, K3 = 25%, and K4 = 35%. The second experiment was greenhouse pot experiment. This experiment was consisted of thirteen treatments with three replications arranged in completely randomized design (CRD). The treatments applied were: four types of compost from the first experimental results aplied to the soil with four dose levels, i.e : 0, 10, 20 and 30 Mg ha-1. The results showed that the addition of boiler ash at the beginning of the composting process improved the quality of the EOPFB compost: which increased pH, amount of humic acids, macro and micro nutrients content and decreased content of Pb. The aplication of all compost –K1, K2, K3, K4– to Ultisol increased pH H2O, P2O5, organic-C, total-N, exchangeable-Ca, exchangeable-K and yield of mustard and decreased exchangeable-H, exchangeable-Al. Moreover the yield of mustard was increased about 84% (33.9 g plant-1) with K4 at doses 20 Mg ha-1 and 85% (34.1 g plant-1) with K3 at doses 10 Mg ha-1.
Co-Authors . Iskandar . Kurniati . Suwarno Dyah Tjahyandari Suryaningtyas Evi Mutiara Dewi, Evi Mutiara Mukti, Rino Rakhmata Priyadi, . Sri Mulyani Sudarsono Syaiful Anwar