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Non Dispersive Chemical Deacidification of Crude Palm Oil in Hollow Fiber Membrane Contactor Purwasasmita, Mubiar; Nabu, Eryk Bone Pratama; Khoiruddin, K.; Wenten, I Gede
Journal of Engineering and Technological Sciences Vol 47, No 4 (2015)
Publisher : ITB Journal Publisher, LPPM ITB

Performance of chemical deacidification of crude palm oil (CPO) using aqueous NaOH solution in a polysulfone hollow fiber ultrafiltration membrane wasÂ investigated. The effects of operating temperature, NaOH concentration and flow rates on percentage of free fatty acids (FFA) removal, oil loss, soap entrainment and overall mass transfer coefficientÂ wereÂ evaluated. Overall mass transfer coefficients, soap content in oil and neutral oil loss all increasedÂ when theÂ temperatureÂ was increased from 60 to 70Â°C due to an increase of the FFA distribution value. A minimum 0.25 N of NaOH or a NaOH to FFAÂ molar ratioÂ of about 7.62 wasÂ required to facilitate the expected extraction efficiency. The increased oil flowrate slightly enhanced the solute transport kinetics,Â while theÂ aqueous phase flowrate did not significantly influence deacidification efficiency or mass transfer coefficient. About 97% of FFA removal was achieved within 4 hours. The maximum oil loss observed was 11% and the highestÂ soap content in theÂ oil without separation step was 3150 ppm. The valuesÂ of theÂ overall mass transfer coefficient variedÂ from 2.97Ã10-7 to 7.71Ã10-7 m/s. These results show the potential of using the non dispersive membrane contacting process for chemical deacidification of CPO as well as other vegetable oils.

Investigation of Electrochemical and Morphological Properties of Mixed Matrix Polysulfone-Silica Anion Exchange Membrane Khoiruddin, Khoiruddin; Wenten, I Gede
Journal of Engineering and Technological Sciences Vol 48, No 1 (2016)
Publisher : ITB Journal Publisher, LPPM ITB

Mixed matrix anion exchange membranes (AEMs) were synthesized using dry-wet phase inversion. The casting solutions were prepared by dispersing finely ground anion-exchange resin particles in N,N-dimethylacetamide (DMAc) solutions of polysulfone (PSf). Subsequently, nanosilica particles were introduced into the membranes. The results show that evaporation time (tev) and solution composition contributed to membrane properties formation. A longer tev produces membranes with reduced void fraction inside the membranes, thus the amount of water adsorbed and membrane conductivity are reduced. Meanwhile, the permselectivity was improved by increasing tev, since a longer tev produces membranes with a narrower channel for ion migration and more effective Donnan exclusion. The incorporation of 0.5 %-wt nanosilica particles into the polymer matrix led to conductivity improvement (from 2.27 to 3.41 mS.cm-1). This may be associated with additional pathway formation by hydroxyl groups on the silica surface that entraps water and assists ion migration. However, at further silica loading (1.0 and 1.5 %-wt), these properties decreased (to 1.9 and 1.4 mS.cm-1 respectively), which attributed to inaccessibility of ion-exchange functional groups due to membrane compactness. It was found from the results that nanosilica contributes to membrane formation (increases casting solution viscosity then reduces void fraction) and membrane functional group addition (provides hydroxyl groups).

The Influence of PEG400 and Acetone on Polysulfone Membrane Morphology and Fouling Behaviour Aryanti, P.T.P.; Joscarita, Shelli R.; Wardani, Anita K.; Subagjo, S.; Ariono, Danu; Wenten, I Gede
Journal of Engineering and Technological Sciences Vol 48, No 2 (2016)
Publisher : ITB Journal Publisher, LPPM ITB

Modification of polysulfone ultrafiltration membrane was conducted by blending polysulfone with PEG400 and acetone as additives. The influence of each additive on the resulted membrane morphology and fouling characteristics were investigated. The experimental results showed that the hydrophilicity of the polysulfone membrane was improved by the increase of PEG400 in the polysulfone membrane. The water contact angle of the membrane was decreased from 76.1Â° to 38.31Â° when 35 %wt of PEG400 was added into the polysulfone solution, while the water content of the membrane was increased by around 38%. The high concentration of PEG400 in the polysulfone solution led to the formation of longer finger-like cavities in the membrane structure and resulted in a thicker membrane skin layer. The high concentration of PEG400 also contributed to the increase in hydraulic resistance of the membrane due to organic matter fouling. This problem could be minimized by the addition of acetone into the polysulfone solution, which resulted in a lower fouling resistance of organic matter during up to five hours of peat water filtration.

Brine Effluents: Characteristics, Environmental Impacts, and Their Handling Ariono, Danu; Purwasasmita, Mubiar; Wenten, I Gede
Journal of Engineering and Technological Sciences Vol 48, No 4 (2016)
Publisher : ITB Journal Publisher, LPPM ITB

Brine discharge is one of the largest sources of wastewater from industrial processes. Because of the environmental impacts arising from improper treatment of brine discharge and more rigorous regulations of pollution control, industries have started to focus on waste minimization and improving the process of wastewater treatment. Several approaches have been proposed to provide a strategy for brine handling by recovering both brine and water or to remove pollutant components so it complies with environmental regulations when discharged. One of the most promising alternatives to brine disposal is reusing the brine, which results in reduction of pollution, minimizing waste volume and salt recovery. The brine may also contain valuable components that could be recovered for profitable use. Also, water recovery from brine effluent is generally performed to save water. In the case of rejected brine from desalination plants, water recovery from higher brine concentrations has huge potential for salt production. This paper gives an overview of different types of brine effluents, their sources and characteristics. Also discussed are impacts of brine on the environment and management options related to their characteristics.

Analysis of Protein Separation Mechanism in Charged Ultrafiltration Membrane Ariono, Danu; Aryanti, Putu Teta P.; Wardani, Anita Kusuma; Wenten, I Gede
Journal of Engineering and Technological Sciences Vol 50, No 2 (2018)
Publisher : ITB Journal Publisher, LPPM ITB

The separation mechanism of proteins on a charged ultrafiltration membrane was analyzed using the extended NernstâPlanck (N-P) model. The model was solved numerically based on experimental data during ultrafiltration of bovine serum albumin/BSA and hemoglobin at various pH (between 5 and 8) to obtain the flux parameter (Jv). The flux parameter was used to determine the effective charge of the membrane (f) and the actual membrane porosity (Ak). These two parameters were then used to predict the transport mechanism of proteins through the charged membrane. Higher flux was obtained during the ultrafiltration of BSA compared to hemoglobin. The most effective separation of mixed proteins occurred at pH 5 (aalbumin= 5). In addition, the mobility of a single protein was lower than when it was mixed with other proteins that had different charges. The effective charges of the membranes were varied between 0.99996 to 1.0000, which means that the fixed charge on the membrane structure was higher than the concentration of proteins, thus the effective charge of the membrane was not influenced by the presence of protein charge at various pH. On the contrary, the value of Ak was influenced by the type and charge of the proteins. A decrease of negative charge along with an increase of solution pH increased the porosity of the membrane, thus reducing the rejection of proteins.

Impurity Removal of Waste Cooking Oil Using Hydrophobic Polypropylene Hollow Fiber Membrane Aliwarga, Lienda; Widodo, Setyo; Suwardana, Novika; Darmawan, Hanna; Khoiruddin, Khoiruddin; Wenten, I Gede
Journal of Engineering and Technological Sciences Vol 51, No 2 (2019)
Publisher : ITB Journal Publisher, LPPM ITB

Removal of impurities from cooking oil is an important step in providing the possibility of WCO reuse to extend the life cycle of cooking oil, leading to a reduction of WCO disposal. This study was conducted to investigate the performance of a polypropylene (PP) hollow fiber ultrafiltration (UF) membrane for removal of impurities from WCO. The results showed that the membrane could remove water content up to 95% (at 0.1 MPa and 30 °C), but the color improvement was only 9.5% as indicated by the absorbance reduction. Within the range of the operation conditions (i.e. a trans-membrane pressure of 0.1-0.2 MPa and a temperature of 30-50 °C), the oil flux varied from 0.3 L.m‑2.h‑1 to 1.3 L.m-2.h-1. In long-term operation, the membrane wettability was improved as shown by the oil contact angle decreasing from 28.2 ± 1.5° to 14.4 ± 0.5°. This resulted in a higher oil flux. At the same time, the hydrophobicity was also increased, as indicated by an increase in the water contact angle from 95.4 ± 0.7° to 97.3 ± 1.1°.

Non Dispersive Chemical Deacidification of Crude Palm Oil in Hollow Fiber Membrane Contactor Mubiar Purwasasmita; Eryk Bone Pratama Nabu; K. Khoiruddin; I Gede Wenten
Journal of Engineering and Technological Sciences Vol. 47 No. 4 (2015)
Publisher : Institute for Research and Community Services, Institut Teknologi Bandung

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.5614/j.eng.technol.sci.2015.47.4.6

Performance of chemical deacidification of crude palm oil (CPO) using aqueous NaOH solution in a polysulfone hollow fiber ultrafiltration membrane was investigated. The effects of operating temperature, NaOH concentration and flow rates on percentage of free fatty acids (FFA) removal, oil loss, soap entrainment and overall mass transfer coefficient were evaluated. Overall mass transfer coefficients, soap content in oil and neutral oil loss all increased when the temperature was increased from 60 to 70°C due to an increase of the FFA distribution value. A minimum 0.25 N of NaOH or a NaOH to FFA molar ratio of about 7.62 was required to facilitate the expected extraction efficiency. The increased oil flowrate slightly enhanced the solute transport kinetics, while the aqueous phase flowrate did not significantly influence deacidification efficiency or mass transfer coefficient. About 97% of FFA removal was achieved within 4 hours. The maximum oil loss observed was 11% and the highest soap content in the oil without separation step was 3150 ppm. The values of the overall mass transfer coefficient varied from 2.97Ã—10-7 to 7.71Ã—10-7 m/s. These results show the potential of using the non dispersive membrane contacting process for chemical deacidification of CPO as well as other vegetable oils.

Investigation of Electrochemical and Morphological Properties of Mixed Matrix Polysulfone-Silica Anion Exchange Membrane Khoiruddin Khoiruddin; I Gede Wenten
Journal of Engineering and Technological Sciences Vol. 48 No. 1 (2016)
Publisher : Institute for Research and Community Services, Institut Teknologi Bandung

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.5614/j.eng.technol.sci.2016.48.1.1

Mixed matrix anion exchange membranes (AEMs) were synthesized using dry-wet phase inversion. The casting solutions were prepared by dispersing finely ground anion-exchange resin particles in N,N-dimethylacetamide (DMAc) solutions of polysulfone (PSf). Subsequently, nanosilica particles were introduced into the membranes. The results show that evaporation time (tev) and solution composition contributed to membrane properties formation. A longer tev produces membranes with reduced void fraction inside the membranes, thus the amount of water adsorbed and membrane conductivity are reduced. Meanwhile, the permselectivity was improved by increasing tev, since a longer tev produces membranes with a narrower channel for ion migration and more effective Donnan exclusion. The incorporation of 0.5 %-wt nanosilica particles into the polymer matrix led to conductivity improvement (from 2.27 to 3.41 mS.cm-1). This may be associated with additional pathway formation by hydroxyl groups on the silica surface that entraps water and assists ion migration. However, at further silica loading (1.0 and 1.5 %-wt), these properties decreased (to 1.9 and 1.4 mS.cm-1 respectively), which attributed to inaccessibility of ion-exchange functional groups due to membrane compactness. It was found from the results that nanosilica contributes to membrane formation (increases casting solution viscosity then reduces void fraction) and membrane functional group addition (provides hydroxyl groups).

The Influence of PEG400 and Acetone on Polysulfone Membrane Morphology and Fouling Behaviour P.T.P. Aryanti; Shelli R. Joscarita; Anita K. Wardani; S. Subagjo; Danu Ariono; I Gede Wenten
Journal of Engineering and Technological Sciences Vol. 48 No. 2 (2016)
Publisher : Institute for Research and Community Services, Institut Teknologi Bandung

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.5614/j.eng.technol.sci.2016.48.2.1

Modification of polysulfone ultrafiltration membrane was conducted by blending polysulfone with PEG400 and acetone as additives. The influence of each additive on the resulted membrane morphology and fouling characteristics were investigated. The experimental results showed that the hydrophilicity of the polysulfone membrane was improved by the increase of PEG400 in the polysulfone membrane. The water contact angle of the membrane was decreased from 76.1° to 38.31° when 35 %wt of PEG400 was added into the polysulfone solution, while the water content of the membrane was increased by around 38%. The high concentration of PEG400 in the polysulfone solution led to the formation of longer finger-like cavities in the membrane structure and resulted in a thicker membrane skin layer. The high concentration of PEG400 also contributed to the increase in hydraulic resistance of the membrane due to organic matter fouling. This problem could be minimized by the addition of acetone into the polysulfone solution, which resulted in a lower fouling resistance of organic matter during up to five hours of peat water filtration.

Brine Effluents: Characteristics, Environmental Impacts, and Their Handling Danu Ariono; Mubiar Purwasasmita; I Gede Wenten
Journal of Engineering and Technological Sciences Vol. 48 No. 4 (2016)
Publisher : Institute for Research and Community Services, Institut Teknologi Bandung

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.5614/j.eng.technol.sci.2016.48.4.1

Brine discharge is one of the largest sources of wastewater from industrial processes. Because of the environmental impacts arising from improper treatment of brine discharge and more rigorous regulations of pollution control, industries have started to focus on waste minimization and improving the process of wastewater treatment. Several approaches have been proposed to provide a strategy for brine handling by recovering both brine and water or to remove pollutant components so it complies with environmental regulations when discharged. One of the most promising alternatives to brine disposal is reusing the brine, which results in reduction of pollution, minimizing waste volume and salt recovery. The brine may also contain valuable components that could be recovered for profitable use. Also, water recovery from brine effluent is generally performed to save water. In the case of rejected brine from desalination plants, water recovery from higher brine concentrations has huge potential for salt production. This paper gives an overview of different types of brine effluents, their sources and characteristics. Also discussed are impacts of brine on the environment and management options related to their characteristics.

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