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Pemanfaatan dan Pengolahan Pupuk Organik Dari Limbah Tanaman Jagung Dan Kulit Coklat Uswatun Hasanah; Murniaty Simorangkir; Indra Masmur; Sajaratud Dur; Elvri Melliaty Sitinjak
JURNAL PENGABDIAN KEPADA MASYARAKAT Vol 20, No 75 (2014)
Publisher : Universitas Negeri Medan

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.24114/jpkm.v20i75.4821

Kegiatan IbM Kelompok Tani Jagung dan Coklat ini bertujuan 1) memberi solusi kepada mitran Kelompok Tani Jagung Sejahtera dan Kelompok Tani Coklat Saroha untuk mengatasi kekuranganpupuk organik dengan memanfaatkan limbah tanaman jagung dan coklat yang cukup melimpahn dalam usaha meningkatkan produktivitas tanaman dan mensukseskan program pertanianorganik, 2) membuka peluang membuka usaha baru pupuk organik. Target khusus yang ingin dicapai adalah publikasi jurnal, laporan kegiatan, aspek produksi dan manajemen. Luaran kegiatan adalah produk pupuk organik limbah tanaman jagung dan coklat berkualitas (fisik dan kandungan unsur hara), desain alat perajang mekanik limbah pertanian dan rencana bisnis sederhana pupuk organik. Metode yang diterapkan adalah penyuluhan, rancang alat perajang mekanik limbah organik, pelatihan dan peraktek produksi serta penyuluhan perencanaan bisnis sederhana pupuk organik. Kegiatan melibatkan tiga orang dosen dan dua mahasiswa. Mitra kegiatan adalah kelompok tani jagung Sejahtera dan kelompok tani coklat Saroha. Hasil kegiatan menunjukkan bahwa 80 % kelompok tani kedua mitra mampu mengolah pupuk organik dari limbah kulit coklat dan limbah batang serta daun jagung dalam waktu 10 hari. Kualitas tekstur pupuk organic baik yaitu tidak berbau, tidak berair, gembur, tidak panas dan warnanya hitam. Kualitas unsur hara .masing-masing pupuk limbah jagung, coklat dan campuranlimbah jagung dan coklata dalah ratio C/N 8,4; 8,8 dan 9,0 yang sudah mendekati ratio C/N tanah, kadar KO 1,60 %; 1,52% dan 1,58% serta kadar P2O adalah 3,15%; 2,50% dan 3,00%. Hal ini menunjukkan bahwa zat organik limbah telah terurai menjadi unsur hara yang menyuburkan tanah dan mudah diserap 5 tanaman. Kelompok tani mitra mengembangkan pembuatan pupuk dengan menggunakan limbah tanaman/batang pisang yang ada di lokasi pada saat sebelum panen jagung. Kapasitas alat perajang mekanik yang digunakan dapat memotong 500 kg limbah pertanian/jam. Sebanyak 50% kelompok tani mitra berminat berwirausaha baru pupuk organik dan 50% lagi sementara hanya untuk memenuhi kebutuhan pupuk tanamannya. Kelompok tani mitra ini memerlukan pembinaan lanjutan baik dalam penyempurnaan produksi, pengemasan maupun pemasaran produksinya.

Bioethanol Manufacturing from α-Cellulose Waste of Empty Palm Oil Frugs (Elaeis guineensis jack) with Hydrolysis Concetration Variations HCl and Cellulase Enzyme Indra Masmur; Herliana Herliana; Bramwell Sitompul; Elvri Melliaty Sitinjak
Indonesian Journal of Chemical Science and Technology (IJCST) Vol 5, No 2 (2022): JULI 2022
Publisher : Universitas Negeri Medan

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.24114/ijcst.v5i2.37455

This study uses raw materials containing lignocellulose, namely empty fruit bunches of oil palm. Oil palm empty fruit bunches were isolated to produce cellulose, hydrolyzed into simple sugars, fermented, and distilled. From the isolation of cellulose obtained α-cellulose of 19.9612 grams (26.6149%). Then it was hydrolyzed using HCl with a concentration variation of 15%; 20%; 25%; 30%; and enzymatically hydrolyzed using cellulase to produce simple sugars which were tested qualitatively with Benedict's reagent and Tollens reagent, then quantitatively tested by the Luff Schroll method. The higher the concentration of acid used, the higher the sugar will be. The best bioethanol obtained from acid hydrolysis is using 30% HCl with ethanol content of 6.54% and enzymatic 7.32%.

Ethanol Production Comparison from Agricultural Waste of Cellulose Source Within Hydrolysis Hcl and Cellulose Enzyme Indra Masmur; Clairine Clairine; Mega Evelin Rajagukguk; Teti Purwita Sari; Elvri Melliaty Sitinjak
Indonesian Journal of Chemical Science and Technology (IJCST) Vol 5, No 2 (2022): JULI 2022
Publisher : Universitas Negeri Medan

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.24114/ijcst.v5i2.37456

The production of Ethanol has been utilized through the process of cellulose isolation from agricultural waste such as corn husk, rice straw and rice husk. Isolation of cellulose with pretreatment delignification using, NaOH 2% to produces cellulose of corn husk 16,6921 g (22,25%), rice straw 16,9021 g (22,53%) and rice husk 16,3691 g (21,85%) then analyzed the functional groups using FT-IR and SEM analysis. Cellulose as much as 2 g is hydrolyzed using HCl 30% and cellulase enzymes to obtain sugar that is qualitatively tested with Benedict and Tollens reagent and quantitatively tested with Luff Schoorl method and produces highest sugar content of rice husk 8,64% and 10,95%. The next stage sugar of hydrolysis will be fermented using yeast (Saccharomyces cerevisiae) with 6 days, and then distilled at a temperature of 78-80oC. Ethanol was calculated by the potassium dichromate oxidation method to gave highest result from agricultral waste of ethanol chemical 5,97% and enzymatic 6,89% is rice husk.

Effect of Chain Length on Fatty Alcohol Sulfation using SO3-DMF Sitinjak, Elvri Melliaty; Masmur, Indra; Tarigan, Dedi; Anggini, Cindy; Simbolon, Emma Juli Anamasta; Simatupang, Endang; Pane, Yulia Ratu; Simorangkir, Murniaty; Nurfajriani, Nurfajriani
Indonesian Journal of Chemical Science and Technology (IJCST) Vol 6, No 2 (2023): JULY 2023
Publisher : Universitas Negeri Medan

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.24114/ijcst.v6i2.49376

The fatty alcohols C8, C10, C16 and C18 were used as raw materials for the sulfation reaction using the SO3-DMF complex to study the ratio of carbon chains. The first step is to prepare the SO3-DMF complex, by reacting SO3 gas into DMF at a temperature of 0-4 0C with a reaction time of 3 hours, then sulfation is carried out at 100 0C for 5 hours on C8, C10, C16 and C18. Tests were carried out on the results of sulfation with an FT-IR Spectrophotometer. Surface tension, foam stability and yield calculations. From the sulfation results, the yield results were respectively 83%, 81%, 68% and 61% then the results from the surface tension analysis were 35.3, dyne/cm, 30.3 dyne/cm, 29.4 dyne/cm and 33.6 dyne/cm and foam stability analysis of 0.2 cm, 0.8 cm, 0.7 cm and 1 cm. Based on the surface tension reduction value, palmityl alcohol is the best raw material for making surfactants.

Synthesis of Sodium Myristyl Sulfate with Myristyl Alcohol Sulfation using SO3-DMF Sitinjak, Elvri Melliaty; Masmur, Indra; Tarigan, Dedi; Anggini, Cindy; Simbolon, Emma Juli Anamasta; Simatupang, Endang; Pane, Yulia Ratu; Simorangkir, Murniaty; Nurfajriani, Nurfajriani
Indonesian Journal of Chemical Science and Technology (IJCST) Vol 6, No 2 (2023): JULY 2023
Publisher : Universitas Negeri Medan

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.24114/ijcst.v6i2.49378

The sulfation reaction between myristyl alcohol and the SO3-DMF complex has been successfully carried out to produce sodium myristyl sulfate. Formation of the SO3-DMF complex by reacting DMF and SO3 gas obtained from the reaction of phosphorus pentaoxide and H2SO4. The variables studied were the time of formation of the complex, the time and temperature of sulfation and the concentration of NaOH at neutralization. The results of myristyl alcohol sulfation with SO3-DMF were tested by FTIR spectroscopic analysis, surface tension test, and foam stability test. The formation time of the SO3- DMF complex of 5 hours is the result of the highest surface tension reduction and the most optimal foam stability. The results of the foam stability test analysis showed the highest value at 80oC with a foam stability of 0.5 cm. The best result of sulfation neutralized with 40% NaOH solution was able to reduce the surface tension value and has foam stability up to 66% with a decrease in foam height of 0.3 cm

Optimasi dan Sintesis Selulosa Dialdehid Berbasis Limbah Tandan Kosong Kelapa Sawit Sitinjak, Elvri Melliaty; Masmur, Indra; Shuwanto, Hardy; Dina, Sari Farah; Hutajulu, Poltak Evencus; Saragih, Gimelliya; Siahaan, Immanuel; Damanik, Fadhila Natania; Doloksaribu, Rahel Argana
Jurnal Teknik Kimia USU Vol. 14 No. 2 (2025): Jurnal Teknik Kimia USU
Publisher : Talenta Publisher (Universitas Sumatera Utara)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.32734/jtk.v14i2.20686

Empty Fruit Bunches of Oil Palm (EFB) represent one of the most problematic biomass wastes in Indonesia due to their massive volume, inefficient management, and underutilization of their chemical potential, leading to significant environmental, economic, and technical impacts. The degradation or processing of such large-scale waste generally requires a long period of time. This study focuses on converting the cellulose content in EFB into dialdehyde cellulose (DAC), which can be applied as a wet strength agent. The aim is to reduce EFB waste by isolating cellulose from EFB biomass and subsequently converting it into DAC, which can be utilized as a wet strength additive in paper or tissue products. The oxidation of EFB cellulose into DAC was optimized using sodium periodate (NaIO₄) as the oxidizing agent, with varying reaction times of 3, 6, and 9 hours. The synthesized DAC was qualitatively analyzed using the Fehling’s test and solubility observations, followed by functional group identification via FTIR and morphological characterization using SEM. Among the samples, DAC-6 exhibited the most optimal characteristics, with a degree of oxidation reaching 82.1% and a carbonyl content of 52.8%. FTIR analysis confirmed the presence of carbonyl functional groups in all DAC samples, indicating successful oxidation of hydroxyl groups in cellulose. DAC-6 showed the most prominent carbonyl absorption peak at a wavenumber of 1748 cm⁻¹.

Optimasi dan Sintesis Selulosa Dialdehid Berbasis Limbah Tandan Kosong Kelapa Sawit Sitinjak, Elvri Melliaty; Masmur, Indra; Shuwanto, Hardy; Dina, Sari Farah; Hutajulu, Poltak Evencus; Saragih, Gimelliya; Siahaan, Immanuel; Damanik, Fadhila Natania; Doloksaribu, Rahel Argana
Jurnal Teknik Kimia USU Vol. 14 No. 2 (2025): Jurnal Teknik Kimia USU
Publisher : Talenta Publisher (Universitas Sumatera Utara)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.32734/jtk.v14i2.20686

Empty Fruit Bunches of Oil Palm (EFB) represent one of the most problematic biomass wastes in Indonesia due to their massive volume, inefficient management, and underutilization of their chemical potential, leading to significant environmental, economic, and technical impacts. The degradation or processing of such large-scale waste generally requires a long period of time. This study focuses on converting the cellulose content in EFB into dialdehyde cellulose (DAC), which can be applied as a wet strength agent. The aim is to reduce EFB waste by isolating cellulose from EFB biomass and subsequently converting it into DAC, which can be utilized as a wet strength additive in paper or tissue products. The oxidation of EFB cellulose into DAC was optimized using sodium periodate (NaIO₄) as the oxidizing agent, with varying reaction times of 3, 6, and 9 hours. The synthesized DAC was qualitatively analyzed using the Fehling’s test and solubility observations, followed by functional group identification via FTIR and morphological characterization using SEM. Among the samples, DAC-6 exhibited the most optimal characteristics, with a degree of oxidation reaching 82.1% and a carbonyl content of 52.8%. FTIR analysis confirmed the presence of carbonyl functional groups in all DAC samples, indicating successful oxidation of hydroxyl groups in cellulose. DAC-6 showed the most prominent carbonyl absorption peak at a wavenumber of 1748 cm⁻¹.

Effect of Chain Length on Fatty Alcohol Sulfation using SO3-DMF Sitinjak, Elvri Melliaty; Masmur, Indra; Tarigan, Dedi; Anggini, Cindy; Simbolon, Emma Juli Anamasta; Simatupang, Endang; Pane, Yulia Ratu; Simorangkir, Murniaty; Nurfajriani, Nurfajriani
Indonesian Journal of Chemical Science and Technology (IJCST) Vol. 6 No. 2 (2023): JULY 2023
Publisher : Universitas Negeri Medan

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.24114/ijcst.v6i2.49376

The fatty alcohols C8, C10, C16 and C18 were used as raw materials for the sulfation reaction using the SO3-DMF complex to study the ratio of carbon chains. The first step is to prepare the SO3-DMF complex, by reacting SO3 gas into DMF at a temperature of 0-4 0C with a reaction time of 3 hours, then sulfation is carried out at 100 0C for 5 hours on C8, C10, C16 and C18. Tests were carried out on the results of sulfation with an FT-IR Spectrophotometer. Surface tension, foam stability and yield calculations. From the sulfation results, the yield results were respectively 83%, 81%, 68% and 61% then the results from the surface tension analysis were 35.3, dyne/cm, 30.3 dyne/cm, 29.4 dyne/cm and 33.6 dyne/cm and foam stability analysis of 0.2 cm, 0.8 cm, 0.7 cm and 1 cm. Based on the surface tension reduction value, palmityl alcohol is the best raw material for making surfactants.

Synthesis of Sodium Myristyl Sulfate with Myristyl Alcohol Sulfation using SO3-DMF Sitinjak, Elvri Melliaty; Masmur, Indra; Tarigan, Dedi; Anggini, Cindy; Simbolon, Emma Juli Anamasta; Simatupang, Endang; Pane, Yulia Ratu; Simorangkir, Murniaty; Nurfajriani, Nurfajriani
Indonesian Journal of Chemical Science and Technology (IJCST) Vol. 6 No. 2 (2023): JULY 2023
Publisher : Universitas Negeri Medan

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.24114/ijcst.v6i2.49378

The sulfation reaction between myristyl alcohol and the SO3-DMF complex has been successfully carried out to produce sodium myristyl sulfate. Formation of the SO3-DMF complex by reacting DMF and SO3 gas obtained from the reaction of phosphorus pentaoxide and H2SO4. The variables studied were the time of formation of the complex, the time and temperature of sulfation and the concentration of NaOH at neutralization. The results of myristyl alcohol sulfation with SO3-DMF were tested by FTIR spectroscopic analysis, surface tension test, and foam stability test. The formation time of the SO3- DMF complex of 5 hours is the result of the highest surface tension reduction and the most optimal foam stability. The results of the foam stability test analysis showed the highest value at 80oC with a foam stability of 0.5 cm. The best result of sulfation neutralized with 40% NaOH solution was able to reduce the surface tension value and has foam stability up to 66% with a decrease in foam height of 0.3 cm

IMPLEMENTASI INTERNET OF THINGS (IoT) DALAM SISTEM PENGONTROLAN SUHU OTOMATIS BERBASIS MIKROKONTROLER PADA ALAT PROOFER UNTUK PENGEMBANG ADONAN ROTI DI UMKM PIZZA OEI OEI AND PATISSERIE Nelson Silitonga; Dian Kurnia; Elvri Melliaty Sitinjak; Sari Farah Dina; Abdillah; Golfrid Gultom; Harmileni; Rycce Sylviana Pratikha; Yanto; Muhammad Iqbal Harapan Muslim Siregar
Journal of Golden Generation Abdimas Vol. 1 No. 2 (2025): Desember : Journal of Golden Generation Abdimas
Publisher : PT. Lembaga Penerbit Penelitian Nusantara

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.65244/jgga.v1i2.398

Implementation of Internet of Things (IoT) technology and microcontrollers as an automatic temperature control system on tools for proofing bread dough at the Oei Oei Pizza and Patisserie Micro, Small, and Medium Enterprise (MSMEs). The primary issue faced by partners was temperature instability during the dough fermentation process, leading to inconsistent product quality. The implementation method included problem identification, tool design and construction, implementation at partner locations, and mentoring and evaluation. The results of the activity showed that the tool can help IoT-based systems maintain stable fermentation temperatures, improve dough quality consistency, and increase production efficiency. This initiative also has a positive impact on increasing partners' capacity to utilize appropriate technology.

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