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Adiarso, Adiarso
Prosiding Seminar Nasional Teknik Kimia "Kejuangan"
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PENGARUH PENAMBAHAN SULFUR PADA PROSES PENCAIRAN BATUBARA BANKO Hidayat, Herman; Adiarso, Adiarso
Jurnal Energi dan Lingkungan (Enerlink) Vol 2, No 2 (2006)
Publisher : Jurnal Energi dan Lingkungan (Enerlink)

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Abstract

The effect of adding sulfur in Central Banko coal liquefaction is examined usingautoclave reactor with limonite catalyst from Soroako, at 450oC, H2 initialpressure = 9 Mpa, holding time = 60 minutes, and S/Fe ratio varies from 1, 2, 3dan 6. It is found that there is significant increase in distillates yield by 53,81% forthe increase of S/Fe ratio from 1 to 2, and at the same time CLB decreases from53,5% to 29,47%. This is because the amount of pyrrhotite for S/Fe ratio =2 ishigh and enough to promote cracking to convert coal to distillates or oil. For S/Feratio = 3, the increase of distillates or oil yield is not significant, so does for S/Fe= 6. This concludes that adding more sulfur in Central Banko coal liquefactionusing limonite catalyst from Soroako is not effective and therefore does notinfluence much to the oil yield. This is because the particle size and amount ofpyrrhotite already achieves equilibrium for S/Fe ratio = 2. The changing of S/Feratio does not give much effect to the yields of H2O, CO+CO2, C1~C4,andhydrogen consumption as well..Kata Kunci : limonit Soroako, rasio S/Fe,yield distilat, yield CLB, pirhotit, yieldH2O, yield CO+CO2, yield C1~C4, konsumsi gas hidrogen
PERBANDINGAN KARAKTERISTIK PENCAIRAN BATUBARA BANKO DAN TANITO HARUM SEBAGAI EFEK KERJA KATALIS LOGAM TRANSISI Hanif, Muhammad; Adiarso, Adiarso
Jurnal Energi dan Lingkungan (Enerlink) Vol 4, No 2 (2008)
Publisher : Jurnal Energi dan Lingkungan (Enerlink)

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Characterization of two oil derived from Indonesian lower-rank coals from SouthBanko (SB) and Tanito Harum (TH) were carried out after liquefied in thepresence of nickel/molybdenum (Ni/Mo) and cobalt/ molybdenum (Co/Mo)catalysts without added solvent. Both coals treated with Ni/Mo have highconversion than those treated with Co/Mo when reacted with hydrogen withinitial pressure of 6MPa at 400oC for 30 minutes. However, with sulfur (CS2)added, the difference between Ni/Mo and Co/Mo catalysts for conversion of bothcoals is eliminated. SB-coal exhibits better conversion than that of Ni/Mo orCo/Mo-treated TH-coal. This probably due to the structure of TH coal is morecondensed and stronger than that of SB coal. The effect of single metal (Ni, Coor Mo separately) could explain the different conversion between Ni/Mo andCo/Mo with and without sulfur and also the difference between SB and TH whenthey reacted with Ni/Mo and Co/Mo with and without added sulfur. The order ofeffectiveness for SB, when it reacted in the absence of sulfur, was decreasedfrom Ni>Mo>Co. But the order was shifted to Mo>>Ni>Co. The similar order wasalso found for TH coal under the same conditions. The study also shows thatreactivity of SB coal was higher than that of TH coal. This results in better yield offuels. Fortunately, the TH coal is still potentially developed for introducing theefficient process of sub bituminous coal liquefaction in Indonesia.Kata Kunci: coal liquefaction, katalis Ni/Mo, Banko, Tanito Harum
KARAKTERISTIK PROSES HIDROKONVERSI KATALITIK DENGAN BAHAN BAKU BITUMEN Yusnitati, Yusnitati; Hanif, Muhammad; Adiarso, Adiarso
Jurnal Energi dan Lingkungan (Enerlink) Vol 6, No 2 (2010)
Publisher : Jurnal Energi dan Lingkungan (Enerlink)

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Abstract

The effects of bitumen types in a hydro-conversion catalytic process to producesyntethic liquid fuels was investigated. Three samples of natural solid bitumenobtained from three different sampling points in Riau Province are used in thisstudy. Preliminary technical feasibility of the natural solid bitumen as a feedstockof synthetic fuel oil using this process is also investigated. Experimental runs arecarried out using a 1 liter stirred batch autoclave reactor under the standardconditions: reaction temperature of 450oC, initial hydrogen pressure of 12 MPafor 1 hour and atomic ratio of sulfur to iron at 2.0. This process condition issimilar to direct coal liquefaction process using heavy oil solvent produced fromBench Scale Unit (BSU) 100 kg/hour input in Takasago, Japan. The resultsindicate that the oil yield increases with the decrease of liquid bottom yield. TotalCO+CO2 and hydrocarbon gases products are almost equal at all bitumensamples. Due to their high ash content, the oil yield (LO, MO and HO) of bitumensamples relatively lower than the oil yield of coal liquefaction process. It was alsofound that O/C and H/C atomic ratio in bitumen samples vary significantly withtheir sampling point, but the H/C ratio of bitumen relatively higher than typicalcoal. The higher of H/C ratio, the easier of bitumen to be converted to syntheticfuel oil and leading to the more efficiently use of gaseous hydrogen. Inconclusion, the natural solid bitumen has a possibility as a feedstock of syntheticfuel oil, if it is fed to the process in the form of a dried-ash-free-bitumen (hyperbitumen).Kata kunci: bitumen, hidrokonversi katalitik, BBM sintetis
ANALISIS KEEKONOMIAN PEMBANGUNAN PEMBANGKIT LISTRIK TENAGA BIOGAS DARI POME DENGAN CONTINUOUS STIRRED TANK REACTOR (CSTR) Sugiyono, Agus; Adiarso, Adiarso; Puspita Dewi, Ratna Etie; Yudiartono, Yudiartono; Wijono, Agung; Larasati, Niken
Majalah Ilmiah Pengkajian Industri Vol 13, No 1 (2019): MAJALAH ILMIAH PENGKAJIAN INDUSTRI
Publisher : BPPT

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (893.039 KB) | DOI: 10.29122/mipi.v13i1.3232

Abstract

Limbah cair kelapa sawit atau dikenal dengan POME (palm oil mill effluent) dapat diproses menjadi biogas sebagai bahan bakar untuk pembangkit listrik. Produksi POME saat ini dapat digunakan untuk pembangkit listrik tenaga biogas (PLTBg) dengan kapasitas mencapai 153,4 MW yang sebagian besar berada di wilayah Sumatera. Salah satu pabrik kelapa sawit (PKS) yang berpotensi untuk pembangunan PLTBg adalah PKS Sei Pagar milik PTPN V Pekanbaru. Studi ini bertujuan untuk melakukan analisis keekonomian pembangunan PLTBg. PLTBg didesain dengan kapasitas 700 kW dengan menggunakan biodigester jenis continuous stirred tank reactor (CSTR). Listrik yang dihasilkan akan dijual ke PLN dengan harga jual sebesar 85% biaya pokok penyediaan (BPP) pembangkitan wilayah Riau sebesar 1.249,5 Rp/kWh. Hasil perhitungan keekonomian menunjukkan bahwa biaya investasi mencapai 26,3 milar Rupiah dengan skema 70% pinjaman dari bank dan sisanya 30% dengan modal sendiri (equity). Biaya opersi dan perawatan mencapai 2,3 miliar Rupiah setiap tahun. Pembangunan PLTBg layak untuk dilaksanakan dengan nilai IRR sebesar 11,44%, waktu pengembalian modal selama 7 tahun 11 bulan, dan NPV sebesar 1.1 miliar Rupiah.
Co-Authors Abd. Rasyid Syamsuri Agus Sugiyono Herman Hidayat, Herman Muhammad Hanif Puspita Dewi, Ratna Etie Wijono, Agung yudiartono, yudiartono Yusnitati Yusnitati