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All Journal Majalah Kulit, Karet, dan Plastik

Prayitno, Prayitno

Center for Leather, Rubber, and Plastic Yogyakarta Indonesia

Author-ID : 734415

Engineering

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Peningkatan ketahanan suhu dingin kulit atasan sepatu melalui pengurangan daya penyerapan air dan pengaruhnya terhadap sifat fisik dan morfologi Prayitno, Prayitno; Kasmudjiastuti, Emiliana
Majalah Kulit, Karet, dan Plastik Vol 33, No 1 (2017): Majalah Kulit, Karet, dan Plastik
Publisher : Center for Leather, Rubber, and Plastic Ministry of Industry, Indonesia

A research has been undertaken to increase the cold resistance of upper leather by decreasing its water absorption ability. Fluorinated acrylic polymer, a water repellent substance, was added at fatliquoring and finishing stages of upper leather with different concentrations levels. Research findings showed that an increase in the water-repellent concentration, i.e. by 5; 7.5; 10; 12.5; and 15%, result in increases in tensile strength, tearing strength, and elongation at break, whereas decreases in water absorption ability. No significant differences for the other physical properties such as water vapor absorption, water vapor permeability, and flexing resistance and they met the standard for shoe leather. Results of scanning electron microscopy indicated an increased thin layer of water repellent on leather fibers as the water-repellent concentration increased. The leather fibers looked smoother, glistened, and thicker. This indicates the penetration of water repellent onto leather fibers.Keywords: water absorption, water repellent, cold resistance, upper leather.

Pengaruh bahan water repellent terhadap morfologi dan sifat-sifat fisika pada pembuatan kulit atasan sepatu ramah lingkungan Prayitno, Prayitno; Kasmudjiastuti, Emiliana; Rahmawati, Dona
Majalah Kulit, Karet, dan Plastik Vol 32, No 2 (2016): Majalah Kulit, Karet, dan Plastik
Publisher : Center for Leather, Rubber, and Plastic Ministry of Industry, Indonesia

The term of eco-friendly leather can be interpreted as chrome-free tanned leather. Recently, almost 80% of leather is tanned using chrome tanning agent because of the ease in processing and excellence of the physical properties. Nevertheless, people nowadays want an eco-friendly leather product. Vegetable tanning materials can be said as eco-friendly tanning material because their waste degrades easily. One of the weaknesses in the use of vegetable tanning is a high water absorption capability. In this research used a water repellent material that has the properties to suppress the ability of water absorption. The purpose of the research was to determine the effect of water repellent on physical properties and morphology of leather tanned by vegetable tanning materials. Because one of the weaknesses in the vegetable tanning is its high water absorption capability, in this research, water repellent was used and varied by 5; 7.5; 10; 12.5; and 15% . Physical properties obtained were compared with analysis of variance with the significance level of 95%. The water repellent increased from 5% to 15%. The results showed a decrease in water absorption capability from 77.6% to 65.39%, tearing strength from 41.64 to 20.05 kg/cm, tensile strength from 227.10 to 163.53 kg/cm2, and elongation at break from 57.11 to 49.68%, strong swelling and WVA have no significant changes, while for WVP, the maximum use of water repellent at 12.5%. SEM results indicate the presence of a thin layer on the leather fiber that can inhibit the absorption of water.Keywords: water repellent, upper leather, vegetable tanning, water absorption.

Co-Authors Emiliana Kasmudjiastuti, Emiliana Kasmudjiastuti, Emiliana Rahmawati, Dona

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