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Potensi Formulasi Sediaan Sabun Padat Minyak Kelapa dengan Pengisi Kaolin sebagai Media Pembersih Najis Mughallazah Panjaitan, Vera Diana; Sukeksi, Lilis; Iriany; Siswarni
Jurnal Teknik Kimia USU Vol. 9 No. 2 (2020): Jurnal Teknik Kimia USU
Publisher : Talenta Publisher (Universitas Sumatera Utara)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.32734/jtk.v9i2.3851

Abstract

Qur'an explains najis mughallazah be purified using water as much as 7 times and one of which uses the ground. The addition of clay to the soap helps remove impure DNA attached to the surface of the skin. This study was conducted to determine the effect of an increase in the amount of kaolin and reaction temperature on water content and hardness of soap; determine whether the soap formulas meet the quality requirements of SNI and determine whether the soap formula capable of eliminating the derivatives pig DNA using PCR analysis method. The reaction was designed in 4 reaction temperatures (50ºC - 80ºC), the consistency of kaolin (10% - 20%), 35% NaOH concentration, reaction time 10 minutes and the stirring speed of 250 rpm. The results showed that all variations meet SNI standards. The best results were obtained in 15%; 50ºC and 17.5%; 60ºC. First, rinse the soap can eliminate DNA smeared unclean human hands. DNA washing using water and soap shows the remaining conventional PCR DNA electrophoresis. Kaolin solid soap formulation produced may eliminate DNA and meet the standard SNI 06-3532-2016.
Potensi Formulasi Sediaan Sabun Padat Minyak Kelapa dengan Pengisi Bentonit sebagai Media Pembersih Najis Mughallazah Tobing, Maria Grace; Sukeksi, Lilis; Iriany; Siswarni
Jurnal Teknik Kimia USU Vol. 10 No. 1 (2021): Jurnal Teknik Kimia USU
Publisher : Talenta Publisher (Universitas Sumatera Utara)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.32734/jtk.v10i1.4575

Abstract

Najis mughallazah is excrement which comes from pigs which earthen soap can use to purify it.  Method to purify unclean that is necessary to use water seven times and the addition of bentonite to soap is expected to be able to remove unclean Deoxyribonucleic Acid (DNA) that is located on the surface of human skin. The purpose of this study was to determine the effect of the amount of bentonite filler and the reaction temperature on the quality of soap, knowing whether the soap formula meets the SNI quality requirements and knowing whether the soap formula can remove Pig DNA residues using the Polymerase Chain Reaction (PCR) analytical method. In this study, the operation conditions were designed at the reaction temperature (50 oC, 60 oC, 70 oC and 80 oC), bentonite consistency (10%, 12.5%, 15%, 17.5% and 20%), 35% NaOH concentration, reaction time 10 minutes and stirring speed 250 rpm. The analyzes carried out in this study include analysis of water content, free alkaline content, free fatty acid content and PCR method. The best results were obtained for 15% (70 °C) soap that had soap hardness characteristics close to conventional soap and 17.5% (50 °C) soap with the characteristics of soap that could remove najis mughallazah. The resulting solid bentonite soap formula meets the SNI 3523: 2016 standard and can eliminate mughallazah unclean.
Ekstraksi Tanin dari Buah Balakka (Phyllanthus emblica L.) dengan Bantuan Microwave: Pengaruh Daya Microwave, Perbandingan Massa Kering Terhadap Jumlah Pelarut Etil Asetat Iriany; Angkasa, Hendri; Namira, Cut Annisa
Jurnal Teknik Kimia USU Vol. 10 No. 1 (2021): Jurnal Teknik Kimia USU
Publisher : Talenta Publisher (Universitas Sumatera Utara)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.32734/jtk.v10i1.5318

Abstract

Tannins are phenolic compounds with considerable abundance in nature. In this study, the extraction of Indian gooseberry fruit was performed using Microwave Assisted Extraction (MAE) method with ethyl acetate as solvent. Two grams of Indian gooseberry fruit were extracted for 1 minute with variable microwave power operation (100, 180, 300, 450 and 600) W. The experiment is continued at the power that gave the highest yield of tannin with  variable ratio sample to solvent (1/10, 1/20, 1/30, 1/40 and 1/50) g/mL. Total tannins in the extract were analyzed using UV-Vis Spectroscopy method to find the yield of tannin. Functional groups that were contained in the extract were analyzed using Fourier-Transform Infrared Spectroscopy (FTIR) method. The results of this study indicate that the extract contains tannins in qualitative tests with gelatin and FeCl3 as well as in FTIR analysis. The highest yield of tannin was 36.86 mg/g which was obtained under conditions of power 100 W and ratio sample with ethyl acetate 1/50 g/mL.
Studi Model Isoterm Adsorpsi Kristal Violet oleh Biosorben Kulit Ubi Kayu (Manihot esculenta) Ramadhan, Muhammad Dafin; Iriany; Misran, Erni; Turmuzi , Muhammad
Jurnal Teknik Kimia USU Vol. 10 No. 1 (2021): Jurnal Teknik Kimia USU
Publisher : Talenta Publisher (Universitas Sumatera Utara)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.32734/jtk.v10i1.5485

Abstract

Crystal violet is a dye that has many uses, but its waste can be harmful to humans and the environment. Adsorption is the most useful method for removing crystal violet waste compared to other separation methods because of its efficiency and viability. Cassava peel is a material that has potential to be an adsorbent. Cassava peel is suitable as an adsorbent because of its high cellulose, hemicellulose, and lignin content. In carrying out adsorption, getting the most appropriate isotherm model is important for predicting the adsorption parameters and the adsorbent system. This study aims to obtain an adsorption isotherm model that is the most suitable for the adsorption of crystal violet by cassava peel biosorbent with high accuracy and to obtain a combined model of the adsorption isotherm model that is the most suitable with the mass balance equation to predict removal efficiency. This research was conducted using secondary data using MATLAB as a supporting tool to perform a non-linear regression and Newton-Raphson iteration. In this research, we conclude that Sips model is the most suitable model with qms = 374,3 mg/g and 0,5933 site heterogeneity. For predict adsorbent mass ratio: adsorbate volume minimum ratio but removal efficiency stay at ≥ 90%, we obtain a correlation factor: m/V = -1.10-11Co4 + 2.10-8Co3 – 2.10-5Co2 + 0.015Co + 1.2686.
Pengaruh Komposisi Bahan Baku dan Ukuran Partikel Terhadap Kualitas Biobriket dari Cangkang Buah Karet dan Ranting Kayu Iriany; Hasibuan, Rosdanelli; Novita, Dian; Ummah, Nisa’a Mufidatul
Jurnal Teknik Kimia USU Vol. 12 No. 1 (2023): Jurnal Teknik Kimia USU
Publisher : Talenta Publisher (Universitas Sumatera Utara)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.32734/jtk.v12i1.9818

Abstract

Biobriquette is a solid fuel derived from raw materials that can be renewed continuously because it is made from a mixture of biomass such as wood, twigs, leaves, grass, straw and other agricultural wastes. The research aims to examine the effect of variations in the composition of raw materials and particle sizes were 50 mesh, 70 mesh, 100 mesh, and 120 mesh. This research was started by carrying out the pyrolysis process on the raw material with temperature 350 oC for sixty minutes, then the refined pyrolysis charcoal powder was mixed with starch adhesive 10% of the weight of the raw material which was then manually pressed cylindrical. The measurement results in this research were compared with quality parameters based on Indonesian National Standard (SNI), Japan, England, and America. The best result for this research is obtained at a ratio of rubber fruit shells and wood twigs 1:5 with a particle size of 100 mesh, that is with inherent moisture of 4.50%, ash content of 2.19%, volatile matter of 13.73%, density 2.2502 g/cm3, and caloric value 6,653.60 cal/g.
Karakterisasi Biofilm Selulosa Bakteri dengan Modifikasi Gliserol secara Ex Situ Panjaitan, Vera Diana; Iriany; Sukeksi, Lilis
Jurnal Teknik Kimia USU Vol. 13 No. 1 (2024): Jurnal Teknik Kimia USU
Publisher : Talenta Publisher (Universitas Sumatera Utara)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.32734/jtk.v13i1.13560

Abstract

Bacterial cellulose (BC) is biomaterial from bacterial fermentation that contain high purity of cellulose, but 90% of BC pellicles retained water from the fermentation process. In this study, BC was modified with glycerol immersion in different concentrations (0%; 2,5%; 5%; 7,5%; 10%). For wide application, water content on BC must be removed by drying. Various oven drying condition are temperature 80 °C and 120 °C and time 60 minutes. The physical and mechanical properties of the dried BC biofilm were determined including tensile strength and elasticity. BC biofilm bound was identified by FTIR and EDX. The results showed that glycerol concentration was able to increase biofilm elasticity from 3.46% to 27.743%. However, glycerol immersion above 7.5% caused a decrease in the tensile strength of BC biofilm. The drying variation of 120 °C produces the highest tensile strength of 7.161 MPa when soaked in 7.5% glycerol. The drying variation of 80 °C produced a biofilm with the best elasticity of 27.473%. The results of FTIR and EDX analysis confirmed that there were differences in the contents of the modified BC.
PEMANFAATAN EDU GAME CLASSCRAFT FABUBI DALAM KIMIA HIJAU BERBASIS KEARIFAN LOKAL UNTUK MENGUATKAN KETERAMPILAN NUMERASI SISWA KELAS X-G SMAN 2 KOTA TERNATE Iriany
Prosiding Seminar Nasional Orientasi Pendidik dan Peneliti Sains Indonesia Vol. 2 (2023): Prosiding Seminar Nasional Orientasi Pendidik dan Peneliti Sains Indonesia (OPPSI) 20
Publisher : Orientasi Pendidik dan Peneliti Sains Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar

Abstract

Pemanfaatan Edu Game Classcraft Fabubi dalam Kimia Hijau berbasis Kearifan Lokal untuk menguatkan keterampilan numerasi siswa Kelas X-G SMAN 2 Kota Ternate. Penelitian ini bertujuan untuk mengetahui peningkatan keterampilan numerasi siswa kelas X G melalui pemanfaatan Edu Game Classcraft Fabubi pada topik Kimia Hijau dalam pembelajaran kimia. Penelitian dilaksanakan di SMA Negeri 2 Kota Ternate dengan menggunakan metode penelitian tindakan kelas selama 2 siklus. Pembelajaran kimia hijau ini menerapkan pembelajaran project based learning dengan sintaks pembelajaran 1) menyajikan masalah kontekstual 2) Merancang ide karya; 3) Menyusun jadwal proyek ;4) Melaksanakan proyek; 5) Monitoring proyek ;6) Presentasi dan Perbaikan Karya serta 7) Publikasi karya. Pada awal pembelajaran siswa diberikan tes awal untuk mengetahui level pemahaman siswa tentang konsep kimia hijau. Pada tahap perencanaan kegiatan pembelajaran dilakukan berbasis proyek, dengan fokus pada pemahaman konsep siswa tentang pengertian dan pentingnya kimia hijau dan pengaplikasiannya dalam proyek-proyek mini yang relevan untuk menguatkan numerasi anak. Proses pembelajaran melibatkan siswa dalam perencanaan, desain, dan pelaksanaan proyek, dengan pengamatan terus-menerus melalui kegiatan metode ilmiah dengan bantuan Edu Game Classcraft Fabubi. Selain itu kegiatan pengenalan simbol unsur kimia, reaksi kimia dan persamaan reaksi diintegrasikan dalam aktivitas riset sumber belajar kimia hijau dan observasi ke lapangan. Kegiatan ini diakhiri dengan refleksi. Kegiatan pembelajaran pada Siklus II penelitian diawali dengan aktivitas siswa melakukan refleksi diri tentang apa yang telah dilakukan di tahap siklus I. Siswa merencanakan proyek implementasi prinsip-prinsip kimia hijau untuk lebih menguatkan keterampilan numerasi lintas mata pelajaran untuk menguatkan pemahaman siswa melalui keterampilan numerasi . Evaluasi hasil belajar siswa dilakukan secara formatif dan sumatif dengan tes kognitif dan penilaian proyek. Hasil penelitian menunjukkan bahwa ada peningkatan yang signifikan dari siklus I sebesar 67,5% dan meningkat sebesar 88,9 % pada siklus II melalui praktek pembelajaran kimia berbasis proyek.
Potensi Formulasi Sediaan Sabun Padat Minyak Kelapa dengan Pengisi Kaolin sebagai Media Pembersih Najis Mughallazah Panjaitan, Vera Diana; Sukeksi, Lilis; Iriany; Siswarni
Jurnal Teknik Kimia USU Vol. 9 No. 2 (2020): Jurnal Teknik Kimia USU
Publisher : Talenta Publisher (Universitas Sumatera Utara)

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (263.082 KB) | DOI: 10.32734/jtk.v9i2.3851

Abstract

Qur'an explains najis mughallazah be purified using water as much as 7 times and one of which uses the ground. The addition of clay to the soap helps remove impure DNA attached to the surface of the skin. This study was conducted to determine the effect of an increase in the amount of kaolin and reaction temperature on water content and hardness of soap; determine whether the soap formulas meet the quality requirements of SNI and determine whether the soap formula capable of eliminating the derivatives pig DNA using PCR analysis method. The reaction was designed in 4 reaction temperatures (50ºC - 80ºC), the consistency of kaolin (10% - 20%), 35% NaOH concentration, reaction time 10 minutes and the stirring speed of 250 rpm. The results showed that all variations meet SNI standards. The best results were obtained in 15%; 50ºC and 17.5%; 60ºC. First, rinse the soap can eliminate DNA smeared unclean human hands. DNA washing using water and soap shows the remaining conventional PCR DNA electrophoresis. Kaolin solid soap formulation produced may eliminate DNA and meet the standard SNI 06-3532-2016.
Potensi Formulasi Sediaan Sabun Padat Minyak Kelapa dengan Pengisi Bentonit sebagai Media Pembersih Najis Mughallazah Tobing, Maria Grace; Sukeksi, Lilis; Iriany; Siswarni
Jurnal Teknik Kimia USU Vol. 10 No. 1 (2021): Jurnal Teknik Kimia USU
Publisher : Talenta Publisher (Universitas Sumatera Utara)

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (274.914 KB) | DOI: 10.32734/jtk.v10i1.4575

Abstract

Najis mughallazah is excrement which comes from pigs which earthen soap can use to purify it.  Method to purify unclean that is necessary to use water seven times and the addition of bentonite to soap is expected to be able to remove unclean Deoxyribonucleic Acid (DNA) that is located on the surface of human skin. The purpose of this study was to determine the effect of the amount of bentonite filler and the reaction temperature on the quality of soap, knowing whether the soap formula meets the SNI quality requirements and knowing whether the soap formula can remove Pig DNA residues using the Polymerase Chain Reaction (PCR) analytical method. In this study, the operation conditions were designed at the reaction temperature (50 oC, 60 oC, 70 oC and 80 oC), bentonite consistency (10%, 12.5%, 15%, 17.5% and 20%), 35% NaOH concentration, reaction time 10 minutes and stirring speed 250 rpm. The analyzes carried out in this study include analysis of water content, free alkaline content, free fatty acid content and PCR method. The best results were obtained for 15% (70 °C) soap that had soap hardness characteristics close to conventional soap and 17.5% (50 °C) soap with the characteristics of soap that could remove najis mughallazah. The resulting solid bentonite soap formula meets the SNI 3523: 2016 standard and can eliminate mughallazah unclean.
Ekstraksi Tanin dari Buah Balakka (Phyllanthus emblica L.) dengan Bantuan Microwave: Pengaruh Daya Microwave, Perbandingan Massa Kering Terhadap Jumlah Pelarut Etil Asetat Iriany; Angkasa, Hendri; Namira, Cut Annisa
Jurnal Teknik Kimia USU Vol. 10 No. 1 (2021): Jurnal Teknik Kimia USU
Publisher : Talenta Publisher (Universitas Sumatera Utara)

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (231.02 KB) | DOI: 10.32734/jtk.v10i1.5318

Abstract

Tannins are phenolic compounds with considerable abundance in nature. In this study, the extraction of Indian gooseberry fruit was performed using Microwave Assisted Extraction (MAE) method with ethyl acetate as solvent. Two grams of Indian gooseberry fruit were extracted for 1 minute with variable microwave power operation (100, 180, 300, 450 and 600) W. The experiment is continued at the power that gave the highest yield of tannin with  variable ratio sample to solvent (1/10, 1/20, 1/30, 1/40 and 1/50) g/mL. Total tannins in the extract were analyzed using UV-Vis Spectroscopy method to find the yield of tannin. Functional groups that were contained in the extract were analyzed using Fourier-Transform Infrared Spectroscopy (FTIR) method. The results of this study indicate that the extract contains tannins in qualitative tests with gelatin and FeCl3 as well as in FTIR analysis. The highest yield of tannin was 36.86 mg/g which was obtained under conditions of power 100 W and ratio sample with ethyl acetate 1/50 g/mL.