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Analysis of Petroleum Products Spill Potential Impact (Gasoline and Diesel Fuels) on Soil Fertility Quality Around Pertamina Rewulu-Cilacap Pipeline Bantul-Yogyakarta Muthohharoh, Thaifah; Latumahina, Linda Johana; Suyanta, Suyanta; Suherman, Suherman
Molekul Vol 18 No 2 (2023)
Publisher : Universitas Jenderal Soedirman

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.20884/1.jm.2023.18.2.5402

Abstract

This research focused on analyzing the potential impact of petroleum products spill (gasoline and diesel fuels) on soil fertility quality around PERTAMINA Rewulu-Cilacap Pipeline Bantul, Yogyakarta. The objectives of this study were to analyze the change of soil fertility parameters that are contaminated by gasoline and diesel fuel oils, compared to uncontaminated soil as control. Soil samples were collected from Pertamina Rewulu-Cilacap around the pipeline. Some physico-chemical properties that reflect soil fertility were determined using standard physico-chemical methods and Total Petroleum Hydrocarbon (TPH) using Gas Chromatography. Soil samples were divided into three points (I, II, and III) based on taken places. The study started with analysis of physical and chemical properties of the soil, then petroleum products (gasoline and diesel) were added to the soil samples. The contaminated soil and control then analyzed for identify the fertility quality and TPH content. The results showed that petroleum product contamination increases N, P, and reduces K concentrations in the soil. The sample in point III had the highest values of TPH concentration without any additional petroleum products. After addition of a dose of 13% gasoline, the concentration of TPH in point I, II, and III increased by 0.036%, 0.08% and 0.008%. With the addition of 15% diesel in the sample, the TPH concentration of point I, II, and III increased by 0.892 %, 1.198%, and 0.91%.
Toxicity Test of Zinc on Contaminated Soil by Petroleum Products (Fuel Oil) around Pertamina Rewulu-Cilacap Pipeline Bantul, Yogyakarta by Using Mung Bean (Vigna radiata) and Water Spinach (Ipomoea aquatica) Latumahina, Linda Johana; Tanzil, Yosua; Suyanta, Suyanta; Suherman, Suherman
Indonesian Journal of Chemistry Vol 24, No 4 (2024)
Publisher : Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.22146/ijc.85381

Abstract

Toxicity test of zinc on contaminated soil by petroleum products around the Pertamina Rewulu-Cilacap pipeline, Bantul, Yogyakarta by using mung bean (Vigna radiata) and water spinach (Ipomoea aquatica) have been studied. This study aims to investigate the physico-chemical properties, adsorption, and desorption of soil samples, and the effect of Zn toxicity on the growth of mung bean and water spinach. The physico-chemical properties were evaluated including moisture content, ash content, pH, conductivity, total organic carbon, cation exchange capacity, and heavy metal content. In addition, total petroleum hydrocarbon was analyzed by using GC-MS, and samples were characterized by using FTIR and XRD. The adsorption and desorption capacities of Zn were determined by an atomic absorption spectrophotometer (AAS) measurement. Toxicity test was conducted on the growth of mung bean and water spinach. This study showed that soil sample point III had the highest Zn content at 632.26 mg kg−1. Adsorption isotherms of zinc metal followed the Langmuir isotherm model and maximum adsorption occurred at 100 mg kg−1. Optimum desorption takes place at the concentration of citrate acid 0.7 mol L−1 and at pH 3. Toxicity test results revealed that zinc metal at high concentrations was found to be toxic to seedling growth.