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Isotherm and Kinetic Adsorption of Cadmium (Cd) onto Biosorbent Made from Kepok Banana Peel (Musa Acuminata balbisian): The Effect of Activator Type and Biosorbent Dosage Cundari*, Lia; Fanneze, Alna Livia; Arisma, Nanda Citra; Julian, Asha Aisha
Aceh International Journal of Science and Technology Vol 12, No 2 (2023): August 2023
Publisher : Graduate School of Universitas Syiah Kuala

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.13170/aijst.12.2.27947

Abstract

The present study determined the isotherm and kinetics model of the cadmium adsorption process onto a biosorbent made from kepok banana peel (Musa Acuminata balbisian). The experiments were carried out in batch process, laboratories scale, room temperature, pH of Cadmium of 4, volume of Cd solution of 20 ml, and biosorbent size particle of 60 meshthe biosorbent produced using chemical activation method onto dry banana peel. The variation in this research was the type of activator (H3PO4 and H2SO4) and the biosorbent dosage (1, 1.5, and 2 g). The experimental data was used to calculate the Langmuir and Freundlich isothermKinetics analysis based on pseudo-first-order and second-order kinetics models. The best condition of the cadmium removal occurred at 90 minutes of contact time and 2 g dosage for H2SO4 and H3PO4 activators. Cadmium biosorption was in accordance with the Langmuir isotherm and pseudo-second-order kinetic model. The linear equation obtained is positive, with the maximum adsorption capacity and the affinity constant. Cadmium adsorption onto banana peel biosorbents followed the Langmuir adsorption isotherm pattern, so chemical adsorption occurred in this study. Cadmium adsorption kinetics onto biosorbent that activated with an acid activator of H3PO4 and H2SO4 followed the pseudo-second-order kinetic model. The best condition of the cadmium removal occurred at 90 minutes of contact time and 2 g dosage for H2SO4 and H3PO4 activators. Cadmium biosorption in this study was in accordance with the Langmuir isotherm and pseudo-second-order.
Reduction of Turbidity, Color Intensity and COD of Jumputan Wastewater with Electrocogulation Method Julian, Asha Aisha; Larasati, Wulan Ayum; Cundari, Lia
Jurnal Rekayasa Kimia & Lingkungan Vol 18, No 1 (2023): Jurnal Rekayasa Kimia & Lingkungan (June, 2023 )
Publisher : Chemical Engineering Department, Syiah Kuala University, Banda Aceh, Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.23955/rkl.v17i2.26511

Abstract

The purpose of this study was to determine the effectiveness of the electrocoagulation method in reducing turbidity, color concentration and COD levels on Jumputan wastewater treatment. The electrodes used are aluminum plates as anode and cathode. The variations of the research used were the speed of agitation and the system used (batch and intermittent system). The fixed variable used is a voltage of 3.5 volts, the 2 aluminium electrodes, and 250 ml volume of Jumputan wastewater. The results showed that the maximum turbidity degraded to 99.89% for the batch system at a contact time of 150 minutes with agitation speed of 150 rpm, and 99.97% for intermittent system at a contact time of 60 minutes with agitation speed of 150 rpm. The maximum percentage of color removal reached 58.90% for the batch system at a contact time of 90 minutes with a stirring speed of 50 rpm, and 54.74% for intermittent system at a contact time of 150 minutes with a stirring speed of 150 rpm. The electrocoagulation method could reduce 78.75% of the COD level for the batch system is and 80% for the intermittent system. The intermittent system slightly had more effect on the turbidity, color and COD reduction compared to batch system. Both batch and intermittent system got optimum turbidity and color removal on first 30 minutes of electrocoagulation process. The results prove that electrocoagulation method has been effective as an alternative to reduce COD and turbidity on Jumputan wastewater.