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Extraction of Natural Dyes from Cocoa Pod Husk (Theobroma cacao L.) using Ultrasound Assisted Extraction as a Natural Fabric Dye Utami, Herti; Harahap, Katrina; Pista, Annisa Fitria; Azizah, Ara Annastasya; Marlina, Arlin; Darni, Yuli; Ginting, Simparmin br
Jurnal Rekayasa Kimia & Lingkungan Vol 19, No 2 (2024): Jurnal Rekayasa Kimia & Lingkungan (December, 2024)
Publisher : Chemical Engineering Department, Syiah Kuala University, Banda Aceh, Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.23955/rkl.v19i2.38384

Abstract

Natural dyes are one of the popular choices for textile dyes today. One part of the plant that has the potential to produce natural dyes is cocoa pod husk (Theobroma cacao L.) because it contains several secondary metabolite compounds, such as tannin which produces a brown color. The extraction method used in this research is Ultrasonic Assisted Extraction (UAE). This study aims to obtain the highest yield of natural dye extracts from cocoa pod husk by varying solvent types, extraction time, and material-to-solvent ratios using the UAE method. In addition, the types of compounds contained in extracts of natural dyes and color results on cotton fabrics were also obtained. The extraction process was carried out using several types of solvents, namely methanol, ethanol, acetone, and distilled water with varying extraction times of 30, 60, and 90 minutes. The research results show that the solvent that can extract the best natural dyes was ethanol with a yield of 11.43% and an extraction time of 90 minutes. Variable ratios of material to 96% ethanol solvent were also observed, namely at ratios of 1:5, 1:6, 1:7, and 1:8 for extraction times of 30, 60, 90, and 120 minutes. The research results were obtained for the ratio of material to ethanol solvent; 1:8 (w/v) and extraction time 120 minutes with a dye yield of 12.29%. The results of the UV-visible spectrophotometry analysis were obtained that the maximum wavelength of cocoa pod husk extract was 656.5 nm with an absorbance of 0.532. The results of the Gas Chromatography-Mass Spectrometry (GC-MS) analysis were obtained that the dye compound in the cocoa pod husk was tannin. Tannin compounds are natural dyes that can be applied to fabrics and will reduce the use of synthetic dyes. The application of dye extracts to cotton fabrics produced a brown color.
Optimization of Operating Conditions for the Extraction of Natural Dyes, from the Peel of Djenkol (Pithecellobium Jiringa) Using the Response Surface Methodology (RSM) Method and Behnken Design (BBD) Experimental Design Utami, Herti; Marlina, Arlin; Azizah, Ara Annastasya; Nurhidayat, Adib
Jurnal Rekayasa Kimia & Lingkungan Vol 20, No 2 (2025): Jurnal Rekayasa Kimia & Lingkungan (December, 2025) In Press
Publisher : Chemical Engineering Department, Syiah Kuala University, Banda Aceh, Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.23955/rkl.v20i2.45536

Abstract

Natural dyes are generally contained in plant parts such as twigs, stems, peel, flowers, fruits, and roots. Djenkol peel is one of the wastes that has the potential to be used as a natural dye. The extraction of natural dyes from djenkol peel is carried out using Ultrasonic Assisted Extraction. Optimization was carried out using the Response Surface Methodology (RSM) with an experimental design of Box Behnken Design (BBD) which aimed to determine the influence of three research variables (solid to liquid ratio, time, and extraction temperature) on the yield response of the obtained natural dye extract. Based on the optimization that has been carried out, an optimal solution was obtained with an optimal %yield result from the natural dye extract of djenkol peel of 25.285% with variations of solid to liquid ratio, temperature, and extraction time respectively of 0.079 g/ml, 59.979 oC, and 89.998 minutes. The results of the UV-Vis spectrophotometry test showed a wave peak at 300 nm with an absorbance value of 4.88, the GC-MS test showed that tannin are the dominant compounds contained in djenkol peel extract.