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BIOMASSA SEBAGAI MATERIAL ELEKTRODA SUPERKAPASITOR Nur Adi Saputra; Wasrin Syafii; Gustan Pari; Deded Sarip Nawawi; Akhiruddin Maddu
Jurnal Penelitian Hasil Hutan Vol. 40 No. 3 (2022): Jurnal Penelitian Hasil Hutan
Publisher : BRIN Publishing

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.20886/jphh.2022.40.3.189-202

Abstract

Electrical storage and distribution devices become important in next generation to help integrate more renewable energy intothe electricity grid. Supercapacitor technology is considered the most promising alternative to Li-ion batteries, which have limitedLithium material. However, the low energy density is a weakness of supercapacitors, even though they have a high-power density.Activated carbon-based supercapacitor electrodes have ideal potential for development. The inherent attributes of activated carbon,pore properties, and functional groups, are responsible for improving the performance of supercapacitors. The main challenge for theresearchers is the pore size distribution, micro (<2nm), meso (2–50 nm), and macro (>50 nm), which varied in activated carbon.Micro pores have an impact on increasing the value of specific capacitance values which will encourage an increase in energy density.Meso pores have an impact on the overall accessibility of the electrode surface by electrolyte ions. Future studies will emphasize oncarbonization and activated carbon activation techniques to improve the surface quality of activated carbon.
PENGARUH ZAT EKSTRAKTIF KAYU GAMAL (Gliricidia sepium Jacq.) TERHADAP NILAI KALOR Rahmi Mauladdini; Wasrin Syafii; Deded Sarip Nawawi
Jurnal Penelitian Hasil Hutan Vol. 40 No. 2 (2022): Jurnal Penelitian Hasil Hutan
Publisher : BRIN Publishing

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.20886/jphh.2022.40.2.125%E2%80%93134

Abstract

The development of gamal wood (Gliricidia sepium Jacq.) aims to meet the needs of biomass energy in rural areas. Manystudies on extractives of gamal wood have been carried out, but there is very little information about the effect of extractives on thecalorific value. The effect of extractives on the calorific value can be determined by analyzing extractives compounds contained in thewood. This study aimed to determine the extractives compounds that affect the wood calorific value. The sawdust of gamal bark andwood was extracted by successively maceration by using solvents with different polarities. The free-extractives sawdust was thenmeasured for its calorific value. To ascertain the effect of extractives on the calorific value, the extract of the gamal bark and woodwas added to the oil palm sawdust, then the increase in calorific value was measured. The results showed that the extractives ingamal bark and wood affect the change of calorific value. The removal of extractives by using different solvents caused a differentdecrease in calorific value. The highest decrease in calorific value (4.03%) was obtained by non-polar (n-hexane) soluble extractiveof the gamal bark. The addition of gamal wood extracts to oil palm sawdust also causes an increase in the calorific value.Phytochemical and LC-MS/MS analysis of n-hexane soluble extractives from gamal bark detected groups of terpene compounds,amides alkaloids, flavonoids, coumarins, and benzopyrans. Based on the results of this study, the n-hexane soluble compounds wassuspected to have the most influence on the calorific value.